A study of external mass transfer effect on biodegradation of phenol using low‐density polyethylene immobilized Bacillus flexus GS1 IIT (BHU) in a packed bed bioreactor

The impact of external mass transport on the biodegradation rate of phenol in a packed bed bioreactor (PBBR) was studied. A potential bacterial species, Bacillus flexus GS1 IIT (BHU), was isolated from the petroleum‐contaminated soil. Low‐density polyethylene (LDPE) immobilized with the B. flexus GS1 IIT (BHU) was used as packing material in the PBBR. The PBBR was operated by varying the inlet feed flow rate from 4 to 10 mL/min, and the corresponding degradation rate coefficients were found to be in the range of 0.119–0.157 L/g h. In addition, the highest removal rate of phenol was obtained to be 1.305 mg/g h at an inlet feed rate of 10 mL/min. The external mass transfer was studied using the model . A new empirical correlation for the biodegradation of phenol in the PBBR was developed after the evaluation at various values of K and n.     

Polyaniline–13X zeolite composite‐supported platinum electrocatalysts for direct methanol fuel cell applications

We successfully synthesized 13X zeolite using a hydrothermal method. Then, composites of polyaniline (PANI) with 13X zeolite and PANI–13X with platinum were prepared by chemical oxidative polymerization and chemical reduction, respectively. Field emission scanning electron microscopy, X‐ray diffraction, Raman spectroscopy and Brunauer–Emmett–Teller techniques were used to characterize the PANI–Pt and PANI–Pt–13X composites. Further, the electrocatalytic activity towards methanol oxidation of the synthesized catalysts was explored using cyclic voltammetry in 1 mol L^?1 CH₃OH + 0.5 mol L^?1 H₂SO₄ solution. From the obtained results, PANI–Pt–13X shows superior performance compared to PANI–Pt towards methanol oxidation and electrical conductivity. Hence, the 13X zeolite‐incorporated PANI–Pt composite could be an efficient catalyst for direct methanol fuel cell applications. © 2019 Society of Chemical Industry     

POSS-based luminescent hybrid material for enhanced photo-emitting properties

In this present work, we have developed a novel POSS type monomer ligand “2,6-pyridinediamine-bis-(propanylheptaisobutyl POSS)” (PDC-POSS) and utilized in the preparation of potential luminescent hybrid complex Eu-PDC-POSS with an inner transition metal ion Eu³⁺. The solubility and photo-emitting properties of new Eu-PDC-POSS hybrid material were studied. The precursor PDC-POSS was synthesized by treating (3-aminopropyl)heptaisobutyl POSS with PDC (2,6-pyridinedicarboxylic acid chloride), and then coordinated with Eu³⁺ using europium nitrate to afford Eu-PDC-POSS hybrid material. The europium-doped hybrid material was characterized using fourier transform infrared spectroscopy, and scanning electron microscopy along with energy dispersive X-ray analysis. The photo emitting properties were studied using a fluorescence spectrophotometer in which, the results showed enhancement in red emission peak at 618 nm for Eu-PDC-POSS, when compared to that of a known solgel-based material Eu-PDC-solgel.     

Structural Properties of Boron-Doped Germanium-Tin Alloys Grown by Molecular Beam Epitaxy

Boron-doped Ge_1?x Sn _x alloys with atomic fractions of tin up to x = 0.08 were grown on n-Ge(001) substrates using solid-source molecular beam epitaxy, in order to study their structural properties. The total boron concentration in the alloys was ~ 10¹⁸ cm^?3 as measured by secondary-ion mass spectroscopy, which also indicated low amounts of impurities such as carbon and oxygen. More than 90% of the Sn atoms occupied substitutional lattice sites in the alloy as determined by Rutherford backscattering spectrometry. High-resolution x-ray diffraction showed that the boron-doped Ge_1?x Sn _x alloys were single crystals that were completely strained with low defect densities and coherent interfaces for thickness up to 90 nm, and for Sn composition of 8%. The boron-doped Ge_1?x Sn _x /n-Ge formed p–n junctions with conventional rectifying characteristics, indicating that the boron produced electrically active acceptor states.     

