A new model for the hazardous waste location-routing problem

Hazardous waste management involves the collection, transportation, treatment and disposal of hazardous wastes. In this paper a new multiobjective location-routing model is proposed. Our model also includes some constraints, which were observed in the literature but were not incorporated into previous models. The aim of the proposed model is to answer the following questions: where to open treatment centers and with which technologies, where to open disposal centers, how to route different types of hazardous waste to which of the compatible treatment technologies, and how to route waste residues to disposal centers. The model has the objective of minimizing the total cost and the transportation risk. A large-scale implementation of the model in the Central Anatolian region of Turkey is presented.     

The effects of achromatic and chromatic color schemes on participants' task performance in and appraisals of an office environment

This study explores the effects of chroma on participants' performance and environmental appraisal of an office. The research was conducted in a full‐scale experimental room designed as a private office where achromatic and chromatic color schemes with coequal values were applied. Sixty participants were assigned tasks and given a questionnaire to appraise the spatial color schemes. The findings show that chroma significantly affects performance and space appraisal. In terms of accuracy and time spent performance scores measured significantly better in the room with the chromatic scheme than those in the room with the achromatic scheme. The office with the chromatic scheme was found to be more pleasant, attractive, satisfying and dynamic than the one with the achromatic scheme, whereas the achromatic scheme was thought to be more formal and harmonious. Categorization of pleasantness, harmony, dynamism and spaciousness by factor analysis also showed differences between the achromatic and chromatic schemes. © 2011 Wiley Periodicals, Inc. Col Res Appl, 2012     

Fatty acid profiles and fat contents of commercially important seawater and freshwater fish species of Turkey: A comparative study

The fat content and fatty acid compositions of edible muscle of commercially important seawater and freshwater fish species were investigated. The fatty acid compositions of seawater fish species were found to be 25.5–39.4% saturated (SFA), 13.2–29.0% monounsaturated (MUFAs) and 25.2–48.2% polyunsaturated acids (PUFAs), whereas the fatty acid compositions of freshwater fish from Lake Seyhan consisted of 28.0–34.6% saturated (SFA), 10.7–22.7% monounsaturated (MUFAs) and 23.2–43.7% polyunsaturated acids (PUFAs). The proportions of n3 PUFAs of seawater fish (ranging from 22.6 for waker to 44.2% for blue fish) were higher than those of n3 PUFAs of freshwater fish (ranging from 11.5% for North African catfish to 28.4% for zander). However, the levels of n6 PUFAs of seawater fish (ranging from 0.43% for blue fish to 14.4% for sea bass) were lower than those of n6 PUFAs of freshwater fish (ranging from 5.27% for kutum to 16.8% for tench). The results showed that fatty acid profiles of most freshwater fish are basically comparable to those of seawater fish as sources of PUFAs.     

Heat transfer enhancement in a tube using circular cross sectional rings separated from wall

A numerical study was undertaken for investigating the heat transfer enhancement in a tube with the circular cross sectional rings. The rings were inserted near the tube wall. Five different spacings between the rings were considered as p = d/2, p = d, p = 3d/2, p = 2d and p = 3d. Uniform heat flux was applied to the external surface of the tube and air was selected as working fluid. Numerical calculations were performed with FLUENT 6.1.22 code, in the range of Reynolds number 4475–43725. The results obtained from a smooth tube were compared with those from the studies in literature in order to validate the numerical method. Consequently, the variation of Nusselt number, friction factor and overall enhancement ratios for the tube with rings were presented and the best overall enhancement of 18% was achieved for Re = 15,600 for which the spacing between the rings is 3d.     

Antibacterial oil‐based polyurethane films for wound dressing applications

As an alternative to petroleum‐based polyol, hydroxyl containing material was prepared from linseed oil for polyurethane synthesis. Hexamethylene di‐isocyanate (HMDI) and/or 4, 4′‐methylene diphenyl di‐isocyanate (MDI) were used as isocyanate source. The polymerization reaction was carried out without catalyst. Polymer films were prepared by casting‐evaporation technique. The MDI/HMDI‐based polyurethane and its films had higher T_g and better thermal property than that of the HMDI‐based one because of the existence of benzene ring in the polymer chain. Static water contact angle was determined to be 74° and 77.5° for HMDI and MDI/HMDI‐based films, respectively. Water adsorption was found to be around 2.6–3.6% for both films. In vitro degradation of polyurethanes in phosphate buffered saline at 37°C was investigated by gravimetric method. Fourier transform infrared spectroscopy and scanning electron microscopy were used for confirmation of degradation on the polymer surface. The degradation rate of the HMDI‐based polyurethane film was found higher than that of the MDI/HMDI‐based film. Both the direct contact method and the MMT test were applied for determination of cytotoxicity of polymer films, and the polyurethane films investigated here was not cytotoxic. Silver‐containing films were prepared using Biocera A® as filler and were screened for their antibacterial performance against Escherichia coli, Pseudomonas aeruginosa, Staphylococcus aureus, and/or Bacillus subtilis. The films prepared with and without Biocera A® exhibited antibacterial activity. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2010     

