Diffusivity of small molecules in polymers: Carboxylic acids in polystyrene

Gravimetry was used to study the diffusion of a homologous series of linear carboxylic acids (C_n, with n = 2, 6–16) in amorphous polystyrene at temperatures from 35 °C to 165 °C, that is, both below and above the polymer glass transition temperature of 100 °C. All the mass uptake results are well described by a simple Fickian model (for t < t_1/2) and were used to calculate the corresponding diffusion coefficients using the thin-film approximation. Acetic acid exhibits a peculiar diffusion rate: its diffusion coefficients in polystyrene do not follow the same trend of all the remaining acids, being smaller than those of hexanoic acid at the same temperatures. Polystyrene swells at a higher rate in hexanoic and octanoic acids than in acetic acid, at the same temperature. This peculiarity is confirmed using NMR spectroscopy for acetic and hexanoic acids. For all the carboxylic acids considered, the temperature dependence of the diffusion coefficients is non-Arrhenius in character. For each liquid penetrant, its log(D) increases linearly with the decrease in liquid viscosity associated with an increase in temperature. Plots of log(n²D) versus n suggest that higher-n carboxylic acids diffuse through a reptation-like mechanism at higher temperatures.     

Site‐Controlled InGaAs Quantum Dots with Tunable Emission Energy

Semiconductor quantum‐dot (QD) systems offering perfect site control and tunable emission energy are essential for numerous nanophotonic device applications involving spatial and spectral matching of dots with optical cavities. Herein, the properties of ordered InGaAs/GaAs QDs grown by organometallic chemical vapor deposition on substrates patterned with pyramidal recesses are reported. The seeded growth of a single QD inside each pyramid results in near‐perfect (<10 nm) control of the QD position. Moreover, efficient and uniform photoluminescence (inhomogeneous broadening <10 meV) is observed from ordered arrays of such dots. The QD emission energy can be finely tuned by varying 1) the pyramid size and 2) its position within specific patterns. This tunability is brought about by the patterning of both the chemical properties and the surface curvature features of the substrate, which allows local control of the adatom fluxes that determine the QD thickness and composition.     

Telecommunications infrastructure and usage and the FDI–growth nexus: evidence from Asian-21 countries

ABSTRACT

This paper examines causal relationships between telecommunications infrastructure and usage (TEL), foreign direct investment (FDI), and economic growth in the Asian-21 countries for the period 1965–2012. TEL is defined in terms of the prevalence of telephone main lines, mobile phones, internet servers and users, as well as the extent of fixed broadband. These measures are considered both individually and collectively in the form of a composite index of TEL. We report results on long-run relationships between TEL, FDI, and economic growth. We also use a panel vector auto-regression model to reveal the nature of Granger causality among the three variables. Results from these causal relationships provide important policy implications to the Asian-21 countries.     

On the method of extraction of lumped parameters for the radiation impedance of complex radiator geometries

This work addresses the problem of finding expressions for the radiation impedance of a circular plate with cuts (holes + slits) and mounted in an infinite baffle. Due to the nontrivial nature of the structural geometry and the boundary conditions, analytical solution of the required Rayleigh integral is difficult for this case. The analysis in this case is carried out numerically using COMSOL Multiphysics. The air on top in contact with the vibrating plate, loads the plate with additional mass and also dissipates away energy depending on the frequency of vibration. The numerical solution obtained using FEA needs to be converted into suitable frequency based expressions. We use curve fitting to relate these radiation impedance values to an already reported equivalent circuit (for modeling the radiation impedance) in the literature. The detailed method of lumped parameter extraction, as well as the method of reduction of the circuit to its high and low frequency counterparts, is reported in this paper. The method described here is a generic one and can be used for any kind of geometry.     

