Effects of Supercritical Fluid Extraction Parameters on Unsaturated Fatty Acid Yields of Pistacia terebinthus Berries

Utilization of renewable resources and development of new processes aimed at converting these materials into value added bio-products are gaining more emphasis. The scope of this study was to optimize supercritical CO₂ extraction (SFE) parameters such as pressure, temperature and flow rate for the yields of unsaturated fatty acids from Pistacia terebinthus berries by a Box-Behnken statistical design. All samples were analyzed for fatty acids by GC-FID. The most effective variables were pressure (P < 0.005) and flow rate (P ≤ 0.005). Maximizing the evaluative criteria for dependent variables (oleic acid, linoleic acid and linolenic acid), optimal conditions were determined to be 240 bar, 60 °C and a flow rate of 16 g/min yielding 51.2% oleic acid, 26.5% linoleic acid and 1.0% linolenic acid. The amounts of unsaturated fatty acids in SFE samples (81.3%) were higher than the hexane (74.3%) and were similar to that of cold press samples (80.1%). High concentrations of unsaturated fatty acids can indicate the utilization of the berries as a major dietary source and demonstrate challenges for industrial application of SFE as a green technology.     

Safety of the Las Vegas left-turn display

This paper provides a safety evaluation of a special protected/permitted left turn signal control (Las Vegas LT Display) that has been implemented in the urbanized area of Las Vegas, Nevada. The Las Vegas LT Display eliminates the yellow trap condition for leading approach in lead/lag operation. It provides protected only left turns during certain times of day by suppressing the permitted green ball and yellow ball displays. Before and after studies were conducted using the crash data from 10 intersections. Results from the analyses indicated that no obvious safety concerns due to use of the special display.     

The effect of nitrogen flow rate on TiBN coatings deposited on cold work tool steel

TiBN coatings have high hardness and high adhesion. Due to these excellent properties there has been increasing interest in TiBN coatings. In this study, TiBN coatings were deposited on AISI D2 cold work tool steel and silicon wafers by closed field unbalanced magnetron sputtering (CFUBMS). The structural, mechanical and adhesion properties of these coatings were analysed by X-ray diffraction, scanning electron microscopy, microhardness test, indentation test and scratch tests. TiBN coatings produced by magnetron sputtering exhibited a dense and columnar structure. These results indicate that TiB₂, TiN and h-BN exist in crystalline forms at all coatings. The highest hardness was obtained at the lowest nitrogen flow rate. Very few cracks were observed at the edge of the indentation marks at the highest nitrogen flow rate. The highest critical load obtained with scratch test was identified as 102?N.     

A numerical scheme for two-dimensional optimal control problems with memory effect

A new formulation for multi-dimensional fractional optimal control problems is presented in this article. The fractional derivatives which are coming from the formulation of the problem are defined in the Riemann–Liouville sense. Some terminal conditions are imposed on the state and control variables whose dimensions need not be the same. A numerical scheme is described by using the Grünwald–Letnikov definition to approximate the Riemann–Liouville Fractional Derivatives. The set of fractional differential equations, which are obtained after the discretization of the time domain, are solved within the Grünwald–Letnikov approximation to obtain the state and the control variable numerically. A two-dimensional fractional optimal control problem is studied as an example to demonstrate the performance of the scheme.     

Polyindene/organo‐montmorillonite conducting nanocomposites. I. Synthesis,characterization, and electrokinetic properties

In this study, Na‐montmorillonite was organically modified with cetyltrimethylammoniumbromide (CTAB) and intercalated with in‐situ polymerized indene. Polyindene(PIn)/Organo‐MMT nanocomposites were obtained with three different compositions and coded as: K1: [PIn(94.5%)/O‐MMT(5.5%)], K2: [PIn(92.8%)/O‐MMT(7.2%)], and K3: [PIn(87.9%)/O‐MMT(12.1%)]. These nanocomposites were subjected to full characterization with various techniques. Electrokinetic studies were conducted to reveal the zeta (ζ)‐potential characteristics of the nanocomposites. ζ‐potentials of the materials were observed to decrease with increasing O‐MMT content. The cationic (CTAB) and anionic (sodium dodecylsulfate) surfactants were shifted the ζ‐potentials of the colloidal dispersions to more positive and more negative regions, respectively whereas nonionic surfactant (Triton X‐100) caused almost no change. The pH and temperature were observed to shift the ζ‐potential values of the nanocomposites to more negative and slightly more positive regions, respectively. With the addition of mono (NaCl), di (BaCl₂) and three (AlCl₃) valent salts, the ζ‐potential of the nanocomposites were shifted to more negative, more positive, and much more positive regions, respectively. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012     

Overall equipment effectiveness when production speeds and stoppage durations are uncertain

Evaluation of manufacturing equipment performance has been very important in production-related functions such as planning, scheduling, and maintenance. Nevertheless, low accuracy of performance measurements can mislead decision makers. In this study, overall equipment effectiveness (OEE) is considered as a performance indicator of manufacturing equipment. In practice, components of OEE may consist of uncertainty due to manual or semi-automatic measurement systems. As a consequence, true performance of equipment may be masked by the uncertainty of measurements. In this study, two types of uncertainty are considered in production speed and stoppage duration measurements, which are used in calculating OEE components. When the measurements have uncertainty due to use of linguistic terms or some minor stoppages, idling, or speed losses being ignored, fuzzy arithmetic is used as a method to handle uncertainty. In some low accuracy cases, best guess interval estimates of operators may better reflect the state than just providing a point estimate. For such cases, interval arithmetic is used as a method to handle uncertainty. Implementation of the methods are illustrated using two real-world examples and a software is provided for practitioners. Proposed methods help making better informed decisions using OEE under measurement uncertainty of production speed and stoppage durations.     

