Effects of a bolaform electrolyte on the sorption of acid dyes by a silk fibre

The sorption behaviour of sodium 1-phenylazo-2-hydroxy-6-naphthalenesulphonate and sodium 1-(3-methylphenylazo)-2-hydroxy-6-naphthalenesulphonate by a silk fibre was investigated in the presence and absence of a bolaform electrolyte. The addition of the bolaform electrolyte influenced the dye sorption to an extent that was dependent on the pH of the dyebath. At pH 3 the amount of dye sorbed by the silk fibre decreased slightly with increasing bolaform electrolyte concentration, while at pH 4 and in pure water it increased. The sorption parameters determined from the sorption isotherms considering the dual sorption mechanism were affected by the addition of the bolaform electrolyte: most importantly, the partition coefficients were significantly enhanced. Furthermore, the effects of the bolaform electrolyte on the dye sorption by the silk fibre were quite different to those seen with a nylon 6 film.     

Space–time blending

Shape transformation between objects of different topology and positions in space is an open modelling problem. We propose a new approach to solving this problem for two given 2D or 3D shapes. The key steps of the proposed algorithm are: increase dimension by converting two input kD shapes into half‐cylinders in (k+1)D space–time, applying bounded blending with added material to the half‐cylinders, and making cross‐sections for getting intermediate shapes under the transformation. The additional dimension is considered as a time coordinate for making animation. We use the bounded blending set operations in space–time defined using R‐functions and displacement functions with the localized area of influence applied to the functionally defined half‐cylinders. The proposed approach is general enough to handle input shapes with arbitrary topology defined as polygonal objects with holes and disjoint components, set‐theoretic objects, or analytically defined implicit surfaces. The obtained unusual amoeba‐like behaviour of the shape combines metamorphosis with the non‐linear motion. Copyright © 2004 John Wiley & Sons, Ltd.     

Novel Synthesis of Mullite Powder with High Surface Area

Boehmite (AlO(OH)) solid-solution gel, which yields stoichiometric mullite (3Al₂O₃2SiO₂) at high temperatures, has been prepared by the hydrazine method. The formation process leading to 3Al₂O₃2SiO₂ is discussed. The as-prepared powder and powders heated below 1200°C consist of very fine particles showing needlelike morphology, whereas the particles of mullite powder show thin prismatic morphology. The mullite powder after heating at 1300°C has a high surface area (87 m²/g).     

Characterization of Ti/Si binary oxides prepared by the sol-gel method and their photocatalytic properties: The hydrogenation and hydrogenolysis of CH3CCH with H2O

Titanium-silicon (Ti/Si) binary oxides having different Ti content were prepared by the sol-gel method and utilized as photocatalysts for the hydrogenation and hydrogenolysis of CH₂CCH with H₂O. The photocatalytic reactivity and selectivity of these catalysts were investigated as a function of the Ti content and it was found that the hydrogenolysis reaction (C₂H₆ formation) was predominant in regions of low Ti content, while the hydrogenation reaction (C₃H₆ formation) proceeded in regions of high Ti content. The in situ photoluminescence, diffuse reflectance absorption, FT-IR, XAFS (XANES and EXAFS), and XPS spectroscopic investigations of these Ti/Si binary oxides indicated that the titanium oxide species are highly dispersed in the SiO₂ matrices and exist in a tetrahedral coordination exhibiting a characteristic photoluminescence spectrum. The charge transfer excited state of the tetrahedrally coordinated titanium oxide species plays a significant role in the efficient photoreaction with a high selectivity for the hydrogenolysis of CH₃CCH to produces mainly C₂H₆ and CH₄, while the catalysts involving the aggregated octahedrally coordinated titanium oxide species show a high selectivity for the hydrogenation of CH₃CCH to produce C₃H₆, being similar to reactions of the powdered TiO₂ catalysts. The good parallel relationship between the yield of the photoluminescence and the specific photocatalytic reactivity of the Ti/Si binary oxides as a function of the Ti content clearly indicates that the high photocatalytic reactivity of the Ti/Si binary oxides having low Ti content is associated with the high reactivity of the charge transfer excited state of the isolated titanium oxide species in tetrahedral coordination, [Ti³⁺-O⁻]*.     

Charging characteristics of construction materials of spacecraft irradiated by an electron beam

Composite materials like carbon fiber‐reinforced plastics (CFRP) or fiber‐reinforced plastics (FRP) are used for construction materials of spacecraft. When FRP are used for construction materials of spacecraft, germanium (Ge)‐sputtered FRP is used because of its thermal control ability. In an orbit at high altitude, charging of polymer materials can hinder measurements on spacecraft. To investigate the charging of these kinds of materials in a vacuum, electron beams were used to irradiate test pieces of FRP, Ge‐sputtered FRP, and CFRP. The experiments were conducted in a high‐vacuum chamber with an electron beam gun. The results show that the absolute surface potential of Ge‐sputtered FRP remains lower than that of FRP. The irradiation of negatively charged Ge‐sputtered FRP decreases the surface potential. Ge‐sputtered FRP with a thicker layer of Ge shows a similar and pronounced tendency. Irradiation with higher current density also causes more rapid decrease of the potential. The results for CFRP also show low values of the saturated surface potential. These characteristics are different from those of simple polymer test pieces such as fluoroethylenepropylene (FEP) film. Although the penetration depth of electrons is confined to the Ge layer, the surface potential of Ge‐sputtered FRP is lower than the potential expected for single materials. The mechanism of this phenomenon seems to be related to secondary electron emission. © 1999 Scripta Technica, Electr Eng Jpn, 127(2): 1–7, 1999     

Separation of aqueous phenol through polyurethane membranes by pervaporation. II. Influence of diisocyanate and diol compounds and crosslinker

