Antioxidant activity and protective effect against plasmid DNA strand scission of leaf, bark, and heartwood extracts from Acacia catechu

The antioxidant activity of methanol extract/fractions of leaf, bark, and heartwood of Acacia catechu was evaluated by various antioxidant assays, including free radical, superoxide and hydroxyl radical, reducing power, metal ion chelation, as well as hydroxyl radical induced DNA strand scission. The leaf, bark, and heartwood powder was extracted in methanol and the lyophilized methanol extract was fractionated with different solvents in the order of increasing polarity. The results indicate that ethyl acetate fraction of heartwood has the highest antioxidant capacities, presenting lower EC(50) values particularly in free radical scavenging activity, including DPPH radicals (4.76 ± 0.14 μg/mL), superoxide anions (26.21 ± 0.79 μg/mL), and hydroxyl radicals (33.69 ± 1.42 μg/mL), in direct assay systems. Reducing power was also highest in ethyl acetate fraction of heartwood (EC(50) of 79.05 ± 1.02 μg/mL). As for the chelating power on ferrous ions, leaf extract was more effective than bark and heartwood extracts. Furthermore, the ethyl acetate and acetone fractions of heartwood significantly protected pBR322 supercoiled plasmid DNA against strand scission induced by hydroxyl radicals in a Fenton's reaction mixture. PRACTICAL APPLICATION: The present investigation suggests that the three organs of A. catechu differ significantly in their antioxidant potential as seen in the DPPH radical scavenging assay, reducing power assay, metal ion chelating assay, superoxide radical scavenging assay and hydroxyl radical scavenging assay. Further, our results showed that crude methanol extract and ethyl acetate fraction of heartwood of A. catechu might have a good potential as a source for natural health products due to its antioxidant and DNA protective activities.     

Significance of Hall effect on heat and mass transport of titanium alloy-water-based nanofluid flow past a vertical surface with IMF effect

In this mathematical presentation, we examined the significance of Hall current on MHD buoyancy-driven boundary layer flow of a Ti₆Al₄V-H₂O based nanofluid past a vertical surface implanted in a uniform permeable region. The vertical surface is considered to be magnetized and induced magnetic field (IMF) impacts are also considered. The nondimensional flow model is solved with the assistance of the two-term perturbation scheme. Various results are obtained by numerical computation for different significant parameters. These results are presented and analyzed in graphical and tabular form. In the boundary layer domain, the transpiration velocity across the surface tends to diminish the main flow, IMF along the main flow, fluid temperature, and concentration. It is remarkably noted that IMF along the main flow grows for incrementing values of volume fraction coefficient of nanofluid. In the magnetic boundary layer domain, the main flow and IMF along the main flow grow with Hall current. Furthermore, it is seen that for the progressing values of magnetic Prandtl number, the main flow reduces while normal flow and IMF along the main flow is induced in the boundary layer domain.     

Application of response surface methodology to optimize diesel engine parameters fuelled with pongamia biodiesel/diesel blends

ABSTRACT

In the present scenario, the rate of fossil fuel consumption is very high and increasing rapidly which lead to a further increase in air pollution levels. Due to an increase in pollution level, researchers are striving to discover some cleaner and environment-friendly fuels for the diesel engines. This study was focused on the optimization of the input parameters of the diesel engine running on pongamia biodiesel for improvement in the engine performance. The input parameters selected for optimization were fuel injection pressure, fuel injection timing, pongamia biodiesel blends, and engine load with respect to BTE, BSFC, exhaust gas temperature, and P_max. An experimental analysis was performed according to the response surface methodology technique. The best engine input parameters setting for getting optimum performance was found at fuel injection timing 25 bTDC, fuel injection pressure 226 bar, 40% of pongamia biodiesel blending, at 74% of maximum rated engine load. Experimental and optimized results of the output responses at optimum input parameters were compared and found in the suggested error range.     

Electricity generation using solar parabolic dish system with thermoelectric generator—An experimental investigation

The present electricity grid installation cost as well as the tariff is quite high in India, particularly remote rural areas, to electrify houses. These problems can be easily solved by installing standalone systems that operate on one of the clean energy sources such as solar energy. An experimental analysis of generating electricity from a thermoelectric generator (TEG) powered by a solar parabolic dish concentrator device with aperture area and focal length of 12.6 m² and 2.42 m, respectively, is presented in this article. A TEG is made up of a thermoelectric module connected to a flat receiver by an absorber layer. The studies were carried out in Indian climatic conditions at the National Institute of Technology, Puducherry. Over a spectrum of beam radiation, the system's maximum energy conversion efficiency, as well as efficient electrical output, are evaluated and presented. The proposed system's average effective electrical efficiency is 0.424%, corresponding to the TEG's average energy conversion efficiency of 2.76%.     

