The occurrence of perchlorate during drinking water electrolysis using BDD anodes

Electrochemical studies were carried out to estimate the risks of perchlorate formation in drinking water disinfected by direct electrolysis. Boron Doped Diamond (BDD) anodes were used in laboratory and commercially available cells at 20 °C. The current density was changed between 50 and 500 A m⁻². For comparison, other anode materials such as platinum and mixed oxide were also tested. It was found that BDD anodes have a thousandfold higher perchlorate formation potential compared with the other electrode materials that were tested. In long-term discontinuous experiments all the chloride finally reacted to form perchlorate. The same result was obtained when probable oxychlorine intermediates (OCl⁻, ClO₂⁻, ClO₃⁻) were electrolysed in synthetic waters in the ppm range of concentrations. The tendency to form perchlorate was confirmed when the flow rate of drinking water was varied between 100 and 300 L h⁻¹ and the temperature increased to 30 °C. In a continuous flow mode of operation a higher chloride concentration in the water resulted in a lower perchlorate formation. This can be explained by reaction competition of species near and on the anode surface for experiments both with synthetic and local drinking waters. It is concluded that the use of electrodes producing highly reactive species must be more carefully controlled in hygienically and environmentally oriented applications.     

Investments into forest biorefineries under different price and policy structures

Increasing scarcity of oil reserves and the high CO₂ emissions from using oil have contributed to the development of renewable biofuels. Pulp and paper mill integrated forest biorefineries offer one important means to increase biofuel production. This study analyzes the effects of policies to support biofuel production in the pulp and paper sector. We study the relative effectiveness of three biofuel supporting policy instruments, namely production subsidy, input subsidy and investment subsidy. We present a partial equilibrium pulp and paper market model with a biorefinery investment option. A numerical model is used to evaluate the impacts of policy instruments on wood prices, as well as input choices and investment strategies of pulp and paper industries. The data represent the Finnish pulp and paper sector. We evaluate the values and direct costs of the policy instruments in a situation of exogenous biofuel production targets. The direct costs of input and investment subsidies are higher than those of a production subsidy. With all the policy instruments, Finnish pulp and paper mills would invest in wood-gasifying technology, instead of black liquor based one. The number of biorefinery units is dependent on the subsidy type — investment and input subsidies are likely to result in more numerous but smaller biofuel production units than a production subsidy. With all the policy instruments the demand for wood increases in Finland leading to higher wood prices. This, in turn, could reflect negatively on the profitability of the pulp and paper industries. To a significant degree, the model and the results can be generalized to other countries and markets where integrated pulp and paper mills are operating.     

An analysis of hydrogen production from renewable electricity sources

Three aspects of producing hydrogen via renewable electricity sources are analyzed to determine the potential for solar and wind hydrogen production pathways: a renewable hydrogen resource assessment, a cost analysis of hydrogen production via electrolysis, and the annual energy requirements of producing hydrogen for refueling. The results indicate that ample resources exist to produce transportation fuel from wind and solar power. However, hydrogen prices are highly dependent on electricity prices. For renewables to produce hydrogen at $2 kg⁻¹, using electrolyzers available in 2004, electricity prices would have to be less than $0.01 kWh⁻¹. Additionally, energy requirements for hydrogen refueling stations are in excess of 20 GWh/year. It may be challenging for dedicated renewable systems at the filling station to meet such requirements. Therefore, while plentiful resources exist to provide clean electricity for the production of hydrogen for transportation fuel, challenges remain to identify optimum economic and technical configurations to provide renewable energy to distributed hydrogen refueling stations.     

Heterogeneous oligonucleotide-hybridization assay based on hot electron-induced electrochemiluminescence of a rhodamine label at oxide-coated aluminum and silicon electrodes

This paper describes a heterogeneous oligonucleotide-hybridization assay based on hot electron-induced electrochemiluminescence (HECL) of a rhodamine label. Thin oxide-film coated aluminum and silicon electrodes were modified with an aminosilane layer and derivatized with short, 15-mer oligonucleotides via diisothiocyanate coupling. Target oligonucleotides were conjugated with tetramethylrhodamine (TAMRA) dye at their amino modified 5′ end and hybridization was detected using HECL of TAMRA. Preliminary results indicate sensitivity down to picomolar level and low nonspecific adsorption. The sensitivity was better on oxide-coated silicon compared to oxide-coated aluminum electrodes and two-base pair mismatched hybrids were successfully discriminated. The experimental results presented here might be useful for the design of disposable electrochemiluminescent DNA biosensors.     

An interconnected 2D-TM EBG structure for millimeter and submillimeter waves

Due to their unique properties, electromagnetic bandgap (EBG) materials are of high interest for applications in communication technology for many frequency bands from microwave up to optical frequencies. We have investigated in both simulation and experiment a two dimensionally periodic EBG structure made by reactive ion etching of silicon with a bandgap for transverse magnetic waves in the millimeter wave range around 100 GHz. The structure comprises both a large bandgap and a high mechanical stability due to interconnecting dielectric bridges.     

Effects of gelatine type and concentration on the shelf-life stability and quality of marshmallows

The effects of gelatine concentration, bloom strength, and origin on the quality and shelf-life stability of marshmallows were studied. All six sample treatments were carried out under accelerated storage conditions of 25 °C and 75% relative humidity (RH) for 25 weeks. Gelatine A 150 bloom had the highest viscosity because of its highest concentration (2.54%), lowest density and greatest amount of moisture loss producing the hardest marshmallows. Hardness and water activity measurements correlate for all sample treatments indicating that moisture loss is the main mechanism for hardening. With the exception of Gelatine B 2.2%, sugar crystallisation may have occurred in all sample treatments at week 20 which would have an impact on hardness as well. Gel network formation may be contributing towards hardness in Gelatine B 2.2% as there was an increase in hardness but no changes were perceived in water activity.