Effects of ethylene-octene copolymer (POE) on the brittle to ductile transition of high-density polyethylene/POE blends

Three kinds of ethylene-octene copolymers (POE) were melt-blended with high-density polyethylene (PE-HD) in different proportions. Detailed characterizations were conducted to analyze their structural differences of POE and its effects in toughening PE-HD. The higher molecular weight POE can improve the toughness of PE-HD. 60:40 PE-HD/POE is elongated to break up to 700% while impact strength is 84.7 kJ/m² at −30°C, which is 21-fold of PE-HD. In the brittle to ductile transition (BDT) during impact, the fracture mechanism changes from the crazing mode to the shear yield-plastic deformation mode. The BDT temperature decreases as the POE molecular weight and its content increase. The interface strength in tension is estimated to access their effects. The Boltzmann-type models were successfully extended to describe the typical S-shaped curves in BDT of notched impact strength vs POE content or temperature. The supplementary decay model is suggested for the attenuation in toughening. Transition map in impact is proposed to select the use range of composition (c ) and temperature (T ) for high toughness. The curves are converted into 3D graph of T -c -impact strength for illustrating their coupling-separate effects, and further into the contour map of impact strength in T -c space for finding their partial equivalence.     

Tuning effect of silicon substitution on magnetic and high frequency electromagnetic properties of R2Fe17 and their composites

In this work, we report the tuning effect of the Si substitution on the magnetic and high frequency electromagnetic properties of R₂Fe₁₇ compounds and their paraffin composites. It is found that the introduction of Si can remarkably improve the magnetic and electromagnetic properties of the R₂Fe₁₇ compounds, making the R₂Fe_17–xSi_x-paraffin composites excellent microwave absorption materials (MAMs). By introducing the Si element, their saturation magnetizations decrease slightly, while much higher Curie temperatures are obtained. Furthermore, better impedance match is reached due to the decrease of the high-frequency permittivity ε′ by about 40%–50%, which finally enhances the performance of the microwave absorption. The peak frequency (f_RL) of the reflection loss (RL) curve moves toward high frequency domain and the qualified bandwidth (QB, RL ≤ ?10 dB) increases remarkably. The maximum QB of 3.3 GHz (12.0–15.3 GHz) is obtained for the Sm_1.5Y_0.5Fe₁₅Si₂-paraffin composite (d = 1.0 mm) and the maximum RL of ?53.6 dB is achieved for Nd₂Fe₁₅Si₂-paraffin composite (d = 2.2 mm), both surpassing most of the reported MAMs. Additionally, a distinguished dielectric microwave absorption peak is observed, which further increases the QB in these composites.     

链轨节用钢15B36Cr的开发与试制

淮钢采用90 t顶底复吹转炉-LF-RH-200 mm×200 mm连铸-连轧工艺流程试生产了2炉Φ60 mm链轨节用钢15B36Cr(/%:0.30～0.37C、0.15～0.30Si、1.20～1.50Mn、≤0.040P、≤0.0505、0.20～0.40Cr、≤0.25Ni、≤0.35Cu、≤0.06Mo、0.0005～0. 0030B)。通过加严影响淬透性化学成分,控制出钢碳≥0.08%,转炉有效挡渣和下渣检测系统控制下渣,LF炉铝粒和电石渣面脱氧,RH最低真空度处理20～30 min,结晶器电磁搅拌、末端电磁搅拌和连铸低过热度保护浇铸等工艺措施,15B36Cr钢的化学成分稳定控制在内控范围内,除了B粗以外,其他类型非金属夹杂物级别全部控制在1.0以内,淬透性控制在较窄的范围内,试制钢种关键技术指标达到客户和预期设计要求。     

吴庄铁矿盘区间柱回采优化研究

基于吴庄铁矿盘间柱宽度不确定性、两侧均为充填体且高度大的现状，为安全高效回采盘区间柱，制定了盘区间柱两侧采场充填体取芯设计方案，并对充填体进行制样，进行了实验室试块抗压强度试验。试验结果表明：一步骤采场（矿柱）充填体强度整体符合设计强度要求，二步采场充填体强度整体偏低，盘区间柱宽度较设计变化较大，宽度极其不规整，整体呈上窄下宽的规律。鉴于盘区间柱宽度不规则、二步骤采场充填体强度低于预期、采场高度大和盘区间柱回采时不能大面积暴露的特点，采用留设一定厚度间柱和采用较小采场长度的措施进行回采方案制定，制定了小采场分段空场嗣后充填法回采方案。该方案的制定和实施，对于其他类似地下矿山三步骤间柱回采工程具有借鉴意义。     

