Production and Emulsifying Effect of Polyglycerol and Fatty Acid Esters with Varying Degrees of Esterification

Esters with acyl groups can be formed by the esterification of polyglycerol. The purpose of the present study was to produce fatty acid esters [hexanoic (caproic), octanoic (caprylic), decanoic (capric), dodecanoic (lauric), tetradecanoic (myristic), hexadecanoic (palmitic), octadecanoic (stearic)] and polyglycerol (average number‐of degrees of polymerization of 5) with varying degrees of esterification and to examine their emulsifying properties. A number of fundamental catalysts of polyglycerol acylation reactions by methyl esters of carboxylic acid were studied, and sodium methoxide was found to be the best choice. The temperature rate of transesterification increased from 180 to 220 °C with the fatty acid chain alkyl residue. Synthesized mono‐, di‐, tri‐, tetra‐, and heptaesters of various fatty acids and polyglycerol provided the highest hydroxyl values from 15 to 815 mg KOH g^?1 and saponification values from 82 to 321 mg KOH g^?1. The emulsifying properties were assessed for all polyglycerol and fatty acid esters, with results showing maximum emulsifying effect for tri‐ and tetraesters of capric, lauric, and caprylic acids. Regardless of the hydrophilic–lipophilic balance value (HLB) of polyglycerol esters and carboxylic acid, a 4:1 ratio of sunflower oil to water formed a water‐in‐oil type emulsion. When mixing oil and water in a 1:1 ratio, mono‐ and diesters of polyglycerol formed an oil‐in‐water type emulsion, heptaesters formed a water‐in‐oil type emulsion, and tri‐ and tetraesters formed both of types of emulsions, depending on the length of the acid hydrocarbon radicals.     

Alterations in Membrane Phospholipid Fatty Acids of Gram-Positive Piezotolerant Bacterium Sporosarcina sp. DSK25 in Response to Growth Pressure

Pressure is an important thermodynamic property of the ocean and the deep biosphere that affects microbial physiology and biochemistry. Here, we report on our investigation of the response of Gram-positive piezotolerant bacterium Sporosarcina sp. DSK25 to hydrostatic pressure. Strain DSK25 responded in an adaptive manner to upshifts of growth pressure and showed systematic changes in phospholipid fatty acids. As the pressure increased from 0.1 to 10 MPa (Megapascal), unsaturated fatty acids in DSK25 increased from 21.7 to 31.1 % of total fatty acids, while the level of iso- and anteiso-branched fatty acids remained unchanged. At higher pressures (30, 50, and 60 MPa), the amount of unsaturated fatty acids decreased, and that of anteiso-branched fatty acids increased from 34.4 to 49.9 % at the expense of iso-branched fatty acids. For the first time, two polyunsaturated fatty acids (PUFA), 18:2n-6 and 18:2n-x, with the latter having much higher abundance than the former, were identified in DSK25. The concentration of the PUFA increased with growth pressure. These results indicate the involvement of unsaturated and methyl-branched fatty acids in the modulation of bacteria membrane fluidity and function over environmentally relevant parameter (pressure). Piezotolerant bacterium Sporosarcina sp. DSK25 appears to utilize two regulatory mechanisms for adaptation to high pressure, a rapid-responding mechanism on transient scale, expressed as increased biosynthesis of monounsaturated fatty acids, and a long-term adaptation mechanism in increased synthesis of anteiso-branched and polyunsaturated fatty acids. Our results further suggest that Gram-positive piezophilic bacteria respond differently than Gram-negative bacteria in adaptation to high pressure.     

Decentralised decision making in heterogeneous teams using anonymous optimisation

This paper considers the scenario where multiple autonomous agents must cooperate in making decisions to minimise a continuous and differentiable team cost function. A distributed and asynchronous optimisation algorithm is presented which allows each agent to incrementally refine their decisions while intermittently communicating with the rest of the team. A convergence analysis provides quantitative requirements on the frequency agents must communicate that is prescribed by the structure of the decision problem. In general the solution method will require every agent to communicate to and have a model of every other agent in the team. To overcome this, a specific subset of systems, called Partially Separable, is defined. These systems only require each agent to have a combined summary of the rest of the team and allows each agent to communicate locally over an acyclic communication network, greatly increasing the scalability of the system.     

Genuinity Signatures: Designing Signatures for Verifying 3D Object Genuinity

3D computer graphics models and digitally-controlled manufacturing have come together to enable the design, visualization, simulation, and automated creation of complex 3D objects. In our work, we propose and implement a framework for designing computer graphics objects and digitally manufacturing them such that no adversary can make imitations or counterfeit copies of the physical object, even if the adversary has a large number of original copies of the object, knowledge of the original object design, and has manufacturing precision that is comparable to or superior to that of the legitimate creator of the object. Our approach is to design and embed a signature on the surface of the object which acts as a certificate of genuinity of the object. The signature is detectable by a signature-reading device, based on methods in computer graphics and computer vision, which contains some of the secret information that was used when marking the physical object. Further, the compromise of a signature-reading device by an adversary who is able to extract all its secrets, does not enable the adversary to create counterfeit objects that fool other readers, thereby still enabling reliable copy detection. We implemented a prototype of our scheme end-to-end, including the production of the physical object and the genuinity-testing device.     

低k集成的曙光

随着对新化学品和集成方案了解的加深，我们不但可以减轻介电层孔隙率增加引起的负担还可以降低工艺对超低k薄膜的损伤。     

Integrated energy performance modeling for a retail store building

This paper presents an integrated energy performance modeling approach that considers heat and mass transfer through building envelope, HVAC (heating, ventilation, and air conditioning) and refrigeration systems of a retail store building with limited measured data. The internal heat gains/losses were estimated based on an Extended Kalman Filter. The simulation coupling strategy among room top units (RTUs), refrigeration display cases and zones is based on the ping-pong coupling strategy. The integrated model was validated against measured data from June to August, 2011. The results show that temperature prediction is within the ±1.5°C error band and the RTU electricity energy use prediction is within the ±10% error band. The difference between measured and simulated annual electricity consumption from the refrigeration system is 3%. Based on further analysis and diagnostics, deviations of model predictions from measured data were found to be partially due to the faults in the RTUs. Such deviation accounts for a 4% saving of the total building electrical energy consumption.