SBA-15 supported mesoporous Ni and Co catalysts with high coke resistance for dry reforming of methane

In this study, the activity of the mesoporous SBA-15 supported Ni, Co and NiCo catalysts prepared by the wet-impregnation were investigated in dry reforming of methane reaction. The catalysts were characterized by XRD, TPR, N₂ adsorption-desorption isotherms, SEM, TEM and TG/DT techniques before and/or after activity tests. N₂ adsorption-desorption isotherm of the all catalysts were consistent with Type IV isotherm, indicating mesoporous structures. TEM images of bimetallic NiCo catalysts clearly proved the presence of characteristic honeycomb structure. Incorporation Co into SBA-15 supported Ni catalysts inhibited the agglomeration of the nickel particles due to the formation of NiCo alloy. Activity test results showed that bimetallic 4Ni1Co@SBA-15 catalyst (Ni/Co:4/1) gave highly promising activity with high methane (73%) and carbon dioxide (89%) conversion values at 750 °C. Co incorporation into SBA-15 supported Ni catalyst significantly decreased the coke formation during dry reforming of methane.     

Fixed point analysis of limited range share per node wavelength conversion in asynchronous optical packet switching systems

In this article, we study an asynchronous optical packet switch equipped with a number of wavelength converters shared per node. The wavelength converters can be full range or circular-type limited range. We use the algorithmic methods devised for Markov chains of block-tridiagonal type in addition to fixed-point iterations to approximately solve this relatively complex system. In our approach, we also take into account the finite number of fiber interfaces using the Engset traffic model rather than the usual Poisson traffic modeling. The proposed analytical method provides an accurate approximation for full range systems for relatively large number of interfaces and for circular-type limited range wavelength conversion systems for which the tuning range is relatively narrow.

The unified interaction model applied to LiF:Mg,Ti (TLD-100): properties of the luminescent and competitive centres during sensitisation

An attempt is made to predict/interpret theoretically the experimentally measured values of f(D) and S(Ds)/So for composite peak 5 in TLD-100. using the Unified Interaction Model (UNIM) with identical values of the UNIM parameters for both sets of experimental data. Although an excellent fit can be obtained to the experimental f(D) data over the entire dose region where f(D) is greater than unity. i.e. from 5 Gy to several thousand Gy, a satisfactory fit to both sets of data is found to require different values for at least one of the parameters. The lack of success in fining f(D) and S(Ds)/So with the same values of all the parameters, suggests that the sensitisation anneal (particularly the duration of the anneal) may somehow change the structure (S(LC)) and/or the total number of available LCs in an unknown manner.     

Dimensioning shared-per-node recirculating fiber delay line buffers in an optical packet switch

Optical buffering based on fiber delay lines (FDLs) has been proposed as a means for contention resolution in an optical packet switch. In this article, we propose a queuing model for feedback-type shared-per-node recirculating FDL optical buffers in asynchronous optical switching nodes. In this model, optical packets are allowed to recirculate over FDLs as long as the total number of recirculations is less than a pre-determined limit to meet signal loss requirements. Markov Modulated Poisson Process (MMPP)-based overflow traffic models and fixed-point iterations are employed to provide an approximate analysis procedure to obtain blocking probabilities as a function of various buffer parameters in the system when the packet arrival process at the optical switch is Poisson. The proposed algorithm is numerically efficient and accurate especially in a certain regime identified with relatively long and variably-sized FDLs, making it possible to dimension optical buffers in next-generation optical packet switching systems.     

Fast parallel Particle-To-Grid interpolation for plasma PIC simulations on the GPU

Particle-In-Cell (PIC) methods have been widely used for plasma physics simulations in the past three decades. To ensure an acceptable level of statistical accuracy relatively large numbers of particles are needed. State-of-the-art Graphics Processing Units (GPUs), with their high memory bandwidth, hundreds of SPMD processors, and half-a-teraflop performance potential, offer a viable alternative to distributed memory parallel computers for running medium-scale PIC plasma simulations on inexpensive commodity hardware. In this paper, we present an overview of a typical plasma PIC code and discuss its GPU implementation. In particular we focus on fast algorithms for the performance bottleneck operation of Particle-To-Grid interpolation.     

