Constant-distance mode scanning potentiometry. 1. Visualization of calcium carbonate dissolution in aqueous solution

Constant-distance mode scanning potentiometry was established by integrating potentiometric microsensors as ion-selective scanning probes into a SECM setup that was equipped with a piezoelectric shear force-based tip-to-sample distance control. The combination of specially designed micrometer-sized potentiometric tips with an advanced system for tip positioning allowed simultaneous acquisition of both topographic and potentiometric information at solid/liquid interfaces with high spatial resolution. The performance of the approach was evaluated by applying Ca(2+)-selective constant-distance mode potentiometry to monitor the dissolution of calcium carbonate occurring either at the (104) surface of calcite crystals or in proximity to the more complex surface of cross sections of a calcium carbonate shell of Mya arenaria exposed to slightly acidic aqueous solutions. Micrometer-scale heterogeneities in the apparent calcium activity profiles have successfully been resolved for both samples.     

Calibration and evaluation of nitric acid and ammonia permeation tubes by UV optical absorption

An ultraviolet (UV) optical absorption system has been developed for absolute calibrations of nitric acid (HNO3) and ammonia (NH3) permeation tube emission rates. Using this technique, dilute mixtures containing NH3 or HNO3, both of which interact strongly with many surfaces, are accurately measured at levels below a part per million by volume. This compact and portable instrument operates continuously and autonomously to rapidly (<1 h) quantify the emission of trace gases from permeation devices that are commonly used to calibrate air-monitoring instruments. The output from several HNO3 and NH3 permeation tubes, with emission rates that ranged between 13 and 150 ng/min, was examined as a function of temperature, pressure, and carrier gas flow. Absorptions of 0.015% can be detected which allows a precision (3sigma) of +/-1 ng/min for the HNO3 and NH3 permeation tubes studied here. The accuracy of the measurements, which relies on published UV absorption cross sections, is estimated to be +/-10%. Measurements of permeation tube emission rates using ion chromatography analysis are made to further assess measurement accuracy. The output from the HNO3 and NH3 permeation tubes examined here was stable over the study period, which ranged between 3 months and 1 year for each permeation tube.     

Implementation of similarity model in the CSB system for chemical reaction predictions

A new algorithm for predicting the course of chemical reactions, implemented in the CSB system is presented. It allows to use of four various models for reaction generation, that lead to create different solution space according to the needs of the user. Depending on the chosen model one can expect solutions featuring great completeness or great reliability.     

Joint Source–Channel Communication for Distributed Estimation in Sensor Networks

Power and bandwidth are scarce resources in dense wireless sensor networks and it is widely recognized that joint optimization of the operations of sensing, processing and communication can result in significant savings in the use of network resources. In this paper, a distributed joint source-channel communication architecture is proposed for energy-efficient estimation of sensor field data at a distant destination and the corresponding relationships between power, distortion, and latency are analyzed as a function of number of sensor nodes. The approach is applicable to a broad class of sensed signal fields and is based on distributed computation of appropriately chosen projections of sensor data at the destination - phase-coherent transmissions from the sensor nodes enable exploitation of the distributed beamforming gain for energy efficiency. Random projections are used when little or no prior knowledge is available about the signal field. Distinct features of the proposed scheme include: (1) processing and communication are combined into one distributed projection operation; (2) it virtually eliminates the need for in-network processing and communication; (3) given sufficient prior knowledge about the sensed data, consistent estimation is possible with increasing sensor density even with vanishing total network power; and (4) consistent signal estimation is possible with power and latency requirements growing at most sublinearly with the number of sensor nodes even when little or no prior knowledge about the sensed data is assumed at the sensor nodes.     