Can-GLWS: Canadian Great Lakes Weather Service for the Soil and Water Assessment Tool (SWAT) modelling

The rapid rise in availability of large geospatial datasets for the development of hydrological models such as Soil and Water Assessment Tool (SWAT) has led to a dramatic increase in both the demand and availability of web services and tools that assist watershed modellers in incorporating data and knowledge into their modelling frameworks. Within the Canadian Great Lakes region, there is a huge potential for the application of SWAT in integrated water resources management. However, a potential barrier is the preparation of SWAT weather inputs that require time-intensive preprocessing of large data sets. Because such preprocessing is reproducible, the redundancy associated with it can be removed by introducing a web service that enables easy and open dissemination of climate data (including climate change and historical data) in SWAT-ready format. This short communication introduces such a web service called the Canadian Great Lakes Weather Data Service for SWAT (Can-GLWS). It hosts observed (historical) and projected (future) daily precipitation, daily maximum/minimum temperature, as well as weather generator database at regular grids (300 arc seconds or ~10 km) for use in SWAT simulations of the region. The novel Can-GLWS web service offers flexibility in selecting the region of interest by allowing them to be uploaded as a shapefile or to draw a rectangle or a polygon. We believe that such data as a service platform will help many practitioners to explore several issues pertaining to the sustainability of the freshwater resources of Canadian Great Lakes using the SWAT model.     

Pricing commodities

How should a seller price her goods in a market where each buyer prefers a single good among his desired goods, and will buy the cheapest such good, as long as it is within his budget? We provide efficient algorithms that compute near-optimal prices for this problem, focusing on a commodity market, where the range of buyer budgets is small. We also show that our LP rounding based technique easily extends to a different scenario, in which the buyers want to buy all the desired goods, as long as they are within budget.     

A study of performance and scalability metrics of a SIP proxy server – a practical approach

In recent years, Internet Protocol (IP) telephony has been a real alternative to the traditional Public Switched Telephone Networks (PSTN). IP telephony offers more flexibility in the implementation of new features and services. The Session Initiation Protocol (SIP) is becoming a popular signalling protocol for Voice over IP (VoIP) based applications. The SIP proxy server is a software application that provides call routing services by parsing and forwarding all the incoming SIP packets in an IP telephony network. The efficiency of this process can create large scale, highly reliable packet voice networks for service providers and enterprises. We established that the efficient design and implementation of the SIP proxy server architecture can enhance the performance characteristics of a SIP proxy server significantly. Since SIP proxy server performance can be characterised by its transaction states of each SIP session, we emulated the $M/M/1$ performance model of the SIP proxy server and studied some of the key performance benchmarks such as average response time to process the SIP calls, and mean number of SIP calls in the system. We showed its limitations, and then studied an alternative $M/M/c$ based SIP proxy server performance model with enhanced performance model and studied additional key performance characteristics such as server utilisation, queue size and memory utilisation. Provided the comparative results between the predicted results with the experimental results conducted in a lab environment.     

Techno-economic analysis of a local district heating plant under fuel flexibility and performance

Brovst is a small district in Denmark. This paper analyses the use of local renewable resources in the district heating systems of Brovst. The present use of fossil fuels in the Brovst district heating plant (DHP) represents an increasing environmental and climate-related load. Therefore, an investigation has been made to reduce the use of fossil fuels for district heating system and make use of the local renewable resources (biogas, solar, and heat pump) for district heating purposes. In this article, the techno-economic assessment is achieved through the development of a suite of models that are combined to give cost and performance data for this district heating system. Local fuels have been analyzed for different perspectives to find the way to optimize the whole integrated system in accordance with fuel availability and cost. This paper represents the energy system analysis mode, energyPRO, which has been used to analyze the integration of a large-scale energy system into the domestic district heating system. A model of the current work on the basis of information from the Brovst plant (using fossil fuel) is established and named as a reference option. Then, four other options are calculated using the same procedure according to the use of various local renewable fuels known as “biogas option,” “solar option,” “heat pump option,” and “imported heat option.” A comparison has been made between the reference option and other options. The greatest reduction in heat cost is obtained from the biogas option by replacing a new engine, where 66 % of the current fuel is substituted with biogas.