载体焙烧温度对Ni/SiO2-Al2O3催化剂稳定性的影响

为了获得高水热稳定的负载Ni催化剂,延长催化剂在含水液相体系中的使用寿命,以不同温度焙烧的SiO₂-Al₂O₃为载体,采用浸渍法制备Ni/SiO₂-Al₂O₃催化剂,通过吡啶-原位傅立叶变换红外光谱、X射线衍射、NH₃-程序升温脱附和H₂-程序升温还原等方法进行表征,以水相1,4-丁炔二醇加氢为探针反应,研究载体焙烧温度对Ni/SiO₂-Al₂O₃催化剂催化加氢性能及含水体系中稳定性的影响。结果表明,在(400~800) ℃,随着载体焙烧温度升高,活性组分Ni存在状态及催化剂加氢活性变化较小,但催化剂的水热稳定性下降,造成这一现象的原因是随着载体焙烧温度升高,载体表面SiO₂聚集,暴露的Al³⁺增加,载体水合程度增大。载体焙烧温度400 ℃时,Ni/SiO₂-Al₂O₃催化剂表现出最佳的水热稳定性。     

工业苯酚丙酮装置氧化尾气的气相色谱分析

采用质量分数2.5%的邻苯二甲酸二壬酯和质量分数2.5%的硅藻土,以chromsorb G·DMCX(150~180μm)为担体的色谱填充柱进行分离,氢火焰离子化检测器进行检测,用峰面积外标法进行定量分析,同时对工业苯酚丙酮装置氧化尾气组成进行气相色谱分析。对色谱柱的选择、操作条件的优化、定性、定量分析,进样量和线性范围、最低检测限等实验项目进行了考察,实验结果表明此方法具有操作简单、分析速度快、分析成本低、重复性与准确性好等特点。     

国内ABS装置及产品分析

作者从生产工艺技术、产品结构、市场应用、产品性能、装置产能产量等方面,对比分析了国内主要ABS生产厂家的技术实力及市场地位。介绍了中国石油吉林石化公司通过引进技术扩建ABS装置,产能达到58万t/a,产品结构逐渐丰富完善,既发挥了原有0215A牌号的品牌优势,又从产能和产品种类方面提高了企业竞争力。目前吉林石化公司ABS产品综合能力已经达到国内第3的水平。     

A CCD-based reader combined with CdS quantum dot-labeled lateral flow strips for ultrasensitive quantitative detection of CagA

Immunochromatographic assays are widely used to detect many analytes. CagA is proved to be associated closely with initiation of gastric carcinoma. Here, we reported that a charge-coupled device (CCD)-based test strip reader combined with CdS quantum dot-labeled lateral flow strips for quantitative detection of CagA was developed, which used 365-nm ultraviolet LED as the excitation light source, and captured the test strip images through an acquisition module. Then, the captured image was transferred to the computer and was processed by a software system. A revised weighted threshold histogram equalization (WTHE) image processing algorithm was applied to analyze the result. CdS quantum dot-labeled lateral flow strips for detection of CagA were prepared. One hundred sera samples from clinical patients with gastric cancer and healthy people were prepared for detection, which demonstrated that the device could realize rapid, stable, and point-of-care detection, with a sensitivity of 20 pg/mL.     

新型城镇化背景下开发区转型发展的模式与策略探讨* ——基于苏州案例的比较

开发区转型是推进新型城镇化的重要内容之一,如何提高转型发展的质量,需要进一步明确转型的路径、模式及相关策略.本文回溯苏州开发区发展的历程,通过案例比较总结开发区发展的两种模式,提出以建设“综合性城区”为目标,构建产业、人居、生态三相互动的转型发展模式,并提出转型中若干具体的优化策略.     

骨料砂浆交界面劈裂损伤声发射特性试验研究

为了研究骨料砂浆交界面损伤破坏过程的损伤特征进而分析其损伤机理,采用全数字化声发射采集系统监测了其整个劈裂损伤破坏过程.在对所伴生的声发射信号进行全面系统分析的基础上,从声发射累积特性、声发射单参数时程变化规律、声发射组合参数变化规律等方面对交界面损伤过程的典型声发射特性进行了研究,这对识别混凝土损伤演化规律和损伤的物理机理都具有重要参考价值.     

试论工程监理与工程项目管理的关系

随着我国工程建设的不断发展,工程监理也逐渐向着工程项目管理的方向转变,工程项目管理将会进一步提升整个项目建设的经济效益和社会效益,成为当前工程管理发展的新方向。本文就工程监理与工程项目管理的关系进行了相关的探讨和分析。     

多锤头碎石化基层直接加铺沥青路面的关键问题研究

本文对旧水泥混凝土路面多锤头碎石化后直接加铺沥青路面的适用条件、检测验收方法进行了总结,并对路面改造中容易导致路面病害的一些关键问题提出了解决方案,为沥青路面碎石化柔性基层的设计施工提供了技术参考。     

提高高温差地区40 m曲线箱梁外观质量一次合格率

混凝土构造物中出现外观质量问题是混凝土施工过程中最为常见的质量通病。在较为恶劣的施工环境下提高外观质量合格率这一问题不仅具有现实意义,同时对今后西部地区的类似工程施工也具有促进作用。     

A Low-Complexity Compressive Sensing Algorithm for PAPR Reduction

One of the major challenges in orthogonal frequency division multiplexing system is its high peak-to-average-power ratio (PAPR). Among the existing PAPR reduction technologies, clipping is the most often used one due to its simplicity of implementation. But it induces signal distortion. In this paper, we propose a new PAPR reduction method which introduces compressive sensing theory to help the clipping and signal recovery processes. Our method has superior symbol-error-rate (SER) performance compared with traditional clipping, and at the same time has better PAPR reduction performance compared with traditional tone reservation based algorithms. What is more, different from the existing high-complexity compressive sensing based scheme which tries to solve an optimization problem, the proposed algorithm uses orthogonal matching pursuit scheme to recover the distorted signals, thereby it significantly reduces the computational complexity with the same PAPR reduction efficiency. Simulation results show that our proposed scheme can achieve dramatic PAPR reduction with only about \(10\,\%\) of the existing method, while still keeps good SER performance.