Mitigating Circulating Common-Mode Currents Between Parallel Soft-Switched Drive Systems

A mathematical model that Is developed for a generalized drive system, including common-mode passive and active elements, is used to explore the issues of paralleling soft-switched resonant dc-link drive systems. Differences between the modulation pattern for each drive system cause common voltage disturbances, which lead to significant circulating currents between the drive systems. Control methods for actively compensating for common-mode circulating currents or reducing the common- mode voltage disturbances are investigated. Practical modifications to the drive system controls are implemented to reduce the circulating currents between paralleled systems.     

Using bottom surface reflectance to map coastal marine areas: a new application method for Lyzenga's model

Remote sensing is widely used in coastal management. Lyzenga's model has been traditionally used to explain the relationship between bottom surface reflectance and the radiance level measured by satellite. Due to its central assumption, this model lacks accuracy compared with the other radiative transfer models. Nonetheless, it enables, with a single and simple equation, representation of the multiple optical processes taking place in coastal areas. Mapping processes associated with this model may include radiometric correction, a technique previously pointed out as a major driver of mapping accuracy. Radiometric correction is generally based on a depth-invariant index, efficient for clear waters (Jerlov water type I to II) but largely unsuitable when transparency decreases (Jerlov water type II to III). In order to overcome this problem, we developed a new index for radiometric correction, which combines bathymetry data with attenuation coefficients. The improved efficiency of our model with regard to the traditional depth invariant index was demonstrated through two case studies: Funakoshi Bay (Japan; Jerlov water type II) and the Gabes Gulf part located off Mahares (Tunisia; Jerlov water type II to III).     

Proteins Marking the Sequence of Genotoxic Signaling from Irradiated Mesenchymal Stromal Cells to CD34+ Cells

Non-targeted effects (NTE) of ionizing radiation may initiate myeloid neoplasms (MN). Here, protein mediators (I) in irradiated human mesenchymal stromal cells (MSC) as the NTE source, (II) in MSC conditioned supernatant and (III) in human bone marrow CD34+ cells undergoing genotoxic NTE were investigated. Healthy sublethal irradiated MSC showed significantly increased levels of reactive oxygen species. These cells responded by increasing intracellular abundance of proteins involved in proteasomal degradation, protein translation, cytoskeleton dynamics, nucleocytoplasmic shuttling, and those with antioxidant activity. Among the increased proteins were THY1 and GNA11/14, which are signaling proteins with hitherto unknown functions in the radiation response and NTE. In the corresponding MSC conditioned medium, the three chaperones GRP78, CALR, and PDIA3 were increased. Together with GPI, these were the only four altered proteins, which were associated with the observed genotoxic NTE. Healthy CD34+ cells cultured in MSC conditioned medium suffered from more than a six-fold increase in γH2AX focal staining, indicative for DNA double-strand breaks, as well as numerical and structural chromosomal aberrations within three days. At this stage, five proteins were altered, among them IQGAP1, HMGB1, and PA2G4, which are involved in malign development. In summary, our data provide novel insights into three sequential steps of genotoxic signaling from irradiated MSC to CD34+ cells, implicating that induced NTE might initiate the development of MN.     

Convective cooling optimization of a blade for a supercritical steam turbine

This paper discusses the problem of blade cooling system optimization connected with conjugate heat transfer (CHT) analysis for reliable thermal field prediction within a steam cooled component. Since the full CHT solution, which involves the main flow, blade material and the coolant flow domains is computationally expensive from the point of view of optimization process, it was decided to reduce the problem by fixing the boundary conditions at the blade surface and solving the task for the interior only (both solid material and coolant). Such assumption, on one hand, makes the problem computationally feasible, and on the other, provides more reliable thermal field prediction than it used to be with the empirical relationships.The analysis involves shape optimization of internal cooling passages within an airfoil. The cooling passages are modeled with a set of four Bezier splines joined together to compose a closed contour. Each passage is fed with cooling steam of constant parameters at the inlet. In the present study the airfoil profile is taken as aerodynamically optimal. The search problem is solved with evolutionary algorithm and the final configuration is to be found among the Pareto optimal cooling candidates.