Myxobacteria ‐mediated synthesis of silver nanoparticles and their impregnation in wrapping paper used for enhancing shelf life of apples

The authors report Myxobacteria virescens (M. virescens) mediated synthesis of silver nanoparticles (AgNPs) and its efficacy against Staphylococcus aureus (ATCC‐33591), Salmonella typhi (ATCC‐51812), Escherichia coli (E. coli) (ATCC‐14948), Klebsiella pneumoniae (MTCC‐4030) and Pseudomonas aeruginosa (MTCC‐4673). The organism exhibiting resistance to various antibiotics showed remarkable sensitivity, when used in combination of antibiotics and AgNPs. Antimicrobial property of AgNPs is playing a significant role in medicine and food storage. In this study, they have used M. virescens for the synthesis of AgNPs, which were characterised by using UV‐Vis spectrophotometer, nano‐particles tracking and analysis, zeta potential, Fourier transform infrared spectroscopy, X‐ray diffraction and transmission electron microscopy. Synthesised AgNPs were impregnated into paper by three different methods, i.e. glass rod method (without binder), glass rod method (with binder) and direct synthesis of AgNPs on paper. Nanoparticles synthesis on paper showed the significant antimicrobial activity against Staphylococcus aureus (ATCC‐33591), Salmonella typhi (ATCC‐51812), E. coli (ATCC‐14948), Klebsiella pneumoniae (MTCC‐4030) and Pseudomonas aeruginosa (MTCC‐4673). Paper impregnated with AgNPs was used for wrapping of fruits (apples) which increases their shelf life up to 15 days. This study demonstrates a new method for wrapping of fruits, which increases the shelf life of apples.Inspec keywords: microorganisms, biotechnology, nanoparticles, wrapping, food packaging, antibacterial activity, ultraviolet spectra, electrokinetic effects, Fourier transform infrared spectra, X‐ray diffraction, transmission electron microscopy, food productsOther keywords: silver nanoparticles, wrapping paper impregnation, apple shelf life enhancement, Myxobacteria virescens mediated synthesis, glass rod method, transmission electron microscopy, X‐ray diffraction, Fourier transform infrared, zeta potential, nanoparticle analysis, nanoparticle tracking, UV‐Vis spectrophotometer, antimicrobial property, antibiotic resistance, MTCC‐4673, Pseudomonas aeruginosa, MTCC‐4030, Klebsiella pneumoniae, ATCC‐14948, E. coli, Escherichia coli, ATCC‐51812, Salmonella typhi, ATCC‐33591, Staphylococcus aureus, M. virescens mediated synthesis     

A novel method to detect the water leakage from tuyere nose cooling circuit in blast furnace

The water cooled tuyere noses, through which hot blast is blown into the furnace, are exposed to very high temperature region of raceway inside the furnace. As a result the chances of rupture of cooling pipes within the tuyere nose are significantly high. The rupture causes water dripping into the furnace and if it continues and unnoticed for a prolonged period it lowers down the local raceway temperature and thus adversely affects the product hot metal and slag quality. Moreover, with heavy water leakage, there is a danger of explosion; monitoring of the cooling water is therefore essential. Despite the availability of water flow metre at each tuyere it is difficult to identify the leaking tuyere at the early stage unless the rupture size grows bigger and so the leakage. In several cases the furnace is forced to shut down to manually inspect the leakage occurring without prior knowledge of the exact tuyere number. Identification of water leakage at an early stage is therefore necessary to prevent process disturbances due to chilling of the furnace and avoid the unscheduled downtime for tuyere replacement. This paper presents a method to identify the water leakage from tuyere nose cooling circuit in blast furnace and the adverse effect of water leakage on the performance of the blast furnace. A system called water leak detection system is developed for different blast furnaces in Tata Steel Jamshedpur to monitor the water leakage through tuyere nose and identify the exact leaking tuyere based on a dimensionless number called leak detection factor.     

Indoor simulation and testing of photovoltaic thermal (PV/T) air collectors

An indoor standard test procedure has been developed for thermal and electrical testing of PV/T collectors connected in series. For this, a PV/T solar air heater has been designed, fabricated and its performance over different operating parameters were studied. Based on the energy balance equations, in a steady state condition, a thermal model has been developed. Comparison between experimental and theoretical results were also been carried out. The thermal and electrical efficiency of the solar heater is 42% and 8.4%, respectively. This test procedure can be used by manufacturers for testing of different types of PV modules in order to optimize its products.     

Reduction of emissions in a biodiesel‐fueled compression ignition engine using exhaust gas recirculation and selective catalytic reduction techniques

This paper analyzes the emissions of a single‐cylinder diesel engine fueled with biodiesel, using selective catalytic reduction (SCR) and exhaust gas recirculation (EGR) techniques. The aim of this paper is to compare both EGR and SCR techniques, which were studied under different brake powers. Grape seed biodiesel was used as a test fuel. Experiments were performed by both techniques at different loads and rates to find out the performance change in the engine and the change in the emission rates using both the techniques. Then the observations from both the techniques were compared, concluding that both the techniques show a sufficient reduction in NOx. Using the abovementioned techniques, a reduction in hydrocarbon (HC), carbon monoxide (CO), carbon dioxide (CO₂), nitrogen oxides (NOx), and smoke was observed. The EGR technique is more suitable for low‐load engine vehicles, as it affects the efficiency of the engine with an increase in the fuel consumption, whereas the SCR technique is suitable for high‐load engines, which do not affect the efficiency of the engine with a decrease in the fuel consumption.     

