Chemical vapor deposition of amorphous ruthenium-phosphorus alloy films

Chemical vapor deposition growth of amorphous ruthenium-phosphorus films on SiO₂ containing ∼ 15% phosphorus is reported. cis-Ruthenium(II)dihydridotetrakis-(trimethylphosphine), cis-RuH₂(PMe₃)₄ (Me = CH₃) was used at growth temperatures ranging from 525 to 575 K. Both Ru and P are zero-valent. The films are metastable, becoming increasingly more polycrystalline upon annealing to 775 and 975 K. Surface studies illustrate that demethylation is quite efficient near 560 K. Precursor adsorption at 135 K or 210 K and heating reveal the precursor undergoes a complex decomposition process in which the hydride and trimethylphosphine ligands are lost at temperatures as low at 280 K. Phosphorus and its manner of incorporation appear responsible for the amorphous-like character. Molecular dynamics simulations are presented to suggest the local structure in the films and the causes for phosphorus stabilizing the amorphous phase.     

VLSI architectural design tradeoffs for sliding-window log-MAP decoders

Turbo codes have received tremendous attention and have commenced their practical applications due to their excellent error-correcting capability. Investigation of efficient iterative decoder realizations is of particular interest because the underlying soft-input soft-output decoding algorithms usually lead to highly complicated implementation. This paper describes the architectural design and analysis of sliding-window (SW) Log-MAP decoders in terms of a set of predetermined parameters. The derived mathematical representations can be applied to construct a variety of VLSI architectures for different applications. Based on our development, a SW-Log-MAP decoder complying with the specification of third-generation mobile radio systems is realized to demonstrate the performance tradeoffs among latency, average decoding rate, area/computation complexity, and memory power consumption. This paper thus provides useful and general information on practical implementation of SW-Log-MAP decoders.     

Study of warpage due to P-V-T-C relation of EMC in IC packaging

There were many studies about the prediction of warpage due to thermal mismatch , . However, cure induced warpage is usually ignored and the results can be inaccurate. To minimize this problem, a thorough understanding of epoxy molding compound (EMC) with pressure-volume-temperature-cure (P-V-T-C) relation is necessary. This paper used the P-V-T-C relation of an encapsulation material to formulate the stress-strain relationship. With the help of finite element method (FEM) and mold flow analysis, warpage predictions combined with P-V-T-C relation were performed and the results show that this approach is practical. For a given P-V-T-C relation, the shrinkage direction is pointing toward the gate and maximum warpage usually occurs at the boundary of an integrated circuit (IC) package. Variation of specific volume difference along the flow direction is larger than that perpendicular to the flow direction. When temperature difference is small in thickness direction, specific volume difference in thickness direction varies only slightly.     

Determinants of Corporate R&D Investment: An Empirical Study Comparing Korea's IT Industry with Its Non‐IT Industry

In our study, we extracted the market, finance, and government factors determining R&D investment of individual firms in the IT industry in Korea. We collected the financial data of 515 individual firms belonging to IT and non‐IT industries between 1980 and 1999 from the Korea Investors Service's database and investigated the empirical relationship between the factors using an ordinary regression model, a fixed effects model, and a random effects model. The main findings of our study are as follows: i) The Herfindahl Index variable representing the degree of market concentration is statistically insignificant in explaining R&D expenditures in the IT manufacturing industry. ii) Assets, which is used as a proxy variable for firm size, have a positive and statistically significant coefficient. These two results suggest that the Schumpeterian Hypothesis may be only partially applied to the IT manufacturing industry in Korea. iii) The dividend variable has a negative value and is statistically significant, indicating that a tendency of high dividends can restrict the internal cash flow for R&D investment. iv) The sales variable representing growth potential shows a positive coefficient. v) The subsidy as a proxy variable for governmental R&D promotion policies is positively correlated with R&D expenditure. This suggests that government policy has played a significant role in promoting R&D activities of IT firms in Korea since 1980. vi) Using a dummy variable, we verified that firms reduced their R&D investments to secure sufficient liquidity under the restructuring pressure during Korea's 1998 and 1999 economic crisis.     

