Suppression of by-product generation in the treatment of aromatic perfumery substances using a surface discharge

Treatment of perfumery materials such as aromatic hydrocarbons was attempted using atmospheric surface discharge and UV light irradiation. The maximum decomposition rate of phenyl ethyl benzene with a concentration of 8% using the discharge with UV light is 96%, that is 12% higher than that without UV light. Combination of surface discharge and UV light enhances the decomposition rate and energy efficiency, and enables to suppress the generation of by-products such as benzene.     

A poly-silicon TFT with a sub-5-nm thick channel for low-power gain cell memory in mobile applications

This work presents a gain-cell solution in which a novel ultrathin polysilicon film transistor provides the basis for dense and low-power embedded random-access memory (RAM). This is made possible by the new transistor's 2-nm-thick channel, which realizes a quantum-confinement effect that produces a low leakage current value of only 10/sup -19/ A at room temperature. The memory has the potential to solve the power and stability problems that static RAM (SRAM) is going to face in the very near future.     

Population structure of Cladophora-borne Escherichia coli in nearshore water of Lake Michigan

We previously reported that the macrophytic green alga Cladophora harbors high densities (up to 10(6) colony-forming units/g dry weight) of the fecal indicator bacteria, Escherichia coli and enterococci, in shoreline waters of Lake Michigan. However, the population structure and genetic relatedness of Cladophora-borne indicator bacteria remain poorly understood. In this study, 835 E. coli isolates were collected from Cladophora tufts (mats) growing on rocks from a breakwater located within the Indiana Dunes National Lakeshore in northwest Indiana. The horizontal fluorophore enhanced rep-PCR (HFERP) DNA fingerprinting technique was used to determine the genetic relatedness of the isolates to each other and to those in a library of E. coli DNA fingerprints. While the E. coli isolates from Cladophora showed a high degree of genetic relatedness (92% similarity), in most cases, however, the isolates were genetically distinct. The Shannon diversity index for the population was very high (5.39). Both spatial and temporal influences contributed to the genetic diversity. There was a strong association of isolate genotypes by location (79% and 80% for lake- and ditch-side samplings, respectively), and isolates collected from 2002 were distinctly different from those obtained in 2003. Cladophora-borne E. coli isolates represented a unique group, which was distinct from other E. coli isolates in the DNA fingerprint library tested. Taken together, these results indicate that E. coli strains associated with Cladophora may be a recurring source of indicator bacteria to the nearshore beach.     

An 0.03 μm gate-length enhancement-mode InAlAs/InGaAs/InPMODFET's with 300 GHz fT and 2 S/mm extrinsictransconductance

We have developed high-performance enhancement-mode InP-based modulation-doped field-effect transistors with 0.03 μm gate-length. A record high current gain cutoff frequency exceeding 300 GHz has been achieved, and the maximum extrinsic transconductance is as high as 2 S/mm with an associated drain current of 0.5 A/mm at a drain bias of 1 V. This high performance is a result of the reduction or gate length, the use of the high barrier metal Pt as gate electrodes, and most importantly the employment of the well-developed wet-etching technology that allows the formation of a very deep gate groove while retaining small side etching. The excellent E-MODFET performance opens up the possibility of implementing ever faster high-speed circuits based on direct-coupled FET logic     

Geothermal resources of Hachijojima

Hachijojima is a gourd-shaped volcanic island in the Pacific Ocean. Nishiyama and Higashiyama volcanoes consist of basalt lava and associated pyroclastic rocks. A promising geothermal resource was found in south Higashiyama, associated with an uplift of Tertiary rocks consisting of mainly andesite lava and related pyroclastic rocks, overlain by Quaternary volcanic rocks. Steep high-temperature (over 250°C) and high-pressure gradients occur in the deeper portion of the system near the Tertiary–Quaternary contact, indicating the presence of a cap rock. The cap rock formed by deposition of hydrothermal minerals. Geothermal fluid ascends from the deeper portions to shallow depths along vertical fractures through the cap rock. These vertical fractures form the geothermal reservoir in the Tertiary formation. Three wells were drilled into these vertical fractures, and approximately 30 t/h of superheated steam was obtained from each well during flow tests. The geothermal fluid is mainly a mixture of seawater and meteoric water in an approximate ratio of 1 to 2, based on chemical analyses, with a portion of volcanic gas included. At present a 3.3 MW_e, geothermal power plant is being constructed here.     

Two-group interfacial area transport equations at bubbly-to-slug flow transition

In relation to nuclear reactor accident and safety studies, experiments on hot-leg U-bend two-phase natural circulation in a loop with a relatively large diameter pipe (10.2 cm inner diameter) were performed for understanding the two-phase natural circulation and flow termination during a small break loss of coolant accident in LWRs. The loop design was based on the scaling criteria developed under this program and the loop was operated either in a natural circulation mode or in a forced circulation mode using nitrogen gas and water. Various tests were carried out to establish the basic mechanism of the flow termination as well as to obtain essential information on scale effects of various parameters such as the loop frictional resistance, thermal center and pipe diameter. The void distribution in a hot-leg, flow regime and natural circulation rate were measured in detail for various conditions. The termination of the natural circulation occurred when there was insufficient hydrostatic head in the downcomer side. The superficial gas velocity at the flow termination could be predicted well by the simple model derived from a force balance between the frictional pressure drop along the loop and the hydrostatic head difference. The bubbly-to-slug flow transition was found to be dependent on axial locations. It turned out that the formation of cap bubbles in the large diameter pipe caused the increased drift velocity, which would affect the prediction of the void fraction in the hot leg.     

