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排序方式: 共有381条查询结果,搜索用时 31 毫秒
31.
Daisuke Saio Toru Amaya Toshikazu Hirao 《Advanced Synthesis \u0026amp; Catalysis》2010,352(13):2177-2182
The hybrid consisting of gold nanoparticles and poly(2‐methoxyaniline‐5‐sulfonic acid), which works as a redox mediator for transferring protons and electrons, catalyzed the oxidation reaction of various alcohols in water under molecular oxygen. 相似文献
32.
Daisuke Kosemura Maki Hattori Tetsuya Yoshida Toshikazu Mizukoshi Atsushi Ogura 《Journal of Electronic Materials》2010,39(6):694-699
Defects and stress gradually accumulate throughout various Si large-scale integration fabrication processes. It is essential
to monitor defects and stress carefully to suppress their unintentional introduction. In this study, we measured the stress
and crystal quality in shallow trench isolation (STI) samples by ultraviolet (UV)-Raman spectroscopy with an extremely high-resolution
wavenumber to evaluate the effect of post-annealing on the recovery of Si crystals. The variations of crystal quality in 200-mm
wafers with STI structures gradually decreased after post-annealing for 4 h, 6 h, and 8 h; however, there was no substantial
difference in the values of full-width at half-maximum of the Raman spectra. Precise measurements of variations of stress
and crystal quality were successfully performed by UV-Raman spectroscopy with a high-resolution wavenumber, which enabled
us to evaluate the STI process accurately. 相似文献
33.
Ichihashi H Kohno H Kannan K Tsumura A Yamasaki SI 《Environmental science & technology》2001,35(15):3103-3108
Forty-four elements were analyzed in 21 tissues of purpleback flying squid, Sthenoteuthis oualaniensis, by high resolution inductively coupled plasma-mass spectrometry (HR ICP-MS) and inductively coupled plasma atomic emission spectrophotometry (ICP-AES). Greater concentrations of V, Fe, Co, Ni, Cu, Ag, Cd, Pb, and Bi were found in liver, pancreas, and ink sac than in other tissues. Ink sac concentrated remarkable levels of Ca and Sr in addition to the above-mentioned elements. Several alkalis, alkaline earth, and rare earth elements preferentially accumulated in muscle. Among the hard tissues, accumulation of V and U in beak, Ni, Zn, and Cd in gladius and Cr in skin was prominent. K, Rb, Cs, Pb, Bi and some transition elements (V, Co, Cu, Zn, Ag, Cd) were significantly (p < 0.05) higher in the livers of adult than in juvenile squids. Sodium, alkaline earth, and rare earth elements were higher in the livers of juveniles than in adult squids. 相似文献
34.
Jing C. Zhou Xianghuai Wang Mei Xue Zheng Xu Toshikazu Hamasaki Yang Yang Kang Wang Bruce Dunn 《Materials science & engineering. C, Materials for biological applications》2010,30(1):20-26
Microtubule (MT) protein filaments were used as templates for fabricating Au nanowires as a bottom-up approach for fabricating building blocks for future integrated circuits. Photochemical reduction methods were employed to form Au nanoparticles which bind and uniformly cover the MT filaments. Synthesis of the MT-templated Au nanowires was characterized using UV/vis spectroscopy and transmission electron microscopy (TEM). In addition, binding between the MT filaments and Au nanoparticles was investigated using surface enhanced Raman spectroscopy (SERS) and X-ray photoelectron spectroscopy (XPS) to establish the nature of the binding sites. A variety of functional groups were identified by SERS to interact with the Au including imidazole, sulfur, aromatic rings, amine, and carboxylate. The imidazole ring in the histidine is the most prominent functional group for Au binding. The results from these studies provide better understanding of the binding between Au and the biotemplate and give insight concerning methods to improve Au coverage for MT-templated Au nanowires. 相似文献
35.
36.
The effect of aluminium on the polymerization of silicic acid was studied at pH 7, 8 and 9 in the aluminium concentration range of 0–26 ppm (Al) by spectrophotometry, gel chromatography and 27Al NMR. Retarding and accelerating effects of aluminium on the growth of polysilicic acid particles and on the reaction between monosilicic acid and polysilicic acid were observed by changing the pH. It is suggested that the accelerating effect on the reaction between polysilicic acid particles is due to the formation of aluminium hydroxide on the surface of polysilicic acid. The rate of decrease in the monosilicic acid concentration in the presence of aluminium was faster than that in the absence of aluminium at pH 9, because monosilicic acid could be adsorbed rapidly on the aluminium hydroxide. From the results it was presumed that the formation of aluminium hydroxide on the solid surface may accelerate the deposition of silicic acid from geothermal water. 相似文献
37.
