高强钢20MnTiB多工位冷镦变形行为EI北大核心CSCD

通过对高强螺栓多工位冷镦变形分区的金属流动、显微组织、力学性能及其变化规律进行分析,并采用Deform-3D数值模拟和实际产品成形相结合的方法,来研究高强材料的多工位冷镦变形行为。结果表明:多工位冷镦变形属于低动态变形;大、小变形区的宏观流线和显微组织有明显的"遗留性",而难变形区由于高强材料的"包辛格效应",铁素体由拉长的晶粒变成等轴晶粒,而珠光体的带状消失,组织"遗留性"最差;通过低动态多工位冷镦变形,20MnTiB高强钢微观组织中铁素体和珠光体均发生了形变强化,且硬度值的增幅相近。     

芳纶表面改性及其与丁腈橡胶复合材料的性能研究

为增强对位芳纶纤维(PPTA)与丁腈橡胶(NBR)之间的界面粘结强度,采用多巴胺(DA)-硅烷偶联剂对芳纶纤维联合改性并制备PPTA/NBR复合材料。结果表明,纤维改性后表面粗糙度增加;表面元素含量和种类都发生较大变化;在H试样抽出测试中,改性后的PPTA帘线/NBR试样抽出力相对于未改性试样增大64.02%,且黏附橡胶较多。改性后的PPTA/NBR试样,纤维含量相同时,断裂伸长率和拉伸强度相对未改性的PPTA/NBR试样增大;随着纤维含量的增加,使用同种方法处理的PPTA/NBR复合材料断裂伸长率减小,拉伸强度先增大后减小。     

载体Al/Si比对Cu-ZnO-ZrO2催化剂上CO2加氢合成甲醇的影响

用直接合成法制备了不同铝硅物质的量比Al-SBA-15(β)(β=n(Al)/n(Si)=0,0.02,0.03,0.05)介孔分子筛,并采用浸渍法制备了金属负载量m=35%的CZZ/Al-SBA-15(β)负载型介孔催化剂,考察了Al/Si比对负载催化剂结构和性能的影响。采用N_2吸附-脱附、X射线衍射(XRD)、H_2程序升温还原(H_2-TPR)、CO_2吸附(CO_2-TPD)、NH3吸附(NH3-TPD)和透射电子显微镜(TEM)等手段对样品进行了表征,在固定床反应器上评价了其CO_2加氢合成甲醇的催化性能。实验结果表明,CZZ/Al-SBA-15(β)具有介孔结构,Al的引入不但增加了载体表面酸性位点,同时还提高了催化剂表面铜分散度(DCu%)和铜比表面积(SCu)以及促进了Cu~+-O-Zn活性位的形成,从而大大提高了催化剂的活性。其中CZZ/Al-SBA-15(0.03)催化剂的甲醇选择性达到26%,与不掺铝的CZZ/Al-SBA-15(0)催化剂相比,甲醇选择性提高了11%,但随着掺Al量的继续增加,酸性太强,CO_2吸附能力下降,活性反而降低。     

企业碳排放信息披露的标准化探讨

近年,我国各地碳交易市场建设步伐迅速,在全国7个试点省市碳排放权交易市场已大体建成,运作亦趋于成熟,计划2017年建立全国统一的碳市场.但纵观如何从以下到上相结合的方式开展碳市场建设,由于标准"打架"、统一的碳排放权交易会计处理信息规范、碳排放信息披露义务与方法方式的准则和规范尚未建立、碳信息披露不充分等因素影响制约,在一定程度上将大大约束企业参与碳排放权交易发展的积极性,以企业为市场主体的活力相对滞后.本文从标准化方面进行了探讨分析.     

一种耐振动远距离输送的常温乳化基质的研制

介绍了一种耐振动、适宜远距离运输、现场装药车装药的乳化基质的研制。经检测,该乳化基质抗振动性好,在振动频率为1 Hz时,振动20 h后仍不破乳、不老化,敏化后爆速稳定;黏度适中,常温黏度为40 000 m Pa·s,不仅有利于现场装药车泵送,且耐储存,储存期达到30 d;敏化后爆速比普通混装乳化基质高,达到5 000 m/s以上;安全性好,摩擦感度和撞击感度均为0。可以满足长距离运输现场装药车装填的需要,适用于各类露天矿山远程配送装填使用。     

Engineering High‐Performance MoO2‐Based Nanomaterials with Supercapacity and Superhydrophobicity by Tuning the Raw Materials Source

Herein, a simple self‐assembly method is proposed for the fabrication of MoO₂‐based superhydrophobic material with record high contact angles (contact angle up to about 173°) for conductive metal oxides on hard/soft substrates. The spin‐coated surface demonstrates excellent oil–water separation efficiency (>98%) after 50 cycles and robust corrosion resistance after immersion into different pH solutions for 20 d. These water‐resistant coatings retain excellent superhydrophobicity after oil immersion, knife‐scratch, and long‐cycle sandpaper abrasion, which is not observed on most artificial surfaces. Meanwhile, the functionality switching from superhydrophobicity to supercapacity, which have an inverse relationship in aqueous solutions because of poor electrode wettability, is achieved simply by editing the raw materials source. Tuning of the raw materials leads to the same product MoO₂/graphitic carbon with different morphologies and functionalities. Different from superhydrophobic MoO₂/carbon ball flowers, MoO₂ nanotubes with carbon exhibit excellent supercapacity with a large gravimetric capacitance and great cycling stability.     

Engineering 3D Ru/Graphene Aerogel Using Metal–Organic Frameworks: Capture and Highly Efficient Catalytic CO Oxidation at Room Temperature

Noble metals (Au, Pt, and Ru) loaded into carbon supports show excellent performance for CO oxidation. Herein, a tunable metal–organic framework (MOF) coating is applied to a macroscopic 3D Ru/graphene aerogel (Ru/GA) composite, using a facial step‐by‐step method. The open macroporous structure of the Ru/GA provides pathways for the access and diffusion of reactant and product molecules. The resulting HK (HKUST‐1)‐containing MOF composite exhibits good performance for CO adsorption. It can simultaneously adsorb and oxidize CO, which improves the reaction rate. In this work, the catalytic efficiency of the resulting catalyst is higher than that (≈48.4%) of the Ru/GA. These findings provide a simple method for increasing the instantaneous concentration of reactants around the catalyst, which in turn increases the reaction rate. The catalytic performances of composites subjected to different pretreatment conditions are also investigated. Hopefully, this finding may provide a feasible direction for the effective management of the diverse environment issues.