户内热转印粉末涂料用混合型聚酯树脂的合成研究

通过分析热转印性能的影响因素合成了不同结构的聚酯树脂，研究了树脂酸值对热转印性能的影响，同时研究了部分单体对聚酯树脂热转印性能的影响。采用 DSC热分析法研究了固化促进剂对粉末涂料固化行为的影响，结果表明：选择合适的固化促进剂对涂层转印性能的提高有至关重要的作用。     

Corrosion behavior of Cu–Sn bronze alloys in simulated archeological soil media

The corrosion behavior of synthetic Cu–Sn bronze alloys with six different Sn contents was examined through an electrochemical test and a synthetic test in a simulated corrosive medium. The mechanism of corrosion and the morphology of the corroded surfaces were characterized through field emission scanning electron microscopy equipped with energy-dispersive spectroscopy. At the corrosion potential, the corrosion behavior appears to be determined by the charge transfer step and the diffusion process. It was found that the bronze-IV (Cu–26.8Sn) specimen exhibited the best corrosion resistance, as evidenced by a low corrosion current density and a high impedance. This improvement resulted from an increase in the content of the Cu–Sn solid solution in the alloy, which was conducive to forming a relatively more protective passive film on the surface of the bronze alloy. This finding would be valuable in the anticorrosion protection of archeological artefacts after their excavation.     

以辉锑矿为原料放电等离子烧结快速制备黝铜矿Cu_(12)Sb_4S_(13)及反应机理

采用辉锑矿为原料成功制备出Cu_(12)Sb_4S_(13)块体。研究以Sb_2S_3矿物为原料时烧结工艺对Cu_(12)Sb_4S_(13)合成的影响。在400 ～ 440℃温度区间内均可快速合成Cu_(12)Sb_4S_(13)块体且二次烧结能够进一步减小中间相CuSbS_2和Cu_3SbS_3。第二相Cu_3SbS_4和残留相CuS随着烧结时间的延长而降低。二次烧结前进行机械化球磨处理,干磨比湿磨更容易减小残留相。初次烧结块体的断面SEM和EDS能谱分析表明内部存在Cu或Cu_2S颗粒团聚现象。适当降低Cu或CuS摩尔量(化学计量比0.1 mol)能促进烧结块表面反应进行。烧结过程中,硫磺蒸汽压的导致烧结块表面成分和内部粉末的成分不同。     

惠州东江水利枢纽变电站优化设计

文章结合广东省惠州东江水利枢纽工程的具体情况,对110 kV变电站进行了优化设计,通过对110 kV变电站采用敞开式布置、主变与GIS同平面布置、主变与GIS采用两层布置的三种不同设备选型及布置方式的技术和经济比较,推荐采用主变与GIS同平面的布置方案.GIS的使用,不仅满足电站运行可靠、灵活及运行维护方便等要求,而且也加快了施工进度,与周围的环境融合在一起,增添了工程的亮点.     

Service composition for generic service graphs

Service composition is a promising approach to multimedia service provisioning, due to its ability to dynamically produce new multimedia content, and to customize the content for individual client devices. Previous research work has addressed various aspects of service composition such as composibility, QoS-awareness, and load balancing. However, most of the work has focused on applications where data flow from a single source is processed by intermediate services and then delivered to a single destination. In this paper, we address the service composition problem for multimedia services that can be modeled as directed acyclic graphs (DAGs). We formally define the problem and prove its NP hardness. We also design a heuristic algorithm to solve the problem. Our simulation results show that the algorithm is effective at finding low-cost composition solutions, and can trade off computation overhead for better results. When compared with a hop-by-hop approach for service composition, our algorithm can find composition solutions that aress 10% smaller in cost, even when the hop-by-hop approach uses exhaustive searches.