Changes in total phenols, total flavonoids, and antioxidant activities of common beans and pinto beans after soaking, cooking, and in vitro digestion process

Even though bean varieties are widely consumed all over the world, data related to how cooking methods and in vitro digestion affect bioactive compounds they contain and data related to bioavailability of polyphenols are limited. The aim of the present study was to investigate how some cooking methods and in vitro digestion influence antioxidant activity, total phenols (TP), and total flavonoids (TF) of widely consumed beans in Turkey. Soaking caused a significant decrease (25.61–38.63%) in the bioavailability of TP of dry common beans (CB). Soaking in cold water resulted in a significant decrease in TP bioavailability of dry pinto beans (PB). TF content was well retained in PB cooked without soaking but was not detected in CB after in vitro digestion. CB soaked in hot water and cooked with the addition of NaHCO₃ showed the greatest inhibition effect on 2,2-diphenyl-1-picrylhydrazyl (DPPH) radical (p<0.05). In vitro digestion caused increase in the antioxidant activity of both CB and PB.     

Physical and mechanical properties of Gokceada: Imbros (NE Aegean Sea) Island andesites

The physical and mechanical properties of the andesite forming much of the island of Gökçeada (Imbros), Turkey, were investigated using 54 mm samples cores from 12 blocks obtained from a quarry. The results were evaluated using regression analysis and good empirical relationships were obtained.     

Solar and Net Radiation-Based Equations to Estimate Reference Evapotranspiration in Humid Climates

Two equations for estimating grass reference evapotranspiration (ET0) were derived using the Food and Agriculture Organization Penman–Monteith (FAO56-PM) method as an index. The first equation, solar radiation (Rs) based, estimates ET0 from incoming Rs and maximum and minimum air temperature, and the second equation, net radiation (Rn) based, uses Rn and maximum and minimum air temperature. The equations were derived using 15 years (1980–1994) of daily ET0 values estimated from the FAO56-PM method using the measured and carefully screened weather data from near Gainesville, Florida. The performance of the derived equations was evaluated for 6 validation years (1995–2000), including dry and wet years, for the same site and for other humid locations in the Southeast United States. Comparisons of the performance of the derived equations with the other commonly used methods indicated that they estimate ET0 as good or better than those other ET0 methods. The Rs- and Rn-based equations resulted in the lowest 6 year average standard error of estimate (SEE) of daily ET0 (0.44 and 0.41 mm?day?1, respectively). Both equations performed quite well for estimating peak month ET0 and had the lowest 6 year average daily SEE for the peak month ET0 (0.24 mm?day?1 for both equations). Estimates for annual total ET0 were very close to those obtained from the FAO56-PM method. The 6 year average ratio of ET0?method to ET0?FAO56-PM were 1.05 and 1.03 for the Rs- and Rn-based equations, respectively. The derived equations were further evaluated in other humid locations in the Southeast United States, including two locations in coastal regions in Florida, one location in Georgia, and another location in Alabama. The comparisons showed that both equations are likely to provide good estimates of ET0 in humid locations of the Southeast United States. When the required input variables are considered, the Priestley–Taylor (PT) method was the closest method to the second derived equation (Rn based). Therefore, it was necessary to evaluate how the PT method would perform compared to the Rn-based equation relative to the FAO56-PM method after it is calibrated locally. Although the performance of the PT method improved slightly after the calibration, its performances for estimating daily and peak month ET0 remained poorer than the Rn-based equation in all cases. Considering the limitations associated with the availability and reliability of the climatological data, especially in developing countries, the derived equations presented in this study are suggested as practical methods for estimating ET0 if the standard FAO56-PM equation cannot be used because of the above-mentioned limitations. These equations are recommended over the other commonly used simplified temperature and radiation-based methods evaluated in this study for humid climates in the Southeast United States.     

Some structural properties of CdO:F films produced by ultrasonic spray pyrolysis method

The fluorine doped cadmium oxide (CdO:F) samples have been deposited at 250 °C by ultrasonic spray pyrolysis method. Cadmiumacetat-dihydrat and ammonium fluoride have been taken as a source of cadmium and fluorine-dopant respectively. The thickness of the CdO:F samples was about 1.4 μm. X-ray diffraction pattern of the CdO:F samples has revealed that the samples are polycrystalline with cubic sodium chloride structure. There are shifts of the d values (interplanar spacing) for CdO:F samples with respect to standard CdO film. The lattice parameters for cubic structure have been calculated using the Bragg equation. The texture coefficients calculated for various planes at different fluorine concentrations indicate that the samples have exhibited (111) and (200) preferential orientations.