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81.
A classical many-body potential for transition metal carbide cluster is developed in the form of the bond-order type potential function. The parameter sets between carbon atoms and several transition metal atoms (Fe, Co and Ni) are constructed by fitting binding energies from Density Functional Theory (DFT) calculations. Using the potential function, clustering process of carbon atoms to a small metal cluster is studied by classical molecular dynamics (MD) simulation. The number of hexagonal rings in the Co cluster increases about twice as fast as in the Fe cluster. This implies that the graphitic lattice interacts more strongly with Co atoms than with Fe atoms. A Co cluster has a crystal structure where metal atoms are regularly allocated and embedded in the hexagonal carbon network in the simulation. In contrast, carbon atoms cover the entire surface in case of the Fe cluster. Additionally, the potential energy surface that a carbon atom feels from a 2D closed-packed facet is examined using a hypothetical FCC(1 1 1) facet of several transition metals. The potential energy minima are distributed on the hexagonal network showing the 2D closed-packed facet can be a template where a graphene is formed. 相似文献
82.
Since the beginning of the ‘Doi Moi’ policy in 1986, Hanoi has witnessed significant changes in its urban areas. Landsat and Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) scenes were used to identify built-up areas in Hanoi, and spatial metrics were used to characterize urban change patterns from 1975 to 2003. Firstly, a spatial metric called the ‘percentage of like adjacency’ was used to discern urban growth patterns, which were classified into three sub-patterns: expansion growth, infill growth and outlying growth. Secondly, the driving force underlying the urbanization of the city for the 1975–1984, 1984–1992, 1992–2001, 2001–2003 periods was investigated using a spatial metric analysis programme (FRAGSTATS). The expansion of urban areas along major transportation routes in the latter 1980s was identified as the main form of urbanization in Hanoi. This paper shows the potential application of spatial metrics as secondary sources of information for supporting remotely sensed data and their use to characterize urban growth patterns. 相似文献
83.
Kiyoshi Minoura Shigeaki Mizushima Yasushi Asaoka Ichiro Ihara Eiji Satoh Sayuri Fujiwara Yasuhisa Itoh 《Journal of the Society for Information Display》2008,16(1):129-136
Abstract— A novel reflective color LCD without polarizers has been developed using a PDLC film and a retro‐reflector. Bright color images including moving images are achievable with ambient light. This novel LCD will enable the new application area of electronic paper. 相似文献
84.
Tae Ho Lee Hirokazu Aoki Yasushi Sugano Makoto Shoda 《Journal of Bioscience and Bioengineering》2000,89(6):545
The production of dye-decolorizing peroxidase (DyP) was investigated by cultivating Geotrichum candidum Dec1 using molasses as a carbon source. Molasses at concentrations greater than 10 g·l−1 was found to increase the decolorization activity of the culture broth toward dye, reactive blue 5 mainly because the amount of enzyme produced was enhanced. However, complete inhibition of DyP activity by molasses was observed at the concentration of 20 g·l−1, indicating that the inhibitory effect of molasses on the culture broth activity to decolorize the dye was involved. When the culture broth was diluted 25 times, the dye-decolorizing activity was 7 times as much as that of non-diluted culture broth. The molasses fractions separated by gel chromatography (300–400 ml and 400–500 ml fractions) completely inhibited the purified DyP. On the basis of these results, we propose a scheme to control both positive and negative effects of molasses on the dye decolorization process. 相似文献
85.
Kagiyma Mitsuyasu Ogasawara Yasuo Goto Kazuo Kajiya Fumihiko 《IEEE transactions on bio-medical engineering》1985,(8):630-633
This communication considers a method for evaluating fluctuations in the integral type output of a linear time-invariant compartmental system with a Markovian transition process. First, we derived a mathematical formula to calculate variances and covariances of integral type. outputs, as with radioisotope data, when transition rates are known. Then, an estimate for the upper limits of variances and covariances, i.e., 1/2?initial dose, when the transition rates are not given beforehand, was introduced. 相似文献
86.
