Dynamic modeling of gas phase propylene homopolymerization in fluidized bed reactors

A new model with comprehensive kinetics for propylene homopolymerization in fluidized bed reactors was developed to investigate the effect of mixing, operating conditions, kinetic and hydrodynamic parameters on the reactor performance as well as polymer properties. Presence of the particles in the bubbles and the excess gas in the emulsion phase was considered to improve the two-phase model, thus, considering the polymerization reaction to take place in both the bubble and emulsion phases. It was shown that in the practical range of superficial gas velocity and catalyst feed rate, the ratio of produced polymer in the bubble phase to the total production rate is roughly between 10% and 13%, which is a substantial amount and cannot be ignored. Simulation studies were carried out to compare the results of the improved two-phase, conventional well-mixed and constant bubble size models. The improved two-phase and well mixed models predicted a narrower and safer window at the same running conditions compared with the constant bubble size model. The improved two-phase model showed close dynamic behavior to the conventional models at the beginning of polymerization, but starts to diverge with the evolution of time.     

The dual-edge alignment technique with improved spur reduction effects in ring oscillators

In this paper, the technique of dual-edge phase-alignment and its effects on ring oscillators are presented. This technique provides resetting of the built-up jitter at both rising and falling edges of a clean aligning signal named as the reference. Using signals and systems theory, the effect of the technique on the spurs due to the aligning reference signal is completely analyzed. We show that adding properly the dual-edge aligning feature to phase-aligned ring oscillators cause the spurs in the neighborhood of the carrier to disappear. First, the validity of the results obtained from the derived analytical equations is verified through simulations using MATLAB. Then a complete circuit considering realistic models for its components is simulated in TSMC RF CMOS 0.18um process using ADS for further validation.     

Trellis precoding for MIMO broadcast signaling

Channel Inversion, and its Minimum Mean Square Error (MMSE) variation, are low complexity methods for Space Division Multiple Access (SDMA) in Multiple Input Multiple Output Broadcast Channel (MIMO-BC). As the channel matrix deviates from orthogonal, these methods result in a waste of transmit power. This paper proposes a trellis precoding method (across time and space) to improve the power efficiency. Adopting a 4-state trellis shaping method from [1], the complexity of the proposed method, which is entirely at the transmitter side, is equivalent to the search in a trellis with 4N states where N is the number of transmit antennas. Numerical results are presented showing that the achievable gains, which depend on the channel realization, can be significantly higher than the traditional shaping gain which is limited to 1.53dB.     

MATRIX AND CEMENT EFFECTS ON RESIDUAL OIL SATURATION IN SANDSTONE FORMATIONS: A NEURAL NETWORK APPROACH

Residual oil in sandstone is affected by mineral composition, clay matrix and cementing material. Matrix minerals affect the affinity of a fluid to spread on a rock surface significantly and in turn controls the fluid distribution within the pore spaces. At the interface between the rock surface and the contacting fluid, electrical charges are in the origin of the extent of phase wetness. Available framework grains, a dominant component of rock matrix, affect porosity and, hence, amounts of rock preferential wetness. Cement, clay matrix and quartz overgrowth, which make up for the rest of the grain population in a rock, influence wetness and, therefore, amounts of residual oil. In this paper, spectro-electromicroscopy (SEM) point-count technique in conjunction with neural network analysis were used to determine the effect of certains rock parameters on the amounts of residual oil following waterflooding operations. Using artifcial neural network, the intent was then to predict the extent of residual oil in sandstone rocks given limited information about rock matrix, cementing material and primary porosity.     

Field-oriented vector control of synchronous motors with additional field winding

This paper presents a new method to control a synchronous motor in such a way to resemble the characteristics of a DC motor. The method suggests including a second field winding to the rotor of a voltage-source-inverter-fed synchronous motor. The angular frequency of the inverter is made equal to the angular rotor speed, (of a self-controlled synchronous motor drive). The added field winding is in space quadrature to the main field winding and is properly excited in such a way as to diminish the direct axis component of the stator current at every load conditions. The motor is controlled to operate with zero power angle from the inverter side and zero direct axis current from the rotor excitation side. Therefore, it operates with minimum stator current and with unity power factor. The addition of the second field winding will not complicate the design because it is just a control winding. This winding may be made with smaller wire cross-section and a larger number of turns. The control on this winding is not complicated and it can be easily created. The synchronous motor along with the added field and the required control loops are simulated and tested extensively. The test results show excellent motor performance in motoring and regenerating modes of operation.     

Retrolabyrinthine vestibular nerve section: a current appraisal

We report our experience (1987-1993) with Meniere's disease patients treated with a retrolabyrinthine vestibular neurectomy. The current literature was reviewed and our results have been compared with those of previous reports. The overall success rate for vertigo relief was 96.7%, with no serious or permanent complications resulting from the procedure. The technical elements of the operation, as they apply to our approach and those of others, have been analyzed, with special attention given to the anatomical features of the region and their influence on success or failure. We conclude that the retrolabyrinthine approach for vestibular nerve section remains a safe and highly successful technique which merits continued use.     