Heat and mass transport performance of MHD elastico-viscous fluid flow over a vertically oriented magnetized surface with magnetic and thermo diffusions

The key objective in this study is to examine the heat and mass transport behavior of magnetohydrodynamic elastic-viscous fluid flow over a vertically oriented magnetized surface placed in a uniform permeable regime with magnetic and thermo diffusions. The fluid is partially ionized and permeated to flow in the presence of a strong magnetic field domain. Hence the Hall current effect is considered in this investigation. The significance of rotation and induced magnetic field on the flowing nature are also scrutinized in this study. The mathematical model of the problem is converted to a similar model by introducing suitable nondimensional variables. To obtain the closed-form solutions of the flow leading equations, the regular perturbation analysis is utilized. For the exhibition of results, figures and tables are generated with the assistance of scientific computation software MATHEMATICA. Computed results are validated with the existing result in the limiting case. Such an investigation is important in evaluating the flow characteristics of low magnetic diffusive viscoelastic fluid. A noteworthy result seen is that magnetic diffusion significantly controls the fluid flow by altering the magnetic drag force. Mass diffusion factor brings an increase in the fluid velocity. Furthermore, we observed that the surface current density along the principal flow direction is significantly reduced by magnetic diffusion and mass diffusion factor.     

Experimental and Morphological Investigations Into Electrical Discharge Surface Grinding (EDSG) of 6061Al/Al2O3p 10% Composite by Composite Tool Electrode

In this study, a special experimental setup of EDSG using EDM and surface grinding machine has been developed in the laboratory to investigate the effect of seven input parameters namely tool polarity, peak current, pulse on-time, pulse off-time, rotational speed, abrasive particle size, and abrasive particle concentration on material removal rate (MRR) as performance measure of the process. The novelty of the present research work is that successful efforts have been made to machine the 6061Al/Al₂O_3p 10% metal matrix composites (MMC) by composite tool itself. The copper-based composite tool electrodes were fabricated by powder metallurgy route with different sizes of abrasives of silicon carbide, while 6061Al/Al₂O_3p 10% MMC were fabricated through stir-casting process. The research outcome will identify the important parameters and their effect on MRR of 6061Al/Al₂O_3p 10% composite in EDSG. The experimental results reveal that tool polarity, peak current, and rotational speed are the most influential parameters that affect MRR in EDSG process. The micro-structural and morphological analysis of machined surfaces has also been carried out to analyze the surface topography. It has been concluded that the abrasive particles substantially improves the MRR after removing the resolidified layer from the machined surface.     

Synthesis and Characterization of Silver Nanoparticles and Silver Inks: Review on the Past and Recent Technology Roadmaps

The synthesis of silver nanoparticles for silver ink formation has attracted broad interest in the electronic part printing and semiconductor chip industry due to the extraordinary electrical and mechanical properties of these materials. The preparation of silver nanoparticles through a physical or chemical reduction process is the most common methodology applied to obtain nanoparticles with the required size, shape and surface morphology. The chemical solution or solvent carrier applied for silver ink formulation must be applied simultaneously with the direct writing technique to produce the desired adherence, viscosity, and reliable performance. This review paper discusses the details concerning the past and recent advancement of the synthesis and characterization of silver nanoparticles and silver ink formation. A review on the advantages of various sintering techniques, which aim to achieve the electrical and mechanical properties of the required printed structure, is also included. A brief summary concerning the recent challenges and improvement approaches is presented at the end of this review.     

Corrosion Behavior of Bare,Cr3C2-25%(NiCr), and Cr3C2-25%(NiCr)+0.4%CeO2-Coated Superni 600 Under Molten Salt at 900 °C

Cr₃C₂-25(NiCr) and Cr₃C₂-25(NiCr)+0.4%CeO₂ coatings were deposited on nickel-based superalloy Superni 600 by Detonation-gun technique. Studies were conducted on bare and coated alloys in molten salt environment (Na₂SO₄-25%NaCl) at 900 °C under cyclic condition. Characterization of the corrosion product was done using field emission scanning electron microscopy/energy dispersive spectroscopy and x-ray diffraction techniques. The bare Superni 600 shows penetration of corrosion beneath the metal layer thereby indicating internal oxidation. The coating of Cr₃C₂-25(NiCr) with 0.4%CeO₂ leads to the formation of adherent scale.