Plastic deformation in a multifunctional Ti-Nb-Ta-Zr-O alloy

Mechanisms for plastic deformation in the newly developed Ti-24 at. pct (Ta + Nb + V)-(Zr,Hf)-O alloys (Gum Metal) were investigated in relation to their unique properties. Transmission electron microscopy revealed that the microstructure after deformation was characterized by highly distorted crystal images, which are accompanied by numerous “giant faults.” Such plastic behavior implies that a large amount of elastic stain energy was stored discretely and hierarchically during cold working. Calculated elastic constants of the Ti-X (Nb,Ta,Mo,V) binary systems predicted that Young’s modulus in 〈001〉 and shear moduli along some directions including slip systems in a bcc crystal were extraordinary small. The low modulus not only well explains the highly distorted microstructure observed in the cold-worked specimens, but also signifies that ideal shear strength of the developed alloys is a very small value, which is close to the practical strength required for plastic deformation in the alloy. This implies that the giant faults observed in the deformed specimen were formed without the aid of dislocation glide.     

On Striping Traffic over Multiple IEEE 802.11(b) Wireless Channels

Due to interference, path loss, multipath fading, background noise, and many other factors, wireless communication normally cannot provide a wireless link with both a high data rate and a long transmission range. To address this problem, striping network traffic in parallel over multiple lower-data-rate but longer-transmission-range wireless channels may be used. In this paper, we propose a new striping method and evaluate its performances over multiple IEEE 802.11(b) channels under various conditions. Our extensive simulation results show that this method is quite effective for such an application. S.Y. Wang is an Associate Professor of the Department of Computer Science and Information Engineering at National Chiao Tung University, Taiwan. He received his Master and Ph.D. degree in computer science from Harvard University in 1997 and 1999, respectively. His research interests include wireless networks, Internet technologies, network simulations, and operating systems. He is the author of the NCTUns 2.0 network simulator and emulator, which is being widely used by network and communication researchers. More information about the tool is available at http://NSL.csie.nctu.edu.tw/nctuns.html. C.H. Hwang received his master degree in computer science from NCTU in 2002 and currently is working for a network company. C.L. Chou currently is a third-year Ph.D. student at the Department of Computer Science and Information Engineering, National Chiao TungUniversity (NCTU), Taiwan. He received his master degree in computer science from NCTU in 2002.     

Efficient OVSF code assignment and reassignment strategies in UMTS

This paper presents an integrated solution for code management, assignment, and reassignment problems in UMTS. We propose a new architecture for code management and, based upon this new architecture, a code assignment strategy, referred to as "crowded-group first strategy". Our system architecture and code assignment strategy represent significant improvements both in the time complexity and the maintenance complexity. Moreover, the code blocking probability of the crowded-group first strategy is competitive to that of the other strategies. In this paper, we also propose a new code reassignment strategy, called the "crowded-branch first strategy". The main objective of this reassignment strategy is to reduce reassigned call probability with low computation overhead and extend this strategy for the general case. In order to systematically analyze the performances of the code assignment strategy, we implement a simulator to analyze the code selection behavior and code blocking probability of each strategy. Moreover, we propose some new performance metrics, named "weighted code blocking", "reassigned call probability", and "ratio of actual code reassignments", in order to precisely measure the performance obtained by different strategies. From the simulation results, we show that our proposed strategies efficiently utilize the OVSF codes with low computation overhead.     

Adaptive median filters: new algorithms and results

Based on two types of image models corrupted by impulse noise, we propose two new algorithms for adaptive median filters. They have variable window size for removal of impulses while preserving sharpness. The first one, called the ranked-order based adaptive median filter (RAMF), is based on a test for the presence of impulses in the center pixel itself followed by a test for the presence of residual impulses in the median filter output. The second one, called the impulse size based adaptive median filter (SAMF), is based on the detection of the size of the impulse noise. It is shown that the RAMF is superior to the nonlinear mean L(p) filter in removing positive and negative impulses while simultaneously preserving sharpness; the SAMF is superior to Lin's (1988) adaptive scheme because it is simpler with better performance in removing the high density impulsive noise as well as nonimpulsive noise and in preserving the fine details. Simulations on standard images confirm that these algorithms are superior to standard median filters.