Macropore formation in p-type silicon: toward the modeling of morphology

The formation of macropores in silicon during electrochemical etching processes has attracted much interest. Experimental evidences indicate that charge transport in silicon and in the electrolyte should realistically be taken into account in order to be able to describe the macropore morphology. However, up to now, none of the existing models has the requested degree of sophistication to reach such a goal. Therefore, we have undertaken the development of a mathematical model (phase-field model) to describe the motion and shape of the silicon/electrolyte interface during anodic dissolution. It is formulated in terms of the fundamental expression for the electrochemical potential and contains terms which describe the process of silicon dissolution during electrochemical attack in a hydrofluoric acid (HF) solution. It should allow us to explore the influence of the physical parameters on the etching process and to obtain the spatial profiles across the interface of various quantities of interest, such as the hole concentration, the current density, or the electrostatic potential. As a first step, we find that this model correctly describes the space charge region formed at the silicon side of the interface.     

电压表的微控制器

图1中的电路是以前一个设计实例的扩展(在无内置ADC的微控制器中如何使用模拟输入),并参考了另一篇设计实例(不用外接开关晶体管如何驱动一个七段LED显示屏)介绍的技巧(参考文献1和参考文献2).本电路增加了一个串行连接,只需要一个双绞线对就可以向一台兼容PC发送每个测量值.     

Combining finite learning automata with GSAT for the satisfiability problem

A large number of problems that occur in knowledge-representation, learning, very large scale integration technology (VLSI-design), and other areas of artificial intelligence, are essentially satisfiability problems. The satisfiability problem refers to the task of finding a satisfying assignment that makes a Boolean expression evaluate to True. The growing need for more efficient and scalable algorithms has led to the development of a large number of SAT solvers. This paper reports the first approach that combines finite learning automata with the greedy satisfiability algorithm (GSAT). In brief, we introduce a new algorithm that integrates finite learning automata and traditional GSAT used with random walk. Furthermore, we present a detailed comparative analysis of the new algorithm's performance, using a benchmark set containing randomized and structured problems from various domains.     

Computer and network security risk management: theory,challenges, and countermeasures

The need to secure information systems and networked infrastructures is now commonplace in most enterprises. The use of novel communication technologies has became a crucial factor that can considerably improve or affect productivity. This is essentially due to the importance of the information transmitted across communication networks and stored in servers. As a consequence, strong ties are being built between security and the enterprise business activity. Risk management, which is the discipline that deals with this aspect, integrates a litany of architectures, techniques, and models that are described in this paper. A global view is proposed to the reader through a presentation of the research activity that has been directed towards this field. Copyright © 2005 John Wiley & Sons, Ltd.     

Etude de l'influence du mode d'anodisation sur la cinétique de croissance des films d'alumine en milieu acide sulfurique

The kinetics of growth of Al₂O₃ oxide films made by anode oxidation of ALuminium 1050A with two anodization techniques has been investigatedan compared. The first technique is the classical method based on continuous tension during the complete electrlysis duration, and the second one is the modern method ofpulsed tensions, whcih consists of periodically imposing to the material two anodc tensions E₁ and E₂ (E₁ > E₂) during time T₁ and T₂ until the end on anodization. We have shown that the second technique allows the fabrication of films more rapidly for the same electrolysis duraton. Energy and electrolysis time are saved, making it attractive from an economical viewpoint. This advantage arises from the positive effect of excess heat disiption gathered during the imposition of tension, E₁, when E₂ is imposed thereafter (recovery effect). The logging of in situ transient responses in the case of pulsed anodization is a significant asset to explain the growth film kinetics obtained with this method.     

Heat capacities of both PMMA stereomers: Comparison between atomistic simulation and experimental data

The domains of time and space generally covered by full atomistic simulation (AS) to represent the glass transition temperature, T_g, are very small. Physical interpretations of the phenomena occurring at this transition are inevitably limited. To specifically address such limitation, behavior of the heat capacity that accounts for the freezing of the degrees of freedom as temperature is decreased, is investigated. The selected polymer is poly(methyl methacrylate) since it offers the opportunity to exhibit a different T_g according to the tacticity of its chain. AS and experimental data are thus compared to a theoretical model that takes into account three contributions to the leap in the heat capacity occurring at T_g. The comparison discloses that an excellent agreement is obtained between simulated and experimental contributions from vibrations and free volume. However, from an AS viewpoint changes in the conformation weakly contribute to this leap. Despite this discrepancy local contributions to the glass transition as predicted by atomistic simulation, are sufficient to determine T_g.     

Factorial design of experiment (DOE) for parametric exergetic investigation of a steam methane reforming process for hydrogen production

Hydrogen is expected to play a significant role in future energy systems. The efficient production of hydrogen at a minimum cost and in an environmentally acceptable manner is crucial for the development of a hydrogen-including economy. The exergy analysis is a powerful tool to quantify sustainable development potential. An important aspect of sustainable development is minimizing irreversibility. The purpose of this study is to perform the exergy analysis of a steam methane reforming (SMR) process for hydrogen production. As a first step, an exergy analysis of an existing process is shown to be an efficient tool to critically examine the process energy use and to test for possible savings in primary energy consumption. The results of this investigation prove that the exergetic efficiency of the SMR process is 65.47%, and the majority of destroyed exergy is localized in the reformer with a 65.81% contribution to the whole process destroyed exergy. Next, an exergetic parametric study of the SMR has been carried out with a factorial design of experiment (DOE) method. The influence of the reformer operating temperature and pressure and of the steam to carbon ratio (S/C) on the process exergetic efficiency has been studied. A second-order polynomial mathematical model has been obtained through correlating the exergetic efficiencies with the reformer operating parameters. The results of this study show that the rational choice of these parameters can improve the process exergetic performance.