Influence of electric fields on the structure of chitosan edible coatings

The aim of this work was to evaluate the effect of electric fields applied at different field strength values on mechanical and thermal properties of chitosan films/coatings (obtained from lobster of the Cuban coasts). XRD analyses indicated that electrically treated chitosan films exhibited a more ordered structure and a clearly higher crystallinity when compared with non-treated films, thus displaying significant effects on the value of the crystallinity index (CI). SEM micrographs evidenced that the surface morphology of chitosan films was influenced by the electric field. In fact, the electric field treatment led to a structure with more regular layers as can be seen in the cross-sections of the films observed under SEM. The application of the electric field to chitosan film-forming solutions resulted in an increase of the tensile strength (c.a. 9%) and elongation-at-break (c.a. 18%) of the corresponding chitosan films. The reported results demonstrate that the application of an electric field to film-forming solutions of chitosan is an interesting instrument to taylor relevant properties of the films or coatings produced from them.     

Chemical Defenses Against Fish Predation in Three Brazilian Octocorals: 11β,12β-Epoxypukalide as a Feeding Deterrent in Phyllogorgia dilatata

The feeding-deterrence properties of crude extracts of three Brazilian octocoral species, Neospongodes atlantica Kükenthal (Alcyonacea, Nephtheidae), Plexaurella regia Castro (Gorgonacea, Plexauridae), and Phyllogorgia dilatata Esper (Gorgonacea, Gorgoniidae), were investigated. All the extracts were incorporated into food strips at the concentrations occurring in the living organisms. Crude extract and its ethyl acetate fraction obtained from P. dilatata collected in Armação dos Búzios (Rio de Janeiro State), when incorporated into artificial diets and tested in the habitat of origin, reduced consumption of food strips by fishes, relative to controls. Crude extracts from two octocoral species collected at the National Marine Park of Abrolhos (Bahia State), N. atlantica and P. regia, had no apparent feeding-deterrence properties; in fact, they seemed to stimulate feeding. Bioassay-guided fractionation of the bioactive P. dilatata crude extract revealed that the deterrent property was restricted to a medium polarity fraction. Field palatability experiments with two pure compounds isolated from this fraction revealed that the furanocembranolide 11,12-epoxypukalide is a potent feeding deterrent produced by P. dilatata against fish. Apparently, furanocembranolides are a particular class of compounds with feeding deterrent properties, protecting some octocorals from potential fish predator species in both tropical and temperate environments.     

Three-Phase Low-Frequency Commutation Inverter for Renewable Energy Systems

The connection of distributed power sources with the utility grid generally needs an electronic power converter for processing the locally generated power and injecting current into the system. If the source provides a dc voltage, the converter must be able to produce a low-distortion high-power-factor ac current. The same aspects related with the voltage and current distortion produced by nonlinear loads can be considered for the injection of power into the grid. In the absence of a specific standard, this paper takes as a reference the limits for current harmonics given by international standards. The justification for this approach is that, from the resulting line voltage degradation, there is no difference between injected and absorbed currents. This paper presents a three-phase inverter using low-frequency commutation. An auxiliary circuit is added to the inverter topology to reduce the output voltage distortion, thus improving the current waveform. The main advantages of this approach are the minimization of the switching losses and the elimination of the electromagnetic interference, which avoids high-frequency filters necessary in high-frequency commutation inverters     

A Comparative Study of Several Material Models for Prediction of Hyperelastic Properties: Application to Silicone-Rubber and Soft Tissues

Abstract:  The correct modelling of constitutive laws is of critical importance for the analysis of mechanical behaviour of solids and structures. For example, the understanding of soft tissue mechanics, because of the nonlinear behaviour commonly displayed by the mechanical properties of such materials, makes common place the use of hyperelastic constitutive models. Hyperelastic models however, depend on sets of variables that must be obtained experimentally. In this study the authors use a computational/experimental scheme, for the study of the nonlinear mechanical behaviour of biological soft tissues under uniaxial tension. The material constants for seven different hyperelastic material models are obtained via inverse methods. The use of Martins's model to fit experimental data is presented in this paper for the first time. The search for an optimal value for each set of material parameters is performed by a Levenberg–Marquardt algorithm. As a control measure, the process is fully applied to silicone-rubber samples subjected to uniaxial tension tests. The fitting accuracy of the experimental stress–strain relation to the theoretical one, for both soft tissues and silicone-rubber (typically nonlinear) is evaluated. This study intents also to select which material models (or model types), the authors will employ in future works, for the analysis of human soft biological tissues.     