Development of an in-air RBS technique using a metal capillary

We have developed a simple Rutherford backscattering spectroscopic (RBS) method to analyze sample depth profiles in air. To avoid excessive energy loss of projectile ions in air, we have used a 3 MeV proton beam extracted into air with a metal capillary. Using this capillary, we were able to extract a sufficiently large proton beam current to perform in-air RBS and in-air PIXE without requiring any window, such as a thin film, between a vacuum chamber and air. We have validated our technique by analyzing the depth profiles for Au foils of various thicknesses, 0.25, 0.75, and 2.5 μm. A comparison of the experimental results with a simple theoretical calculation indicates that this technique is useful for analyzing the depth profile of any specimen in air.     

Incremental learning methods with retrieving of interfered patterns

There are many cases when a neural-network-based system must memorize some new patterns incrementally. However, if the network learns the new patterns only by referring to them, it probably forgets old memorized patterns, since parameters in the network usually correlate not only to the old memories but also to the new patterns. A certain way to avoid the loss of memories is to learn the new patterns with all memorized patterns. It needs, however, a large computational power. To solve this problem, we propose incremental learning methods with retrieval of interfered patterns (ILRI). In these methods, the system employs a modified version of a resource allocating network (RAN) which is one variation of a generalized radial basis function (GRBF). In ILRI, the RAN learns new patterns with a relearning of a few number of retrieved past patterns that are interfered with the incremental learning. We construct ILRI in two steps. In the first step, we construct a system which searches the interfered patterns from past input patterns stored in a database. In the second step, we improve the first system in such a way that the system does not need the database. In this case, the system regenerates the input patterns approximately in a random manner. The simulation results show that these two systems have almost the same ability, and the generalization ability is higher than other similar systems using neural networks and k-nearest neighbors.     

Effects of CdS buffer layers on photoluminescence properties of Cu(In,Ga)Se2 solar cells

Photoluminescence (PL) have been studied on Cu(In,Ga)Se₂ (CIGS) thin films, CdS/CIGS and CIGS solar cells, to clarify the carrier recombination process. The chemical-bath deposition (CBD) of the CdS buffer layer on the CIGS thin film leads to (i) the enhancement of near-band-edge PL intensity by a factor of 2–3, (ii) change in energy of the defect-related PL and (iii) the slight change in the decay time. They are related not only to the minimization of the surface recombination but also to the modification of native defects at the Cu-poor surface of CIGS by the occupation of Cd atom at the Cu site. A donor–acceptor pair PL at low-temperature and temperature-dependent PL have been studied. They are discussed in terms of the impurity and defect levels created in the CIGS film during the CBD-CdS process.     

Energy-level alignment at model interfaces of organic electroluminescent devices studied by UV photoemission: trend in the deviation from the traditional way of estimating the interfacial electronic structures

The electronic structures of model interfaces of organic electroluminescent (EL) devices were investigated with UV photoemission spectroscopy (UPS). Interfaces of TTN (tetrathianaphthacene) and TCNQ (tetracyanoquinodimethane) were also studied as extreme cases for hole transport and electron transport material, respectively. For all organic/metal interfaces studied, the work function of metal electrode was changed by deposition of organic layer, i.e., the vacuum level was shifted at the interface, indicating the invalidity of the traditional energy level alignment model where a common vacuum level was assumed at organic/metal interface. At TCNQ/Au, DP-NTCI/Al, which are acceptor/metal interfaces, upward shift of the vacuum level of organic layer relative to that of metal was observed, suggesting the formation of interfacial dipole due to electron-transfer from metal to acceptor. At other organic/metal interfaces, TPD(N, N'-diphenyl-N, N'-(3-methylphenyl)-1, 1'-biphenyl-4, 4'-diamine)/Au or ITO (indium tin oxide), ALq/sub 3/ (tris(8-hydroxyquinolino) aluminum)/Al, DP-NTCl(N, N'-diphenyl-1,4,5,8- naphthyltetracarboxylimide)/Al or Au, downward shift of the vacuum level was observed. Such downward shift has been also observed in our previous study for porphyrin/metal interfaces, and seems to be a trend for organic/metal interfaces at which no electron-transfer from metal to organic layer occurs. This trend suggests that the traditional model tends to underestimate (overestimate) the barrier height for hole (electron) injection. On the other hand, the vacuum level shift at ALq/sub 3//TPD interface was less than 0.1 eV, leading to an apparent applicability of the traditional model. However, it is not always the case for organic/organic interfaces: finite shift of 0.2 eV was observed at TTN/TCNQ interface due to electron-transfer from TTN to TCNQ. Possible origins of vacuum level shift at organic/metal interfaces were also discussed.