Structural transition of a homopolymer in solvents mixture

The present work is aimed at studying the thermodynamic behaviour of a polymer in solvents mixture. Dynamic light scattering is used to measure the hydrodynamic radius of polyvinylpyrrolidone (M_w = 360,000 g/mol), in water/methanol solvents mixture, versus the mixed solvents composition at 25 °C. Then, we show that the polymer conformation adopts the Coil–Globule–Coil structure when the methanol molar fraction X_A is varied. This transition is attributed to solvent quality change which result from water and methanol complex formation. The polymer contraction rate calculated for each composition takes its maximum value at X_A = 0.17. Hildebrand theory assuming the solvents mixture as an equivalent solvent was used to analyze the change in mixed solvents quality. These changes can be attributed to dispersive forces in solvents mixture.     

At-Rest Earth Pressure of Overconsolidated Cohesionless Soil

Earth pressure theories occupy a paramount position in the field of geotechnical engineering. An experimental investigation of the at-rest earth pressure of overconsolidated cohesionless soil acting on retaining walls was conducted. A prototype model of a vertical rough wall, retaining horizontal backfill, was developed in the laboratory. The model was instrumented to measure the earth pressure at selected points on the wall, the total earth force acting on the wall, and the overconsolidation ratio (OCR) in the sand mass. Tests were conducted on walls retaining homogeneous overconsolidated dense, medium, or loose sands. Test results showed that the coefficient of at-rest earth pressure increases with the increase of the OCR. The present experimental results were used to examine the empirical formulas available in the literature. It can be reported that these formulas compared well with the experimental results for OCR values up to 3. An empirical formula is proposed to predict the coefficient of at-rest earth pressure for overconsolidated cohesionless soils. The results obtained by this formula agreed well with the present experimental results for all values of overconsolidation ratios.     

Polymer complexes. XXXI. Potentiometric and thermodynamic studies of 2‐acrylamido‐2‐amino‐3‐hydroxy pyridine and its metal complexes

Proton ligand dissociation and metal ligand stability constants of 2‐acrylamido‐2‐amino‐3‐hydroxy pyridine (AAHP) with some transition metal ions in 0.1 M KCl and 50% (v/v) ethanol–water mixture were calculated potentiometrically. In the presence of 2,2′‐azobisisobutyronitrile as initiator the proton‐polymeric ligand dissociation and metal polymeric ligand stability constants were also evaluated. The influence of temperature on the dissociation of AAHP and the stability of its metal complexes in the monomeric and polymeric forms were critically studied. On the basis of the thermodynamic functions, the dissociation process of AAHP was found nonspontaneous, endothermic, and entropically unfavorable, although the formed metal complexes showed spontaneous, endothermic, and entropically favorable behavior. © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 77: 2552–2557, 2000     

Design of High Speed AWGN Communication Channel Emulator

This paper presents a method for designing a high accuracy white gaussian noise generator suitable for communication channel emulation. The proposed solution is based on the combined use of the Box-Muller method and the central limit theorem. The resulting architecture provides a high accuracy AWGN with a low complexity architecture for a digital implementation in FPGA. The performance is studied by means of MATLAB simulations and various complexity figures are given.     

Elastic Constants of Erbia Single Crystals

The elastic properties of single-crystalline erbia (Er₂O₃) at room temperature have been investigated using resonant ultrasound spectroscopy. The three independent stiffness constants of anisotropic Er₂O₃ cubic type-C crystals have been measured. The values of the stiffness constants were c ₁₁= 256.4 GPa, c ₁₂= 146.8 GPa, and c ₄₄= 75.2 GPa. From the stiffness constants, the estimated values for dense polycrystalline erbia for Young's modulus, the shear modulus, the bulk modulus, and Poisson's ratio at room temperature were 179 GPa, 67 GPa, 183.3 GPa, and 0.337, respectively. The value of Young's modulus is a minimum along [001] and a maximum along [111]. The value of the shear modulus is independent of the direction in the (001) and (111) planes, whereas it decreases in (11¯0) from 75 GPa along [001] to 55 GPa along [110].     