Biologically‐synthesised ZnO/CuO/Ag nanocomposite using propolis extract and coated on the gauze for wound healing applications

Wound healing has long been recognised as a major clinical challenge for which stablishing more effective wound therapies is necessary. The generation of metallic nanocomposites using biological compounds is emerging as a new promising strategy for this purpose. In this study, four metallic nanoparticles (NPs) with propolis extract (Ext) and one without propolis including ZnO/Ext, ZnO/Ag/Ext, ZnO/CuO/Ext, ZnO/Ag/CuO/Ext and ZnO/W were prepared by microwave method and assessed for their wound healing activity on excision experimental model of wounds in rats. The developed nanocomposites have been characterised by physico‐chemical methods such as X‐ray diffraction, scanning electron microscopy, diffuse reflectance UV–vis spectroscopy, Fourier transform infrared spectroscopy, thermogravimetric analysis and Brunauer–Emmett–Teller analyses. The wounded animals treated with the NPs/Ext in five groups for 18 days. Every 6 days, for measuring wound closure rate, three samples of each group were examined for histopathological analysis. The prepared tissue sections were investigated by haematoxylin and Eosin stainings for the formation of epidermis, dermis and muscular and Masson''s trichrome staining for the formation of collagen fibres. These findings toughly support the probability of using this new ZnO/Ag/Ext materials dressing for a wound care performance with significant effect compared to other NPs.Inspec keywords: nanomedicine, X‐ray diffraction, II‐VI semiconductors, visible spectra, ultraviolet spectra, nanocomposites, biomedical materials, proteins, wounds, nanoparticles, scanning electron microscopy, nanofabrication, skin, zinc compounds, silver, antibacterial activity, Fourier transform infrared spectra, copper compounds, molecular biophysicsOther keywords: propolis, wound healing applications, effective wound, metallic nanocomposites, biological compounds, metallic nanoparticles, microwave method, wound healing activity, physico‐chemical methods, Fourier transform infrared spectroscopy, diffuse reflectance UV‐vis spectroscopy, Brunauer‐Emmett‐Teller analyses, wounded animals, wound closure rate, wound care performance, histopathological analysis, scanning electron microscopy, X‐ray diffraction, thermogravimetric analysis, haematoxylin, Eosin stainings, Masson trichrome, epidermis, muscular trichrome, collagen fibres, time 18.0 d, time 6.0 d, ZnO‐CuO‐Ag     

Absorption/desorption of calcium ions on polypyrrole-loaded reticulated vitreous carbon

Polypyrrole/polystyrene sulfonate-loaded reticulated vitreous carbon electrodes RVC/PPy/PSS were studied as electrochemical cation exchangers for the absorption of Ca²⁺ ions from aqueous solutions. Two grades of RVC were used mainly with 20 and 45 PPI. The preparation and characterization of the PPy/PSS layers on RVC are described. The structure and morphology of the porous electrodes were characterized using cyclic voltammetry (CV) and scanning electron microscopy (SEM). The potential dependent absorption and desorption of Ca²⁺ on RVC/PPy/PSS electrodes was studied in 0.1 M CaCl₂ solution using chronoamperometry and atomic adsorption spectroscopy (AAS). The extent of Ca²⁺ ions absorbed into RVC/PPy/PSS was found to increase with decreasing absorption potential, the specific surface area and the extent of polymer loading. Recovery of the RVC/PPy/PSS electrode was performed by anodic polarization at potentials at which Ca²⁺ ions are desorbed. The coulomb efficiency for the Ca²⁺ desorption process was found to be higher than that for the Ca²⁺ absorption process. From these results the feasibility of using RVC/PPy/PSS for water softening was determined under the prevailing experimental conditions.     

On the Performance of FFT/DWT/DCT-based OFDM Systems with Chaotic Interleaving and Channel Estimation Algorithms

The efficiency of data transmission over fading channels in orthogonal frequency division multiplexing (OFDM) systems depends on the employed interleaving method. In this study, we propose an improved chaotic interleaving scheme which aims to improve the performance of OFDM system under fading channel. In the proposed scheme, the binary data is interleaved with chaotic Baker map prior to the modulation process. In the sequel, significant degree of encryption is being added during data transmission. The performance of the proposed approach is tested on the conventional fast Fourier transform OFDM, discrete wavelet transform OFDM, and discrete cosine transform OFDM with and without chaotic interleaving. Furthermore, an expectation–maximization (EM) algorithm is proposed for improving channel impulse response (CIR) estimation based on a maximum likelihood principle. The proposed scheme makes use of EM algorithm to update the channel estimates until convergence is reached. The simulation results show the efficiency of the proposed algorithms under Rayleigh fading environments where the symbol error rate essentially coincides with that of the perfect channel case after the fifth EM iteration.