A simple experimental arrangement for measuring the vapour pressures and sublimation enthalpies by the Knudsen effusion method: Application to DNA and RNA bases

We measured the vapour pressure of several DNA and RNA bases—uracil, adenine, guanine, thymine and cytosine—in the 300–450 K range. In each case the sample mass loss rate was measured as function of temperature with a simple setup consisting of a commercial film deposition system and a homemade oven. Afterwards vapour pressure values were extracted from these data using the Knudsen effusion method. Sublimation enthalpy values, obtained from vapour pressure data by applying the Clausius–Clapeyron equation, are in very good agreement with literature values. The results suggest that crystal-based film thickness monitors may be useful in on-line cross-section measurements, monitoring the gas target thickness. They also show the viability of using this oven for producing a biomolecular gas target.     

Chemical and microbiological quality of grass carp (Ctenopharyngodon idella) slaughtered by different methods

The effect of two slaughter methods (immersion in ice-water slurry and electrical stunning followed by ice slurry asphyxiation) on chemical and microbiological parameters of grass carp (Ctenopharyngodon idella) stored in ice for 20 days was evaluated. No differences in total volatile basic nitrogen (TVB-N), pH, carbohydrate or protein content of mucus were observed between the slaughter methods. Ice-slaughtered fish had lower bacteria counts at the beginning of storage, but higher counts than fish slaughtered by electricity at the end of storage (p < 0.05). However, no significant differences in the shelf life were observed between the slaughter methods evaluated (limit of acceptability – counts > 3 × 10⁶ CFU g⁻¹ – attained after 13–16 days). Results indicated that the chemical parameters evaluated have a limited applicability to assess the shelf life of grass carp stored in ice, since pH limit (6.8) was exceeded after 4 days, while TVB-N limit (30 mg%) was not attained after 20 days of storage.     

Programmable CMOS switched-capacitor biquad using quasi-passivealgorithmic DAC's

This paper describes an electrically programmable switched-capacitor (SC) biquad using quasi-passive algorithmic digital-to-analog converters (DAC's). Since only two equal-valued capacitors are needed for programming each capacitance value, the proposed technique offers compact, cost-effective programmability when compared to traditional programming techniques employing binary-weighted capacitor-arrays (C-arrays). A demonstration prototype chip realized in a 1.2 μm CMOS double-metal double-poly technology, and which implements an 8 b programmable SC biquad giving a wide range of lowpass, bandpass and highpass filtering functions, occupies an active area of only 0.38 mm²     

Treatment outcome with radiation therapy after breast augmentation or reconstruction in patients with primary breast carcinoma

BACKGROUND: Analyses were performed to determine local control and cosmetic outcome of breast carcinoma patients with prosthetically augmented or reconstructed breasts who had received radiation therapy (RT). METHODS: Twenty-one newly diagnosed breast carcinoma patients with prosthetically augmented or reconstructed breasts were treated with external beam RT. All patients received whole breast RT (median dose, 50.4 gray [Gy]) and 19 were boosted to a median dose of 60.4 Gy. A median dose of 50.4 Gy was delivered to the regional lymph nodes in 12 patients. Tissue equivalent bolus material was used in six patients. Seventeen patients received adjuvant systemic therapy. Cosmetic results were evaluated at 3-6-month intervals. RESULTS: With a median follow-up of 32 months, good/excellent cosmetic results were observed in 71% of patients (100% in those with augmented breasts and 54% in those with reconstructed breasts). Four patients (19%) with fair/poor cosmetic outcomes required implant removal and/or revision. Multiple clinical and treatment-related factors were analyzed for their impact on cosmetic outcome. A worsened cosmetic result was observed with increasing stage (P = 0.076), breast reconstruction (vs. augmentation) (P = 0.030), and bolus application (P = 0.016). All patients with fair/poor cosmetic outcomes had time intervals from implant insertion to RT ranging from 53-213 days. Two patients developed an isolated local recurrence within the augmented breast. CONCLUSIONS: Patients with prosthetically augmented breasts can undergo RT and expect good/excellent cosmetic results. Patients with reconstructed breasts are at a significantly greater risk for cosmetic failure. This risk may be related to the higher percentage of patients with advanced disease, those who received bolus application, and those who received earlier delivery of RT (after the cosmetic procedure) in reconstructed breasts.