Modified g-C3N4 derived from ionic liquid and urea for promoting visible-light photodegradation of organic pollutants

In this work, modified g-C₃N₄ was fabricated successfully by calcination of ionic liquid (IL) and urea. The addition of IL changed the polymerization mode of urea, induced the self-assembly of urea molecules, modified the morphological structure of the tightly packed g-C₃N₄, and extended the electron conjugation system. When using 1-butyl-3-methylimidazolium chloride ([Bmim]Cl) as a modifier, the heteroatom Cl could be inserted into the g-C₃N₄ to optimize the electronic structure. The results of characterizations indicate that the unique structure of modified g-C₃N₄ has an expanded electron delocalization range, introduces an interlayer charge transmission channel, promotes the charge transmission, reduces the band gap, enhances the absorption of visible light, and inhibits electron-hole recombination. Modified g-C₃N₄ showed excellent photocatalytic performance for the degradation of rhodamine B and tetracycline. Furthermore, the effect of different anions in 1-butyl-3-methylimidazolium salts ([Bmim]Cl, [Bmim]Br, [Bmim][BF₄], and [Bmim][PF₆]) on the structure and function of g-C₃N₄ are discussed.     

基于FPGA的高压直流输电系统建模与实时仿真

高压直流HVDC(high-voltage direct current)输电技术的应用改变了传统输电网的形态与运行特性,大量高频电力电子设备的接入使得输电网动态特性更加复杂,通过实时仿真研究其复杂动态特性对于电网的运维具有重要意义.首先,基于现场可编程门阵列FPGA(field programmable gate array)设计了HVDC系统的实时仿真平台,确定了基于FPGA的HVDC实时仿真系统基本仿真框架.其次,提出了基于FPGA的晶闸管、变压器以及熄弧角检测模块等主要元件的建模方法,开发了基于FPGA的HVDC实时仿真系统.最后,以CIGRE HVDC系统为例,进行了步长5μs故障状态下的暂态实时仿真,验证了所提建模方法以及HVDC实时仿真系统的正确性与有效性.     

电力系统测控装置中功率频域算法优化

无功功率根据定义的不同,有多种不同的算法,但适合测控装置的频域算法计算过程复杂,引入误差的环节也较多.对此提出一种优化的频域算法,以减少计算环节,简化频域算法.首先,分析了频域算法中某固定频次下,有功功率和无功功率的算法,分解了计算过程.然后,通过对频域算法计算过程的拆解及三角函数转换,得出了电压、电流的实部、虚部与功率间的关系,得到了频域算法的优化算法.最后,将优化频域算法放入测控装置中运行,从试验数据可看出优化后的频域算法明显地减少了运算环节,降低了运算量,运算时间较优化前减少了约一半,同时经优化后的频域算法计算得出的功率值也能满足测控装置行业标准5‰的精度要求.     

工业烟气设备的防腐蚀浅析

详细阐述了工业烟气设备装置中的烟道、烟囱、洗涤塔等的腐蚀原理，并针对不同场合的情况分别讨论防腐蚀材料的选择及其结构形式，为工业烟气设备的防腐蚀提供可靠的处理方法。     

40Cr钢的补焊

40Cr钢是机械制造工业中常用的钢种之一，调质处理后，具有硬度高、塑性良好和低温冲击韧性、低的缺口敏感性及高疲劳强度。该钢还适合碳氮共渗和高频淬火处理，切削性能和淬透性好，但冷变形塑性和焊接性较差。常用来制造重要的高强度调质零件，如齿轮、轴、紧固件等。当零件磨损后，重新购进成本太高，经过大量的实践，总结出以下补焊方法。40Cr钢的化学成分见表1。     

NIT-Ph-p-BEN氮氧自由基的制备及催化降解性

以对醛基苯甲酸为原料，通过醛酸与2,3-二甲基-2,3-二羟胺基丁烷缩合，再经NaIO4氧化最终制得4-(4,4,5,5-四甲基-1,3-二氧化物)咪唑基-1-苯甲酸（NIT-Ph-p-BEN氮氧自由基）。采用FTIR、UV、ERP（电子顺磁共振波谱仪）和元素分析等对其结构进行表征；通过催化降解废水中有机染料甲基橙、甲基蓝和罗丹明B对其催化活性进行了评估。结果表明，当甲基橙、甲基蓝和罗丹明B浓度为15 mg/L，NIT-Ph-p-BEN质量浓度为0.15 g/L，H2O2浓度为30 mmol/L时，NIT-Ph-p-BEN对甲基橙有更好的催化降解性，仅在1 h内甲基橙的降解率达到94.26%。此外，反应机理表明，H2O2有助于实现NIT-Ph-p-BEN自由基的再生和循环利用。     

东风水库下游临岸潜流带水流场响应规律研究

水库下游临岸潜流带水流场响应规律可用于预测不同水库运行情景下临岸潜流带的水头与流量变化情况。本文以复州河东风水库为例,基于测量数据得到其下游某断面临岸潜流带的水头及流量响应过程,提出响应强度指标的概念,得到简单直观的响应规律经验公式,从而为该水库下游临岸系统的生态建设提供依据,并为水库运行方案的生态影响评价提供参考。     

On compatibility of uncertain multiplicative linguistic preference relations based on the linguistic COWGA

The aim of this work is to develop a new compatibility for the uncertain multiplicative linguistic preference relations and utilize it to determine the optimal weights of experts in the group decision making (GDM). First, the compatibility degree and compatibility index for the two multiplicative linguistic preference relations are proposed. Then, based on the linguistic continuous ordered weighted geometric averaging (LCOWGA) operator, some concepts of the compatibility degree and compatibility index for the two uncertain multiplicative linguistic preference relations are presented. We prove the property that the synthetic uncertain linguistic preference relation is of acceptable compatibility under the condition that the uncertain multiplicative linguistic preference relations given by experts are all of acceptable compatibility with the ideal uncertain multiplicative linguistic preference relation, which provides a theoretic basis for the application of the uncertain multiplicative linguistic preference relations in GDM. Next, an optimal model is constructed to determine the weights of experts based on the criterion of minimizing the compatibility index in GDM. Moreover, an approach to GDM with uncertain multiplicative linguistic preference relations is developed, and finally, an application of the approach to supplier selection problem with uncertain multiplicative linguistic preference relations is pointed out.     

基于退化四元小波变换的纸币识别

针对如何提取纸币图像特征和提高识别率的问题,综合利用退化四元小波变换具有的相位特性,提出一种基于退化四元小波变换的纸币识别方法.该方法首先对采集的纸币图像进行倾斜校正和边缘检测,然后运用退化四元小波对纸币图像进行分解操作,并对分解系数进行统计分析,将每个分解子带系数的能量和标准差作为该纸币图像的特征向量,最后将支持向量机作为分类器对纸币图像进行识别.本文方法在资源约束的嵌入式清分系统上实现,实验结果表明采用本文提出的算法突破了传统纸币识别系统识别率很难再提高的瓶颈,同时能够满足清分系统的实时性要求.     

新型绝缘树脂及应用

本文介绍了FUCHEM系列无溶剂绝缘树脂的性能及应用，着重探讨了产品的阻燃、低收缩、高耐腐蚀、高耐热等级等特性。