Morphology,mechanical, and physical properties of wet-spun cellulose acetate fiber in different solvent-coagulant systems and in-situ crosslinked environment

Wet spinning is a popular fiber manufacturing process where the effects of solvent and coagulant on the wet-spun fiber are significant. In this study, we have explored the effect of solvent-coagulant interaction and in-situ crosslinking on the wet-spun cellulose acetate (CA) fiber. Investigation on 12 different solvent-coagulant systems revealed that variation in the systems resulted in significant variance in morphology and mechanical property of the fiber. Remarkable increase in mechanical property was observed after in-situ crosslinking with citric acid and polyethylene glycol (PEG). Inclusion of sodium hypophosphite (NaH₂PO₂) as catalyst further increased tensile modulus (~407%) and crystallinity index (~46%) compared to CA fiber crosslinked with only citric acid. It was established that fiber from CA-DMSO solution crosslinked with 10% citric acid and 10% PEG extruded in ethanol showed the highest tensile modulus (~30 MPa). This in-depth study found an appropriate combination of solvent-coagulant for forming stable CA fiber, with the addition of crosslinkers and catalyst further increasing the strength and usability of the fiber.     

Real-time blast furnace hearth liquid level monitoring system

A stable and efficient blast furnace operation requires proper control of hot metal and slag drainage from the hearth. Many operational problems such as non-dry casts, blow outs, excessive hearth lining wear and low-blast intake arise when the liquid level in the hearth exceeds the critical limit where hearth coke and deadman start to float. Since the direct measurement of the hearth liquid level is practically impossible due to high temperature and pressure inside the furnace, it is therefore important to estimate the liquid level in the hearth and display it to the operators on real-time basis for efficient cast management. This paper presents a system, called hearth liquid level monitoring (LLM), which simulates the liquid level and drainage behaviour of the furnace hearth. It is based on the theoretical hot metal and slag generation rate from the specific oxygen rate and the computed drainage rate from torpedo radar signals and the slag flow measurement system. The system advises the blast furnace operator when to initiate tapping and close the taphole when the liquid level is controlled. It also alerts operators when to use the larger drill bit diameter for opening the next cast.     

Quality by design approach for development of suspension nasal spray products: a case study on budesonide nasal suspension

The objective of this study was to provide quality by design (QbD) approach for development of suspension type nasal spray products. Quality target product profile (QTPP) of test product budesonide nasal suspension (B-NS) was defined and critical quality attributes (CQAs) were identified. Critical formulation, process and delivery device variables were recognized. Risk assessment was performed by using failure mode and effect analysis (FMEA) methodology. Selected variables were further assessed using a Plackett Burman screening study. A response surface design consisting of the critical factors was used to study the interactions between the study variables. Formulation variable X₂: median particle size of budesonide (D₅₀) (µ) has strikingly influenced dissolution (%) (Y₁), while D₅₀ droplet size distribution (µm) (Y₂) was significantly impacted by formulation variable X₁: Avicel RC 591 (%) and process variable X₄: homogenization speed (rpm). A design space plot within which the CQAs remained unchanged was established at lab scale. A comprehensive approach for development of B-NS product based on the QbD methodology has been demonstrated. The accuracy and robustness of the model were confirmed by comparability of the predicted value generated by model with the observed value.     

Optimisation of vertical axis wind turbine: CFD simulations and experimental measurements

A system for the conversion of kinetic energy of wind into thermal energy has been developed which can replace relatively expensive electro‐mechanical equipment. The system consists of a vertical axis wind turbine (VAWT) which is coupled with the shaft of a stirred vessel. In the present work, computational fluid dynamic (CFD) simulations have been performed for the flow generated in a stirred tank with disc turbine (DT). The predicted values of the mean axial, radial and tangential velocities along with the turbulent kinetic energy have been compared with those measured by laser Doppler anemometry (LDA). Good agreement was found between the CFD simulations and experimental results. Such a validated model was employed for the optimisation of drag‐based VAWT. An attempt has been made to increase the efficiency of turbine by optimising the shape and the number of blades. For this purpose, the combination of CFD and experiments has been used. The flows generated in a stirred tank and that generated by a wind turbine were simulated using commercial CFD software Fluent 6.2. A comparison has been made between the different configurations of wind turbines. Results show that a provision in blade twist enhances the efficiency of wind turbine. Also, a wind turbine with two blades has higher efficiency than the turbine with three blades. Based on the detailed CFD simulations, it is proposed that two bladed turbine with 30° twist shows maximum efficiency. © 2011 Canadian Society for Chemical Engineering