Feasibility and performance evaluation of a 6LoWPAN‐enabled platform for ubiquitous healthcare monitoring

Technology has revolutionized medical practices by enabling more convenient and non‐intrusive monitoring of patient's health, leading to next generation ubiquitous healthcare (u‐healthcare). The exploitation of the Internet protocol version 6 addressing space along with the miniaturization of electronic devices has fostered providing interoperability and connectivity of wearable sensor devices in wireless body area networks to the Internet of Things. In this paper, we propose to integrate the IPv6 over low power wireless personal area network (6LoWPAN) to the u‐healthcare monitoring system architecture. The main objective is to study the feasibility of the 6LoWPAN‐enabled platform in real‐world scenarios dealing with medical data. The performance evaluation of this platform is carried out initially through simulations using OMNet++ and then supported by an experimental study using sensor motes and a customized micro‐computing unit. Performance metrics such as throughput, end‐to‐end delay, packet error rate, and energy consumption are investigated under acute health conditions, where patient's health information has to be sent continuously and at maximum rate to the care provider. The obtained results show that the proposed 6LoWPAN solution fulfills the main quality of service requirements of u‐healthcare applications. Copyright © 2015 John Wiley & Sons, Ltd.     

133Cs and 23Na MAS NMR Spectroscopy of Molybdate Crystallization in Model Nuclear Glasses

Sodium borosilicate base glasses modeled on French nuclear waste materials were prepared to test the dependence of crystallization product quantity and distribution on cesium‐ and molybdenum‐loading and glass cooling rate. Scanning electron microscopy shows the presence of micrometer‐sized domains of Mo‐rich crystalline precipitates. X‐ray diffraction patterns are complex but reveal the presence of sodium molybdates and CsNaMoO₄·2H₂O. ¹³³Cs and ²³Na magic‐angle spinning NMR spectroscopy exhibit distinct peaks for glassy and crystalline phases which can be quantified to obtain the identities of the individual compounds that are formed as well as the fractions of these nuclei in particular crystalline phases. In these model systems, 1 mol% Mo can be entirely incorporated into the glassy network whereas 2.5 and 5 mol% Mo produce significant quantities of crystalline phases, with little dependence on cooling rate. Cesium content appears to have a weak influence on crystallization behavior. Sodium molybdate and sodium‐cesium molybdate hydrate are the dominant devitrification phases in all cases.     

Production of a halotolerant lipase from Halomonas sp. strain C2SS100: Optimization by response-surface methodology and application in detergent formulations

The aim of this work was to optimize the production of a new lipase by a halotolerant bacterial strain Halomonas sp. C2SS100, by means of the response-surface methodology (RSM). The process parameters having the most significant effect on lipase production were identified using the Plackett–Burman screening design-of-experiments. Then, Box–Behnken design was applied to optimize lipase activity and the quadratic regression model of the lipase production was built. Indeed, the lipase yield was increased, and the value obtained experimentally (39 ± 2 U/ml) was very close to the rate predicted by the model (40.3 U/ml). Likewise, optimization of parameters by RSM resulted in 2.78-fold increase in lipase activity. These findings provide the first report on lipase production and optimization by a halotolerant bacterial strain belonging to Halomonas genus. Afterward, the biochemical properties of the produced lipase were studied for apply in oil stains removal. The crude lipase showed a maximum activity at 60°C and at pH ranging from 7 to 10. It displayed an important stability at high temperature, pH, and NaCl. Interestingly, this bacterial lipase exhibited a prominent stability toward some commercial solid and liquid detergents after 30 min of incubation at 50°C. The capability of the crude lipase to eliminate stain was ascertained on polycotton fabric pieces stained with lubricating oil. Whether with the addition of hot water alone or of a commercially available detergent, lipase is able to considerably boost the elimination of oil stains. The actual findings highlight the capacity of Halomonas sp. lipase for energy-efficient biocatalytic application.