某大坝右岸防渗缺陷和新增防渗排水措施效果分析

某大坝是国内已建工程中覆盖层最深的,尤其是其右岸覆盖层最大深度达420 m。工程运行中发现右岸渗漏量较大,且右岸山坡地下水位整体偏高,局部山坡和排水廊道发生渗透破坏。结合工程现场检查情况和现有监测资料,对该大坝右岸渗流性状进行综合分析,分析渗水主要来源和途径、渗流稳定以及防渗系统存在的缺陷。根据现阶段右岸出现的问题,初拟两种防渗系统延长方式及新增排水廊道的处理方案,运用有限元对渗流场进行计算,对比分析两种初拟方案对减少渗漏量和降低地下水位的效果。结果表明在0+610~0+710底部新增封闭式防渗墙与帷幕灌浆,能有效减少渗漏量并能降低防渗系统右端沿线的水头,新增排水廊道排水孔能有效降低排水廊道附近的水头,对右岸边坡渗透稳定有利。所以,截渗与导排相结合是较为有效的防渗处理措施。     

不同促进剂对NR平衡硫化体系的影响

研究了促进剂的种类，促进剂并用及硫化温度等条件对平衡硫化体系（ＥＣ）硫化天然橡胶（ＮＲ）的影响。结果表明，噻唑类促进剂具有较低的硫化返原率，尤其是促进剂ＤＭ，在１３０～１７０℃的硫化温度范围内，硫化２小时的硫化返原率均为０；当促进剂ＮＯＢＳ或ＣＺ与ＤＭ并用时，可缩短正硫化时间；当ＤＭ摩尔分数分别为４０％和５０％左右时，不仅使硫化２小时的硫化返原率为０，而且可使３００％定伸应力保持恒定；以ＮＯＢＳ或ＣＺ为主促进剂时，正硫化时具有较高的拉伸强度和撕裂强度，但硫化２小时时的降低幅度比ＤＭ大。     

Robots learn to dance through interaction with humans

In this paper, we investigated an approach for robots to learn to adapt dance actions to human’s preferences through interaction and feedback. Human’s preferences were extracted by analysing the common action patterns with positive or negative feedback from the human during robot dancing. By using a buffering technique to store the dance actions before a feedback, each individual’s preferences can be extracted even when a reward is received late. The extracted preferred dance actions from different people were then combined to generate improved dance sequences, i.e. performing more of what was preferred and less of that was not preferred. Together with Softmax action-selection method, the Sarsa reinforcement learning algorithm was used as the underlining learning algorithm and to effectively control the trade-off between exploitation of the learnt dance skills and exploration of new dance actions. The results showed that the robot learnt, using interactive reinforcement learning, the preferences of human partners, and the dance improved with the extracted preferences from more human partners.     

单扫描极谱法快速测定胱氨酸的研究及应用

在pH 9.6的H3BO3-NaOH介质中,胱氨酸于-0.56 V(vs.SCE)处产生一灵敏的吸附还原波。用于胱氨酸的测定,波高与0.8~10μmol/L的胱氨酸有线性关系,检测限为0.4μmol/L。许多氨基酸在较高浓度共存情况下不干扰胱氨酸的测定。应用该法测定了人发及胱氨酸片剂中胱氨酸的含量。     

煤中吡啶型氮热解机理的量子化学研究

用密度泛函 ( DFT)方法 ,在 UB3LYP/6- 31 G( d)水平上研究了煤中吡啶型氮的热解机理 ,对热解过程中由于官能团周围环境的不同而形成的三类吡啶自由基进行了量子化学计算 ,通过对键的 Mulliken布居数等计算结果的分析 ,分别得到了这三类自由基的热解途径 .并优化得到了反应物、中间体和产物的几何构型 .计算结果表明 ,吡啶型氮主要是以 HCN的形式释放出来的 .NH3 是 HCN二次反应的产物 .     

防紫外线细旦丙纶DTY生产工艺

研究了防紫外线细旦丙纶DTY生产工艺及其对纤维性能的影响。选择变形速度 40 0～5 0 0m/min ,拉伸倍数 1.4～ 1.6,D/Y比 1.60 ,第一热箱温度 ( 15 0± 5 )℃ ,第二热箱温度 12 0～ 13 0℃ ,纤维品质优良 ,一等品率达 95 % ,紫外线遮挡率大于 99%。     

填料-旋流板脱硫塔在净化加压变脱改造中的设计与应用

阐述了以塑料阶梯环填料与带溢流锥双程叶片旋流塔板组合的新型复合脱硫塔的设计开发,其结构特点为旋流板塔板采用了双程叶片结构,溢流装置采用新型带螺旋叶片结构,塔上部设置高2.53m填料层,改进并优化了喷淋装置及气体进、出口结构等。通过实际应用,证明该型脱硫塔在净化加压变换气脱硫工序中的应用是成功的。     

聚丙烯发泡材料的研究进展

简要阐述了聚丙烯发泡材料的性能,分别从直接使用高熔体强度PP、化学交联/接枝改性、共混/填充改性这三种提高PP发泡性能的途径上对目前聚丙烯发泡材料的研究进展进行了介绍。     

不锈钢冶炼用不烧镁钙砖的研制及应用

介绍了冶炼不锈钢用不烧镁钙砖的研制过程及其在冶炼不锈钢的 90tAOD炉炉帽和 90t装入包包底的应用情况。结果表明 :在 90t装入包包底的使用寿命达 1 1 0次 ,最大侵蚀速度仅为 1 .50mm·次 -1 左右 ;在 90tAOD炉炉帽上的使用寿命达 2 1 7次 ,最大侵蚀速度仅 0 .55mm·次-1 ,但存在裂纹和剥落现象 ,今后应改进砖型设计 ,增加调整砖 ,以消除砌缝 ,提高衬砖的整体性和稳固性     

One‐step synthesis and ring‐opening polymerization of novel macrocyclic(arylene multisulfide) oligomers

A series of macrocyclic(arylene multisulfide) oligomers were synthesized under high dilution conditions by reacting diphenyl ether/diphenyl/diphenyl disulfide/diphenyl methane with dichloro disulfide in the presence of a trace amount of iron powder by a one‐step reaction. From MALDI‐TOF mass spectra, it was established that the repeating units of the cyclization ranged from two to seven and the unit of macrocyclic(arylene multisulfide) oligomers had one to seven sulfur atoms. The macrocyclic oligomers readily underwent ring‐opening polymerization in the melt, resulting in linear, high molecular weight polymultisulfides. DSC thermograms demonstrated that the four polymultisulfides, derived from the macrocyclic(arylene multisulfide) oligomers, are amorphous in nature. The macrocyclic(arylene multisulfide) oligomers and polymers were analyzed by MALDI‐TOF‐MS, IR, HPLC, NMR, DSC, and TGA methods. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 91: 735–741, 2004