A Nb3Sn composite conductor with ≈ 10 000 submicron diameter filaments has been manufactured using the external diffusion process. A.c. losses were greatly reduced by the use of a fine filament size (0.53 μm, design value), a tight twist pitch (0.87 mm) and a small wire diameter (0.153 mm) with a bronze matrix. In an a.c. field with a frequency of 50 Hz and amplitude of 2.0 T, the hysteresis loss and the coupling current loss were observed to be 465 kW m−3 and 26 kW m−3, respectively. A triplex conductor was constructed by cabling three strands at a twisting pitch of 3 mm, and a small coil was wound from this cable (i.d. 11 mm, o.d. 33 mm, axial length 19 mm). With d.c. the coil generated a field of 1.3 T at the critical current, lc of 37.4 A. When the coil was operated at 50 Hz, with an exciting current of Ic, the observed loss averaged over the windings was 240 kW m−3. The quenching current for 50 Hz operation was 53 A at a maximum field of 1.8 T. This was considerably higher than the critical values under d.c. conditions. Preliminary studies have shown that, if this conductor is used in superconducting armature windings of rotating machines, economical benefits are obtained compared with the use of conventional armatures. 相似文献
87.
This paper describes an efficient contention resolution algorithm and its distributed implementation for large capacity input queuing cross-connect switches, which will establish virtual paths in future broadband ATM networks. The algorithm dynamically allocates sending time to cells held in input queues when no contention is indicated in the designated output ports. An expression for the mean delay and the cell loss probability for random traffic are derived through an approximate analysis. Input cells are served on a first-come, first-served basis as conventional contention resolution algorithms whose throughput saturates at 58 per cent because of head of line blocking in input queues. The proposed algorithm achieves a maximum throughput of 76 per cent. 相似文献
88.
The synergistic effect of methyltrioctylammonium chloride (QCI) on the extraction of Np(V) by 1-phenyl-3-methyl-4-benzoyl-pyrazolone(HP) in benzene is studied over the pH range 2-6. This system extracts Np(V) better than any previously reported. The interaction of the extractants and monomer-dimer equilibria affect the distribution behavior of Np(V) in a complicated manner. Analysis of the results suggests that NpO2 + (M+) is extracted as mixed dimers, (QMP2QCl)o and (QMP2QP)o. 相似文献
89.
Yuji Yabuki Yoshitaka Mukaida Yoshinori Saito Kazunori Oshima Tatsuo Takahashi Eiichi Muroi Kei Hashimoto Yasushi Uda 《Food chemistry》2010
To characterise the composition of sulphur-containing constituents in Chinese chive (Allium tuberosum Rottler), GC–MS and HPLC analyses were carried out, using 12 varieties of Chinese origin, 4 varieties of Japanese origin and 6 commercially available cultivars. Five disulphides (dimethyl, allyl methyl, methyl 1-(E)-propenyl, diallyl, and allyl 1-(E)-propenyl), two trisulphides (dimethyl and allyl methyl), and two vinyldithiins (3-vinyl-[4H]-1,2- and 2-vinyl-[4H]-1,3-) were identified on the basis of their mass spectral and GC-retention data. Among the detected sulphur compounds, sulphides with a methyl group predominated over those with an allyl group. This was supported by the HPLC estimations, suggesting that all cultivars examined had much greater amounts of methiin than alliin. Also, two novel compounds were tentatively identified as [3H,4H]-1,2-dithiin and [2H,4H]-1,3-dithiin on the basis of their mass spectral features, GC-retention data, and some experimental results on their formation in reaction mixtures with different proportions of methiin and alliin. Their formation mechanism was proposed. 相似文献
90.
The unsteady behavior of flow driven by a jet suddenly injected into a cell is numerically studied by solving the axisymmelric two-dimensional compressible Navier-Stokes equations. The system of the calculation is a model of the laser ablation of a certain duration followed by a discharging process through the exit hole at the down- stream end of the cell. In the calculations, the contour of the cell is changed while other parameters such as the Mach number of the jet, its duration, and the diameter of the cell exit are fixed. Monitoring the velocity at the exit hole is used to investigate the influence of the shape on the interaction between the shock wave and the jet. As the result, it was found that the velocity peak value and its arrival time at the downstream end of the cell exit are determined by the diameter of the cell. 相似文献