Binning algorithm for high-resolution IRS-P4 OCM chlorophyll image

Daily chlorophyll-a concentration from the Ocean Colour Monitor (OCM) sensor onboard the Indian Remote Sensing satellite (IRS-P4) is used to make weekly and monthly chlorophyll-a concentration maps. The pathwise swath data at 12 noon for every alternate day over the north Indian Ocean (NIO) during February 2004 and February 2005 were used to compare the existing algorithms for binning the data. Atmospherically corrected and geocorrected OCM data were used in the comparative study of three averaging algorithms – arithmetic mean (AVG), geometric mean (GEO) and maximum likelihood estimator (MLE). The analysis shows that the AVG algorithm is best suited when compared with the two other algorithms. However, for case 1 water, MLE gives nearly the same value as AVG. Based on this result, AVG was selected for operational weekly and monthly averaging of OCM data over the NIO. These high-resolution-derived chlorophyll-a weekly and monthly products will be useful to resolve inter-annual-to-decadal changes in chlorophyll-a concentration over the NIO.     

Plug-load densities for energy analysis: K-12 schools

Benchmarking plug-load densities is essential to bypass arbitrary and/or incorrect inputs used in building energy analysis. As more building simulationists play a decision-making role for the design team, they tend to lean on building energy standards and guidelines for preliminary inputs such as plug-load densities. It is necessary for building energy standards and rating systems to implement plug-load density benchmarks to reward design teams in their efforts to reduce plug-load energy use. Using case study buildings, this paper establishes benchmark plug-load densities for K-12 schools under two new categories – classrooms with computers and classrooms without computers. Eighteen K-12 schools including 9 elementary, 2 middle, and 7 high schools are assessed for actual plug-load densities. For the same case study buildings, four existing approaches – NREL, COMNET, ASHRAE 90.1-1989, and Title-24 are evaluated for plug-load densities. Results show under- and over-estimation of plug-load densities over actual densities. The development of benchmark for K-12 schools will pave way for instituting targets for trimming plug-load densities in new and retrofit building projects.     

Genesis of enhanced photoactivity of CdS/Nix nanocomposites for visible-light-driven splitting of water

A series of CdS/Ni_x nanocomposite photocatalysts, containing ca. 0.6–15 wt% Ni, were synthesized using a one-step hydrothermal method and characterized for their crystallographic, morphological, interfacial, and optical properties. Rietveld refinement of powder XRD data revealed the coexistence of wurtzite (hexagonal) and zinc blende (cubic) phases of CdS in ratios dependent on Ni content. Only a fraction of Ni existed as a secondary phase of NiS while the majority occupied the lattice positions of hexagonal CdS. Whereas up to 10-fold enhancement in H₂ evolution compared with pure CdS was observed for samples containing ∼1.5–4.5 wt% Ni, samples with smaller or larger Ni content displayed poor activity for visible-light-induced splitting of water in presence of sulfide–sulphite ions as sacrificial electron donors. In contrary to recent findings, our study reveals that the enhanced CdS photoactivity is not a result of charge transfer between p-type NiS and n-type CdS, Ni-induced visible-region absorbance, or the coating of CdS particles by non-photoactive NiS. Instead, the preparation-dependent hexagonal/cubic CdS phase boundaries and particle morphology may play a crucial role. Additionally, certain Ni-doping-induced sub-bandgap shallow energy levels contribute to charge carrier separation.     

Study of Non-lubricated Wear of the Al–Si Alloy Composite Reinforced with Different Ratios of Coarse and Fine Size Zircon Sand Particles at Different Ambient Temperatures

In the present work, a detailed study of ceramic reinforcement of different size ranges in the matrix of LM13 alloy on the friction and wear behavior has been carried out. For this purpose, LM13/Zr composite containing 10 wt% zircon sand particles of different size ranges using stir casting process has been developed. Zircon sand particles were incorporated in two ways: firstly as single size reinforcement and secondly dual size reinforcement. Durability of the composites was tested by finding the wear rate of the composite against the steel disk by pin-on-disk method. Addition of zircon sand particles in the LM13 alloy improves the hardness of the composite as well as wear resistance. Wear rate of the developed composites was tested under different test conditions by varying the applied load and ambient temperatures. Wear rate of the composite changes significantly at different ambient temperatures. SEM analysis of the worn surfaces was done to know the operative wear mechanism.     

A figure of merit for evaluating sustainability of renewable energy systems

For grading different types of renewable energy based electricity generation systems, a figure of merit has been proposed and evaluated. The figure of merit has been obtained by analyzing total energy utilization in constructing and installing the systems and by their respective electricity generation. The gross carbon emission has also been estimated for evaluation of figure of merit. This figure of merit clearly indicates that wind power is the most sustainable source for electricity generation, followed by small hydropower and solar photovoltaics.