Shin’ichi Konno Shigeo Kazama Maki Hiraoka Hirokazu Sakamoto Kenji Mizoguchi Hiromi Taniguchi Toshikazu Nakamura Kou Furukawa 《Journal of Low Temperature Physics》2006,142(3-4):621-624
β′-(BEDT-TTF)(TCNQ) is a compound of BEDT-TTF (=ET) and TCNQ molecules aligned orthogonally with each other, forming two-dimensional
sheets and one-dimensional columns of 1/4-filled π band, respectively. It is known that the metal-insulator transition occurs
at 330 K at ambient pressure. We have measured the electronic spin susceptibility by means of the EPR-NMR method at 50 MHz,
and the angular dependence of g-factor and line width of EPR both at Q (34 GHz) and W (94 GHz) band. We successfully confirmed
that the antiferromagnetic transition occurs in ET sheets and TCNQ columns, independently. 相似文献
38.
Thermoplastics such as cyclic olefin copolymer (COC) and polymethylmethacrylate (PMMA) have been increasingly used in fabricating microfluidic devices. However, the state-of-the-art microvalve technology is a polydimethylsiloxane (PDMS)-based three-layer structure. In order to integrate such a valve with a thermoplastics-based microfluidic device, a bonding method for thermoplastics/PDMS must be developed. We report here a method to bond COC with PDMS through surface activation by corona discharge, surface modification using 3-(trimethoxysilyl)propyl methacrylate (TMSPMA), and thermal annealing. The method is also applicable to PMMA. The bonding strength between thermoplastics and PDMS was represented by the peeling force, which was measured using a method established by the International Organization for Standardization (ISO). The bonding strength measurement offered an objective and quantitative indicator for protocol optimization, as well as comparison with other PDMS-associated bonding methods. Using optimized bonding conditions, two valve arrays were fabricated in a COC/PDMS/COC device and cyclic operations of valve closing/opening were successfully demonstrated. The valve-containing devices withstood 100 psi (~689 KPa) without delamination. Further, we integrated such valve arrays in a device for protein separation and demonstrated isoelectric focusing in the presence of valves. 相似文献
39.
Toshikazu Hori Yoshiyuki Mohri Yuji Kohgo Kenichi Matsushima 《Soils and Foundations》2011,51(1):53-66
Failures of earth dam embankments and river dikes, which are constructed of sandy soils with low dry densities, have been observed to occur during rising of water levels. In this paper, a large-scale physical model test was conducted in order to investigate the behavior of a small dam embankment as water levels rose. The test results were simulated by use of a consolidation analysis method coupled with an elastoplastic model for unsaturated soils. All parameters used in the simulation were obtained from element tests; oedometer, triaxial compression, soil water retention, and permeability tests. First, in order to verify the parameters identified, direct shear tests were simulated using the consolidation analysis method; results of the simulation and the tests were consistent. From the embankment model test it was found that the crest of the embankment moved upstream at the first stage of impounding and then moved back. After a seepage surface appeared on the downstream slope, tension cracks occurred on the downstream slope, and sliding occurred through the crack and the downstream toe. The results of the simulation were consistent with those of the model test. This consolidation analysis method could be used to simulate the complex deformations induced by saturation collapse and shear strains and even failure behavior. Old embankments constructed with loose densities might have histories in which cracks occurred on the downstream slopes when the reservoir water level rose, and their stabilities might have decreased. 相似文献
40.
Lihe Qian Hiroyuki Toda Toshikazu Akahori Mitsuo Niinomi Toshiro Kobayashi Seishi Nishido 《Metallurgical and Materials Transactions A》2005,36(11):2979-2992
Hypoeutectic Al-Si alloys consist of primary α-Al and Al-Si eutectic phases and show typical elasticplastic fracture. To understand their fracture behavior, fracture processes
were simulated using an elastic-plastic finite-element method. The validity of the J-integral-based criterion was verified and applied to the simulations. A complicated model was used to simulate the fracture
in an idealized dendritic microstructure, and four simplified models were intended to more clearly understand the interaction
between a crack and individual α phases. Results show that the crack is attracted to the soft α phase when passing by the α phase, whereas it is repelled when the α phase is close in front of or behind the crack tip. The presence of α phase close in front of or behind the crack tip leads to an amplification of the driving force. However, the α phase beside the tip reduces the driving force. Furthermore, the fracture behavior is mainly affected by the adjacent α phase on one side around the crack tip, while the remote α phase on the opposite side has an offsetting effect. The local stress-strain fields were examined to analyze the simulated
behavior. The simulated crack-growth path in the dendritic model was compared and verified with the experimentally observed
path. 相似文献