Effects of different polymerization protocols on the degree of conversion of two dual‐cured core buildup composites polymerized by light‐emitting diode and halogen light‐curing units

The aim of study was to investigate the effects of various curing protocols with quartz–tungsten halogen (QTH) or light‐emitting diode (LED) light‐curing units on the degree of conversion (% DC) of two dual‐cured core buildup resin composites. Two dual‐cured core buildup resin composites, Clearfil Dc Core Automix (CLF) and Grandio Core Dc (GR), were selected. Specimens were exposed to the polymerization protocols as follows: there was immediate photoactivation or photoactivation delayed by 2 or 5 min by a QTH or LED source, and one group was allowed to chemically polymerize and served as a control (n = 6). The % DC of the specimens was determined with attenuated total reflectance–Fourier transform infrared spectroscopy. The GR samples polymerized with QTH for the 5‐min‐delayed photoactivation had higher % DC values than those self‐cured, and the Clearfil Dc Core Automix (CLF) samples with immediate or delayed curing protocols with halogen yielded higher % DC values than the samples that were chemically polymerized. The comparison of the two resin composites polymerized with halogen showed a higher % DC for CLF than for GR in the 2‐min‐delayed photoactivation. On the other hand, when they were cured with LED, the % DC values of GR significantly increased after the 2‐min‐delayed photoactivation. In light of the results, it might be stated that CLF polymerized with QTH, could be the better option. GR provided adequate chemical polymerization; therefore, it might be useful in areas in which light curing is not possible. Clinicians should consider the polymerization characteristics of dual‐cured resin composites. The use of different composites may require the modification of the application procedures recommended by the manufacturer. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 40560.     

Preconditioning of AISI 304 stainless steel surfaces in the presence of flavins—Part I: Effect on surface chemistry and corrosion behavior

Stainless steel AISI 304 surfaces were studied after a mild anodic polarization for oxide growth in the presence and absence of two derivatives of vitamin B2 (riboflavin and flavin mononucleotide) that can be secreted by metal-reducing bacteria and act as a chelating agent for iron species. The alterations in oxide chemistry were studied by means of surface-sensitive techniques such as X-ray photoelectron spectroscopy and time-of-flight secondary ion mass spectrometry analysis. The complementary electrochemical characterization revealed a preferential growth of an oxide/hydroxide iron-rich film that is responsible for an altered pit initiation and nucleation behavior. These findings suggest that as the corrosion behavior is determined by the interplay of the chemical and electronic properties, only a mild anodic polarization in the presence of redox-active molecules is able to alter the chemical and electronic structure of the passive film formed on stainless steel AISI 304. This helps to achieve a profound understanding of the mechanisms of microbially influenced corrosion (MIC) and especially the possible effects of the redox-active biomolecules, as they may play an important role in the corrosion susceptibility of stainless steel surfaces.     

A study on swelling behavior of poly(p‐chloro styrene) networks in some aromatic hydrocarbons and linear poly(p‐chloro styrene) solutions

Crosslinked networks (NPPCS) and linear polymers (LPPCS) of poly (p‐chloro styrene) were synthesized by free‐radical polymerization of p‐chloro styrene. NPPCS networks were swollen in four different molecular weights of LPPCS solutions in toluene at three different concentrations. The equilibrium swelling results were evaluated by means of Flory‐Rehner theory to obtain network–linear polymer interaction parameter, χ′₂₃ between NPPCS and LPPCS. It was concluded that the parameter χ′₂₃ decreased with molecular weight but increased with concentration of LPPCS in outer solution. The solvent independent interaction parameter between NPPCS and PPCS was estimated as 0.7 by extrapolation of the values of χ′₂₃ to zero value of the fraction ratio of solvent to linear polymer, ν₁/ν₃ inside the network. As well as, the binary interaction parameters, χ₁₂ of NPPCS with benzene, ethyl benzene, n‐propyl benzene and isopropyl benzene were obtained by means of Flory‐Rehner theory at temperatures between 25 and 55°C. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2009     

Person?×?Situation interactionism in self-encoding (Iam…when…): Implications for affect regulation and social information processing.

Although Person?×?Situation (P?×?S) interactionism is central in current social-cognitive conceptions of personality organization, its implications for the encoding of the self remain unexplored. Two studies examined the causal role of P?×?S interactionism in self-encoding on affect regulation and discriminative social perception. Following failure (Studies 1 and 2) and success (Study 2) ideation, participants were prompted to encode the self either in P?×?S interactionist terms (I am…when…) or in traitlike unconditional terms (I am…). Interactionist (compared with unconditional) self-encoding led to less affective extremity, suggesting that such encoding may prevent individuals from generalizing specific success and failure experiences to the self as a whole. Study 2 also found that interactionist self-encoding attenuated the endorsement of global stereotypes, suggesting that such encoding may enhance fine-grained social perception as well. (PsycINFO Database Record (c) 2010 APA, all rights reserved)