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71.
Jun Rong Li Jun Wang Jia Rui Xu Ming Qiu Zhang Min Zhi Rong Qiang Zheng 《Composites Science and Technology》2006,66(16):3126-3131
The authors of this paper synthesized a series of amphiphilic triblock copolymers of polystyrene-b-poly(ethylene glycol)-b-polystyrene (PS-PEG-PS) having different PEG/PS ratios with nearly identical molecular weights of the entire copolymers. The interfacial interactions in the composites consisting of carbon black and the copolymers can thus be tailored. When these conducting composites are exposed to certain solvent vapors, their electrical resistances greatly increase, showing the gas sensitivity. The present work indicated that this switching behavior is controlled by the structural relaxation of the composites because matrix swelling acts as the main mechanism. The response time has been correlated with absolute temperature by Arrhenius equation, and the estimated activation energy reflects mobility of the fillers involved in the solvent induced expansion of the surrounding polymer. Therefore, by using the gas sensibility of the conductive composites, the structure evolution of the composite materials in solid state and the effect of filler/matrix interfacial interaction on the relaxation property of the matrix polymer has been inspected. It was found that lower activation energy represents stronger interfacial interaction in case good solvent of the matrix was used for the test. 相似文献
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74.
Biomimetic synthesis of spherical nano-hydroxyapatite in the presence of polyethylene glycol 总被引:1,自引:0,他引:1
Spherical nano-hydroxyapatite (nano-HA) was synthesized successfully by a biomimetic method using Ca(NO3)2·4H2O and (NH4)3PO4·3H2O as reagents in the presence of polyethylene glycol (PEG). The crystalline phase, microstructure, chemical composition, and morphology of the obtained samples were characterized by X-ray powder diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and transmission electron microscopy (TEM). The results show that spherical nano-HA with diameter of 30–50 nm can be synthesized in the presence of a certain concentration (2–6%) of PEG. The crystallinity of HA powder synthesized in the presence of PEG was higher than that synthesized in the absence of PEG, but the crystallinity of HA reduced with increasing the concentration of PEG. The electrical conductivity (EC) of the solution revealed that PEG reduced the transfer rate of Ca2+ in the process of HA crystallization, indicating the interaction between PEG and HA. The possible mechanism of formation spherical nano-HA was discussed. 相似文献
75.
A new efficient numerical method and the dynamic analysis of composite laminates with piezoelectric layers 总被引:1,自引:0,他引:1
Firstly, a numerical method for the inversion of Laplace transform is developed and its accuracy is shown through examples. Then, a state-vector equation for the dynamic problems of piezoelectric plates is deduced directly from a modified mixed variational principle for piezoelectric bodies and its exact solution for the dynamic problems of simply supported rectangle piezoelectric plate is simply given. For multilayered hybrid plates, we derive the solution in terms of the propagator matrices. The techniques accounts for the compatibility of generalized displacements and generalized stresses on the interface both the elastic layers and piezoelectric layers, and the transverse shear deformation and the rotary inertia of laminate are also considered in the global algebraic equation of structure. Meanwhile, there is no restriction on the thickness and the number of layers. As an application of the numerical inversion of Laplace transform presented in this paper, typical numerical examples of the harmonic vibration and transient response are proposed and discussed. Since the highly accurate numerical results, they can serve as benchmarks to test various thick plate theories and various numerical methods, such as the finite and boundary element methods for transient response problems. 相似文献
76.
A series of novel block polymers of polyurethane (PU) and chitosan have been prepared in two steps. The first step is the preparation of PU prepolymer, obtained from polytetramethylene oxide glycol (PTMO, Mn = 1000), isophrone diisocyanate (IPDI), and 2,2′-dimethylol propionic acid (DMPA), followed by ionizing PU prepolymer with triethylamine (TEA). The second step involves PU chain-extended by water-soluble chitosan of low molecular weight (Mn = 5000) by self-emulsion polymerization method. The sizes of the latex particles, morphology, and copolymer architecture have been characterized by dynamic light scattering (DLS), general tensile test, infrared spectroscopy (IR), surface contact angle measurement, and transmission electron microscopy (TEM). Furthermore, it shows that the addition of chitosan remarkably increases anticoagulative property of PU elastomers confirmed by the recalcification time. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
77.
��չ����Ȼ��Ϊԭ�ϵ�ȼ�ϵ������ 总被引:6,自引:0,他引:6
研究燃料汽车及其氢源系统是当今国内外能源工业与汽车工业的共同课题,而优选制氢能源则是这一课题的关键。章介绍了利用能源、经济、环境(EEE)——生命周期评估(LCA)这一综合评估方法,针对以天然气、煤或石油作为制氢能源的多种燃料电池氢源供应方式以及配套的燃料电池汽车系统,从经济性、能源利用效率和环境影响三个方面进行了生命周期清单分析和EEE综合评价。结果显示:天然气作为发展燃料电池汽车氢源的一次能源,具有氢制取技术路线多样化、经济上竞争力强、能源利用效率高和环境效益好等诸多优势,应为燃料电池汽车的首选制氢能源。对这一评估模型的敏感性分析显示,即使在天然气价格波动较大时,天然气制甲醇--甲醇车载重整车和天然气制氢--纯氢车这两个方案仍然最具优势。 相似文献
78.
79.
In this paper, a new dynamic developable surface model is proposed. The proposed model represents developable surfaces using triangle meshes. A novel algorithm is proposed to introduce the Hamilton principle into these meshes such that the resulting developable model is dynamic, i.e., it can offer a time-dependent continuous path to deform the model. Applications with examples are presented; these show that the proposed technique can model buckled developable surfaces well, and can offer physically-realistic animations of deformed developable surfaces. 相似文献
80.
介绍了使用HMS87C1408B作为主控芯片的籽棉、菜籽和粮食水分综合测试仪的实现方法,重点说明了阻抗变换、软件驱动LCD和语音播报技术的实施. 相似文献