高分子材料配方均匀设计系统

结合实验均匀设计和逐步回归优化方法，设计了更为科学的高分子材料配方设计系统，可更准确地预测产品的性能，简化实验程序，提高实验效率。该系统特别适用于多因素多水平多指标实验，在配方变量的变化范围内，利用回归方程建立单一组分与性能间的关系，并可用于预测某一配方的性能指数，利用计算机程序在设定优化条件后可得到相应的优化配方及其性能指标。     

Effects of soaking soybeans in dilute acids on biologically active components

Soaking soybeans in dilute acids affected activities of lipoxygenase, trypsin inhibitor and urease. Effects of soaking time, acid concentration and soaking temperature were investigated. Lipoxygenase activity was completely eliminated by soaking in 0.3 M HC1 at either 23°C or 40°C for 8 hr. Less than 50% trypsin inhibitor remained and urease was inactivated to an acceptable level (0.04 ΔpH).     

苜蓿田杂草茎口叶处理药剂筛选试验报告

对5％普施特AS、25％苯达松AS、50％高特克SE、15％精稳匀得EC、6．9％威霸EW等10种除草剂及其混用在苜缩中进行了药效试验。除草效果达到80．7％－98．2％，增产效果显著。     

Effect of scraped-surface tube cooler temperatures on the physical properties of palm oil margarine

The effects of scraped-surface tube cooler temperatures on the isothermal solid fat content (SFC) of palm oil margarine during processing and on margarine consistency (yield value, g/cm²), SFC, and polymorphic changes in storage were studied. SFC was measured in the mixing tank after leaving the tube cooler and the pin worker. The SFC at the tube cooler exit was proportional to the amount of cooling; a higher SFC was produced by more extreme cooling treatment. The SFC of all margarines were reduced in the pin worker, and the reduction was related to the initial SFC profile of palm oil. Margarine samples were stored at 28°C for 28 d and tested daily. Margarine processed at 25°C in the tube cooler had the highest consistency and the least change in SFC, but by the second week crystals had transformed into the β form. Uniform product consistency and SFC were observed in margarines processed at 20 and 15°C. These margarines retained the β′ crystal form for 3 and 4 wk, respectively. The best palm oil margarine was obtained with a tube cooler temperature of 15°C and a residence time of 1.8 min.     

精对苯二甲酸干燥动力学模型

分析了精对苯二甲酸(PTA)干燥过程中干燥温度,物料初始含湿量,空气流速对干燥速率的影响。结果表明:PTA干燥过程由预热阶段、恒速阶段和降速阶段组成,临界含湿量为5%。随着干燥温度或初始含湿量的升高,干燥速率升高,随着载气流量的升高,干燥速率变化不明显。干燥温度对干燥速率的影响最为显著。通过模型比较得出合适的PTA干燥模型为Page模型,模型计算值与实验值吻合较好。     

The kinetics of B‐a and P‐a type copolybenzoxazine via the ring opening process

The structure of benzoxazines is similar to that of phenolic resin through thermal self‐curing of the heterocyclic ring opening reaction that neither requires catalyst nor releases any condensation byproduct. These polybenzoxazine resins have several outstanding properties such as high thermal stability and high glass transition temperature. To better understand the curing kinetics of this copolybenzoxazine thermosetting resin, dynamic and isothermal differential scanning calorimetry measurements were performed. Three models, the Kissinger method, the Flynn–Wall–Osawa method, and the Kamal method, were used to describe the curing process. Dynamic kinetic activation energies based on Kissinger and Flynn–Wall–Osawa methods are 72.11 and 84.06 KJ/mol, respectively. The Kamal method based on an autocatalytic model results in a total order of reaction between 2.66 and 3.03, depending on curing temperature. Its activation energy and Arrhenius preexponential are 50.3 KJ/mol and 7959, respectively. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 95: 730–737, 2005     

Incorporation and distribution of saturated and unsaturated fatty acids into nuclear lipids of hepatic cells

Liver nuclear incorporation of stearic (18∶0), linoleic (18∶2n−6), and arachidonic (20∶4n−6) acids was studied by incubation in vitro of the [1-¹⁴C] fatty acids with nuclei, with or without the cytosol fraction at different times. The [1-¹⁴C] fatty acids were incorporated into the nuclei as free fatty acids in the following order: 18∶0>20∶4n−6≫18∶2n−6, and esterified into nuclear lipids by an acyl-CoA pathway. All [1-¹⁴C] fatty acids were esterified mainly to phospholipids and triacylglycerols and in a minor proportion to diacylglycerols. Only [1-¹⁴C] 18∶2n−6-CoA was incorporated into cholesterol esters. The incorporation was not modified by cytosol addition. The incorporation of 20∶4n−6 into nuclear phosphatidylcholine (PC) pools was also studied by incubation of liver nuclei in vitro with [1-¹⁴C]20∶4n−6-CoA, and nuclear labeled PC molecular species were determined. From the 15 PC nuclear molecular species determined, five were labeled with [1-¹⁴C]20∶4n−6-CoA: 18∶0–20∶4, 16∶0–20∶4, 18∶1–20∶4, 18∶2–20∶4, and 20∶4–20∶4. The highest specific radioactivity was found in 20∶4–20∶4 PC, which is a minor species. In conclusion, liver cell nuclei possess the necessary enzymes to incorporate exogenous saturated and unsaturated fatty acids into lipids by an acyl-CoA pathway, showing specificity for each fatty acid. Liver cell nuclei also utilize exogenous 20∶4n−6-CoA to synthesize the major molecular species of PC with 20∶4n−6 at the sn-2 position. However, the most actively synthesized is 20∶4–20∶4 PC, which is a quantitatively minor component. The labeling pattern of 20∶4–20∶4 PC would indicate that this molecular species is synthesized mainly by the de novo pathway.     

浅析村民自治在农村社会的运行及其制度完善

村民自治制度实施的质量,直接映射出我国基层民主政治的发展水平.分析和审视了我国村民自治实施中出现的观念难以转变、村委会直接选举的程序缺乏科学性与民主性、制度弹性过大等问题,提出从体制、机制与技术等层面加强村民自治制度的建设和创新,对于进一步完善我国村民自治制度,促进基层民主政治建设具有重要意义.     

良好设施 科学规范化管理的必要性

江西省药物研究所于2008年建立了实验动物屏障设施,同年八月取得《实验动物使用许可证》,现已正常运行两年,由于我们严格按照屏障系统设施标准操作规范进行管理,实验动物屏障设施启用后,一直比较稳定。通过对实验动物屏障设施空调净化系统两年多的运行管理,深深体会到良好设施科学规范管理是非常必要的。     

丙烯酸乙酯合成反应产物的GC／MS分析

本文叙述了丙烯酸乙酯合成产物的ＧＣ／ＭＳ分析．从分析结果看出，本应在酯化反应前除去的ＣＨ３Ｃｌ３仍有较大的含量，这也许是导致丙烯酸乙酯被氯代的原因。