The potentiometric behaviour of copolymers of methacrylic acid in water-ethanol solutions

Summary The synthesis is reported of copolymers of styrene with methacrylic acid and of methyl methacrylate with methacrylic acid by radical copolymerization, of copolymers of methyl methacrylate with methacrylic acid by partial alkaline hydrolysis of poly(methyl methacrylate), and of block copolymers of styrene with methacrylic acid. Modified titration curves of all these copolymers were recorded in water and water-ethanol solutions. In a solution containing 50 mass.% ethanol, only small differences could be observed between the potentiometric behaviour of the individual copolymers and polymethacrylic acid. Also, there were no essential differences in any of the solvents used between the potentiometric behaviour of block copolymers of styrene with methacrylic acid, on the one hand, and polymethacrylic acid, on the other. On the contrary, maxima and minima were always observed on the modified titration curves of statistical copolymers with a higher content of the hydrophobic comonomer in solutions with a high water content. Thus, using the modified titration curves, it is possible to decide whether a given copolymer is of the block or statistical type.     

Influence of air oxidation on the pressure exerted by coking coals during carbonization

The effects of air oxidation of three Spanish coals on the pressure exerted during carbonization have been studied. Coals were oxidized by air in an oven at 120 and 140 °C. The extent of oxidation was assessed by the Audibert-Arnu dilatometer test. Coal samples oxidized at different levels were subjected to the Koppers-lncar laboratory coking pressure test. The results obtained indicated that for coals classified as ‘dangerous’ the ‘danger’ increased and reached a maximum at a certain level of oxidation, after which it decreased sharply. This behaviour did not occur with coals classified as safe.     

节约型高校建设对策探析

讨论节约型高校建设的现实价值以及节约型高校建设的问题和成因,从思想政治教育、科学管理、科研创新、典型示范的角度出发,论述了加强节约型高校建设的对策。     

海南某大跨斜拉桥抗震性能分析

采用三主梁精细有限元模型对海南某斜拉桥的地震响应进行计算分析.进行了反应谱和几何非线性时程分析法地震响应的对比分析.计算结果表明:该桥的桥塔刚度满足要求,主梁刚度基本满足要求,主梁顺桥向的弹性约束和阻尼装置对减小顺桥向位移有一定的作用,但在罕遇地震作用下存在动力失稳的可能性,因此对主梁位移的限制应更严格,从而提高其整体的抗震性能.     

烟气冷凝热能回收利用装置烟气流动方式优化研究

烟气冷凝热能回收利用装置中烟气的分布与流动对换热起着重要作用,为优化烟气冷凝热能回收利用装置,保证烟气能够在装置中分布均匀、充分换热,分别设计两种烟气流动方式,采用CFD软件Fluent模拟了烟气冷凝热能回收利用装置中的流场及温度场,并将其分别应用于实际工程进行现场实测.结果表明,采用渐变断面设计的烟气流动方式,烟气在换热面上分布更均匀,更有利于强化换热,阻力更小,节能率比采用等高断面最大可提高3.25%,可有效降低和消除噪音.     

齐鲁文化精神对中国传统体育文化的影响

本文主要论述了齐鲁文化所表现出来的和合精神、人道主义精神、厚德仁民精神、大公无私精神、自强不息精神等,对中国传统体育文化产生的重要影响。     

Dielectric and pyroelectric characteristics of the infrared sensitive (Pb1?xSrx)TiO3 ceramics

PST ferroelectric ceramics were fabricated successfully by a two-step method, i e first, PbTiO₃ and SrTiO₃ were sintered respectively, then mixed and sintered together. The process and characteristics of PST ferroelectric ceramics were introduced and researched. Their dielectric and pyroelectric characteristics are as follows dielectric constant 10⁴ order, low dielectric loss (lower than 3.0% in the working frequency range of 1–1 000 kHz), saturation polarization intensity 10⁻¹ C/m² order, and pyroelectric coefficient 10⁻³ C/m²·K order.     

最大Lyapunov指数实现局域网流量的预测

由于网络中存在复杂的非线性动力学特性,基于混沌理论,采用最大Lyapunov指数对局域网络流量序列进行预测分析,能够实现较早地预测出网络流量的突变特性.首先,采用相空间重构理论,并结合C-C算法将实际测试的流量时间序列投影到重构的相空间中.然后,计算其最大Lyapunov指数并对最大可预测时间进行了分析,同时对预测算法进行了研究.最后,对实际测试的局域网流量序列分别采用点预测和区间预测方法进行了分析.仿真结果显示,采用点预测方法对流量突变可以进行有效预测,突变越剧烈预测越准确;而采用区间预测可以有效预测流量的变化趋势,但不适用于广域网环境.进一步表明此方法能有效地利用所有数据信息进行预测,预测效果准确、可靠,可广泛的用于网络拥塞和网络攻击中.     

Preparation and electrochemical characterization of activated carbons by chemical-physical activation

A process was proposed based on the combination of chemical and physical activation for the production of activated carbons used as the electrode material for electric double layer capacitor (EDLC). By material characterization and electrochemical methods, the influences of the activitation process on the specific surface area, pore structure and electrochemical properties of the activated carbons were investigated. The results show that specific surface area, the mesopore volume, and the specific capacitance increase with the increase of the mass ratio of KOH to char (m(KOH)/m(char)) and the activation time, respectively. When m(KOH)/m(char) is 4.0, the specific surface area and the mesopore volume reach the maximum values, i.e. 1 960 m²/g and 0.308 4 cm³/g, and the specific capacitance is 120.7 F/g synchronously. Compared with the chemical activation, the activated carbons prepared by chemical-physical activation show a larger mesopore volume, a higher ratio of mesopore and a larger specific capacitance. Foundation item: Project(2007BAE12B01) supported by the National Key Technology Research and Development Program of China     

基于OFDM的认知无线电系统中的功率分配改进

基于正交频分复用(OFDM)的认知无线电系统中,次用户子载波功率的泄漏会对主用户产生干扰.针对这一问题,提出了一种改进的功率分配方法,即在主、次用户所在子信道间合理设置保护带条件下,采用迭代分块注水算法.仿真结果表明,改进的算法满足各主用户干扰功率上限的条件下,也使得次用户信道容量最大化.