The influence of diisocyanate and diol compounds of polyurethane and crosslinking agent on the separation of phenol aqueous solution by pervaporation was investigated. Polyurethanes were prepared by polyaddition of diisocyanate and diol compounds and trimethylolpropane (TMP) using dibutyltindilaulate as a catalyst. The polyurethane membrane was prepared by a casting method and was sandwiched with a porous polypropylene membrane (Celgard® 2500). Pervaporation measurement was carried out under vacuum on the permeate side, and the permeant was collected with a liquid nitrogen trap. Little influence of diisocyanate compounds on the phenol permselectivity through diisocyanate–polytetramethyleneglycol [PTMG(1000)] membranes was observed since the influence on the solubility and the diffusivity was small. The phenol permselectivity was increased with an increase in the molecular weight of PTMG and polycaprolactone diol (PCL) for the 1,6‐diisocyanato hexane (HMDI)–PTMG and HMDI–PCL membranes. It was considered that the increase in phenol diffusivity can be attributed to an increase in phenol selectivity. The permeability and selectivity of HMDI–[PTMG(2900)–TMP] membrane was relatively constant below the 2% TMP content. © 1999 John Wiley & Sons, Inc. J Appl Polym Sci 71: 439–448, 1999     

Fundamental characteristics of DRAM capacitor application of PLZT ultrathin films prepared by MOCVD

Lanthanum-modified lead zirconate titanate (PLZT) thin films (50 nm to 200 nm) were deposited on Pt/SiO₂/Si substrate by metal-organic chemical vapor deposition (MOCVD). The electrical properties of the films were investigated as a function of the La content or the substrate temperature. Ferroelectric PZT(0/50/50) films were obtained at substrate temperatures as low as 500 °C; their electrical characteristics improved with increasing substrate temperature. La exhibited adequate solid solution in the PZT above 650 °C. PLZT(15/45/55) films with a thickness of 100 nm were found to have good properties for application to the capacitors of dynamic random access memory (DRAM), namely, an effective charge density of 80 fF/μm², a permittivity of 1000, an SiO₂ equivalent thickness of 0.4 nm, and a leakage current density of 5 × 10⁻⁸ A/cm. Addition of La to PZT was effective in reducing the leakage current with an increase in the registration rate. RuO₂ and/or IrO₂ bottom electrodes for ferroelectric PLZT films were also investigated. The RuO₂ films were found effective as diffusion barriers for PLZT and MgO. Significant interdiffusion at RuO₂/Si and RuO₂/SiO₂ interfaces occurred during the deposition of PLZT films. Annealing of the RuO₂ film considerably depressed interface reactions. © 1998 Scripta Technica. Electr Eng Jpn, 122(1): 25–36, 1998     

Role of an overhead ground wire in the generation of lightning-induced voltage over lossy ground

The role of an overhead ground wire on the generation for lightning-induced voltage on a multiconductor line associated with a vertical return-stroke channel is studied based on numerical calculation. The induced voltage is calculated by a method in which the tangential component of the electric field to the wire is looked upon as an inducing source. The analyzed multiconductor line consists of three phase wires and an overhead ground wire having one or two earthing points. The influence of the overhead ground wire on the induced voltage is dependent on the direction of a return stroke, as well as the ground conductivity. When a return stroke is on the side of a power distribution line, the induced voltage decreases with a decrease in the earthing resistance of the overhead ground wire, irrespective of the ground conductivity. When a return stroke is close to an end of a distribution line, the influence of the overhead ground wire is dependent on the ground conductivity. In this case, the voltage induced on overhead wires over lossy ground sometimes increases with the presence of an overhead ground wire having only one earthing point. This effect can be avoided by adding earthing points to the overhead ground wire. © 1998 Scripta Technica. Electr Eng Jpn, 121(4): 18–27, 1997     

MORI-A CPS: 3D printed soft actuators with 4D assembly simulation

Artificial Life and Robotics - Soft modular robotics combines soft materials and modular mechanisms. We are developing a vacuum-driven actuator module, MORI-A, which combines a 3D-printed flexible...     

Effect of Raw and Heat‐Moisture Treated High‐Amylose Corn Starch on Fermentation by the Rat Cecal Bacteria

Resistant starch content of high‐amylose corn starch (HAS) was doubled by heat‐moisture treatment. Resistant starch content of HAS and heat‐moisture treated high‐amylose corn starch (HMT‐HAS) were 31.8 and 67.3%, respectively, as determined by enzymatic‐gravimetric method. Effects of the two types of high‐amylose corn starches, HAS and HMT‐HAS, on starch fermentation, microflora, pH, short chain fatty acid (SCFA) content and β‐glucuronidase activity in the cecal content have been investigated. Rats were given ordinary corn starch (OCS; control), HAS or HMT‐HAS at 10% level for 10 13 days. The cecal and colorectal content s weights were larger in HAS and HMT‐HAS groups than in the OCS group. The cecal content s weight did not differ between HAS and HMT‐HAS groups, while the colorectal content s weight was higher in the HMT‐HAS group than in the HAS group. The upper and lower small intestinal and cecal starch contents were significantly higher in the HAS and HMT‐HAS groups than in the OCS group, whereas there were no differences between colorectal starch content in group OCS and HAS. Starch excretion in feces was significantly higher in groups HAS and HMT‐HAS than in group OCS, the increase in the HMT‐HAS group was especially remarkable. The composition of the cecal microflora was not effected by the diet. β‐Glucuronidase activities in rats fed HAS or HMT‐HAS decreased. SCFA concentration was higher in groups HAS and HMT‐HAS than in group OCS, and the cecal pH was lower in groups HAS and HMT‐HAS than in group OCS.