Simple and fast spectrophotometric determination of low levels of thiabendazole residues in fruit and vegetables after pre-concentration with ionic liquid phase microextraction

There is a great importance of monitoring thiabendazole (TBZ) residues in fruits and vegetables to ensure food safety. Therefore, a new ionic liquid (IL) phase microextraction method using IL, 1-butyl-3-methylimidazoliumhexafluorophosphate [C₄mim][PF₆], as extracting solvent is proposed for simple and fast determination of low levels of TBZ in fruits and vegetables by spectrophotometry. The method is based on selective complex formation of TBZ with Cu(II) ions in presence of PF₆^– as counter ion at pH 5.5, and then microextraction of the complex into the fine micro-drops of IL phase. After optimisation of variables affecting microextraction efficiency, the analytical parameters of the method were determined by calibration curves. The method exhibits a linear relationship (0.3–280 μg L^?1), low detection limit (0.1 μg L^?1), good intra- and inter-day precision (2.4–4.5% as RSD_r%, 2.1–5.6% as RSD_R%), good recovery (≥95.1–98.2%) and high sensitivity enhancement factor (150) by solvent-based calibration curve. It allows a detection limit of 0.24 μg L^?1 and a range of 0.8–250 μg L^?1 by the matrix-matched calibration curve. After validation, the method was successfully applied to the determination of TBZ residues with method quantification limits in fruit and vegetables of 2.0 and 2.5 µg kg^?1 with and without adding polyvinylpyrrolidone (PVP-15) solution. Recoveries range from 85.5% to 98.2% after spiking (10, 50 and 100 µg kg^?1, n: 3).     

Simultaneous determination of antimony and boron in beverage and dairy products by flame atomic absorption spectrometry after separation and pre-concentration by cloud-point extraction

A new cloud-point extraction (CPE) method was developed for the pre-concentration and simultaneous determination of Sb(III) and B(III) by flame atomic absorption spectrometry (FAAS). The method was based on complexation of Sb(III) and B(III) with azomethine-H in the presence of cetylpyridinium chloride (CPC) as a signal-enhancing agent, and then extraction into the micellar phase of Triton X-114. Under optimised conditions, linear calibration was obtained for Sb(III) and B(III) in the concentration ranges of 0.5–180 and 2.5–600 μg l^?1 with LODs of 0.15 and 0.75 μg l^?1, respectively. Relative standard deviations (RSDs) (25 and 100 μg l^?1 of Sb(III) and B(III), n = 6) were in a range of 2.1–3.8% and 1.9–2.3%, respectively. Recoveries of spiked samples of Sb(III) and B(III) were in the range of 98–103% and 99–102%, respectively. Measured values for Sb and B in three standard reference materials were within the 95% confidence limit of the certified values. Also, the method was used for the speciation of inorganic antimony. Sb(III), Sb(V) and total Sb were measured in the presence of excess boron before and after pre-reduction with an acidic mixture of KI-ascorbic acid. The method was successfully applied to the simultaneous determination of total Sb and B in selected beverage and dairy products.     

The physical state of nafcillin sodium in frozen aqueous solutions and freeze-dried powders

The purpose of this study was to develop a better understanding of the physical chemistry of freeze drying of lyotropic liquid crystals using nafcillin sodium as a model solute. Solutions and freeze-dried powders of nafcillin sodium were studied by polarized light microscopy, differential scanning calorimetry, x-ray powder diffraction, and water vapor adsorption. Differential scanning calorimetry thermograms of nafcillin sodium solutions contain a melting endotherm at approximately -5.5 degrees C and, depending on the concentration and heating rate, a crystallization exotherm immediately after this endotherm followed by the melting endotherm of ice. When the sample is annealed at -4 degrees C, both the endotherm and exotherm are eliminated, and a new endotherm appears at approximately -1 degree C on the shoulder of the ice-melting endotherm. The data are interpreted as melting of a liquid crystalline phase, followed by crystallization. X-ray powder diffractograms of unannealed freeze-dried nafcillin sodium are consistent with a lamellar liquid crystal. Diffractograms of annealed freeze-dried nafcillin sodium indicate crystalline material which is a different crystal form than the monohydrate starting material. Moisture adsorption isotherms of the freeze-dried annealed (crystalline) and unannealed (liquid crystalline) nafcillin sodium show different affinities for moisture compared to the crystalline starting material. Solid-state stability data demonstrate that the freeze-dried liquid crystalline form of nafcillin sodium is much less stable than the freeze-dried crystal-line material. The literature recognizes two types of solute behavior on freezing, where the solute either crystallizes from the freeze concentrate or remains amorphous. Lyotropic liquid crystal formation during freezing represents a separate category of freezing behavior, the physical chemistry of which is worthy of further investigation.     

Simulation of vapour explosions

Vapour explosions, also called thermal detonations, occur when a liquified gas comes into contact with water. During the contact of the two liquids with considerably different temperatures, intensive boiling of one of them takes place which is accompanied by an explosive increase in pressure. A similar phenomenon also arises in the cooling systems of nuclear-power stations, when, as a result of some accident, the heated particles of the nuclear fuel settle in the cold water. This leads to the explosive boiling of the liquid and to a rapid increase of the pressure. This paper presents analytical and numerical modelling of the behaviour of small-scale single drops of liquified gas in water.