MoSi2—Mo5Si3复合材料的低温氧化行为

通过热重分析（TGA）、X射线衍射（XRD）和扫描电镜（SEM）研究了MoSi2-Mo5Si3复合材料的低温氧化行为,指出材料低温氧化时,随Mo5Si3量增多,材料氧化加剧,当Mo5Si3含量超过16％（质量分数）时发生“PEST”现象,所形成的SiO2由于MoS3晶须的大量存在,使其不能均匀连续地分布于材料表面,从而加剧了氧化。     

水性聚氨酯木器漆中消泡剂的选用

水性聚氨酯木器漆极易产生气泡,影响其装饰性。通过系列试验,筛选出适宜的消泡剂,并确定其最佳用量。     

The mechanism of color reversion in soybean salad oil

An enzymatic reaction might be the major cause of color reversion in soybean oil. During the soybean flaking process, enzymatic reactions take place to convertγ-tocopherol to 5-(tocopheryloxy)-γ-tocopherol (γ-TED), and then further convertγ-TED to the precursors which are the cause of color reversion. The variations ofγ-tocopherol andγ-TED contents in soybean oil are accompanied by an inverse change in the precursors’ concentration. Therefore, the contents ofγ-tocopherol orγ-TED in crude soybean oil could be used as an index for predicting the color quality (color reversion) of soybean salad oil. Almost all the precursors (such as tocored) were converted to color-reverted substances under catalysis after bleaching treatment, and they were converted back to the precursors during deodorization. Those precursors might be gradually reconverted into the color reverted substances during storage to cause the color reversion in soybean salad oil.     

表达重组人可溶性TRAIL的毕氏酵母发酵工艺

目的优化rhsTRAIL毕氏酵母工程菌在5L发酵罐中的发酵表达工艺参数。方法研究培养基种类、细胞密度、甘油含量、pH值、甲醇浓度、甲醇流加速率及诱导时间等参数对工程菌生长及目的蛋白表达的影响,并用电镜观察其诱导肿瘤细胞凋亡特征。结果在无机盐培养基中,按10%接种A600=8～12的种菌后,24h酵母菌增殖至A600=76;甘油含量为1%时,菌体生长速度快(A600=160);培养基pH值5.0,甲醇终浓度为1%时,诱导96h表达量最高达到120mg/L,并具有诱导肿瘤细胞凋亡特征。结论rhsTRAIL毕氏酵母的发酵工艺参数为无机盐培养基,pH值5.0,接种10%A600=8～12的种菌,甘油含量1%,甲醇终浓度1%,诱导96h。     

相位测量定位法在焦炉车辆上的应用与研究

文中通过测量载波相位进行定位的方法来解决焦炉车辆的定位问题，以达到无线定位的目的。并对定位的数学模型进行了详细的分析与论述。     

The application of reactive dyes to cotton by a wet-on-wet cold pad-batch method

Cotton ha been dyed with reactive dyes by both wet-on-wet (WOW) and wet-on-dry (WOD) cold pad-batch processes, and by conventional exhaust methods. The colour yields, in terms of the Kubelka-Munk values as a function of the amount of fixed dye, showed that the WOW method required less fixed dye to produce a given depth of shade than the other methods. It is proposed that the higher colour yields are a consequence of limited dye penetration into the cotton fibre. Compared with exhaust dyeings, WOW and WOD dyeings were clearly ring dyed but, unfortunately, no definitive difference in the degree of dye penetration into the cotton fibres was found despite their colour yield differences. Although ring dyeings often have inferior fastness properties, the WOW dyeings were of equal or slightly superior fastness to repeated washing and to normal daylight in comparison with the other dyeings     

NHD脱硫液中总铁含量的测定

分析NHD脱硫溶液中的铁含量可以及时了解系统设备的腐蚀情况。采用双氧水消除脱硫溶液的颜色干扰,用盐酸羟胺将溶液中的Fe3 还原为Fe2 ,邻菲口罗啉与Fe2 生成稳定的橙红色络合物,用7230分光光度计可准确测定脱硫溶液中的总铁含量,标准偏差0.078,相对标准偏差为0.16。     

膜蒸馏用聚偏氟乙烯微孔膜的结构控制 Ⅲ.制膜条件的选择和膜蒸馏性能

为了提高聚偏氟乙烯微孔膜的膜蒸馏通量,本文对制膜条件进行了综合控制,在铸膜液中加入了丙酮溶胀剂,并采用乙醇水溶液作凝固浴。研究了挥发时间和凝固浴中乙醇含量对膜形态结构的影响。比较了由不同制膜条件制得的膜的膜蒸馏性能。结果表明,适当选择制膜条件,能得到膜蒸馏性能优良的膜。其截留率近于100%。在暖侧温度为55℃、冷侧温度为25℃时,膜的膜蒸馏通量可达22.5 kg/(m~2·h),已接近反渗透膜的水平。     

偶联剂对地砖用PVC填充材料相态结构和力学性能的影响

研究了钛酸酯类偶联剂和硅烷类偶联剂对钙矿、硅酸盐填充的PVC填允材料力学性能、相态结构、密度、热失重率及吸水伸长率和耐热阻燃性能的影响。结果表明,偶联剂可改善填充PVC的抗冲性能,降低其拉伸强度,扫描电镜分析表明,填料越细,分散越均匀,越易被PVC树脂所包覆,力学性能越好,研究得到了比重大、热失重率低、吸水伸长率小、阻燃耐烧灼性好的高填充PVC硬质塑料地板砖。     

Synthesis, characterization of bimetallic Sn-Zn-MCM41 and its catalytic performance in the hydroxylation of phenol

A series of Sn-Zn modified-MCM41 has been synthesized by direct hydrothermal method and characterized using ICP, XRD, TG/DTA, FT-IR, HRTEM and N_2-adsorption techniques. Catalytic performances of the obtained materials were evaluated in the hydroxylation of phenol with H₂O₂. Results indicated that all the samples exhibited typical hexagonal arrangement of mesoporous structure with high surface area and the heteroatoms were probably incorporated into the framework of MCM41. Catalytic tests revealed that the bimetallic incorporated materials were effective catalysts in the hydroxylation of phenol. The conversion of phenol could be reach to 56.8% for the catalysts with Sn: Zn: Si = 2.69: 4.57: 100 (molar ratio) under the optimized reaction conditions. Moreover, the materials containing Sn and Zn exhibited higher catalytic activity than monometallic Sn and Zn modified MCM41.