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81.
We investigated the effect of varying polymer crystallinity, morphology, and optical property, produced by adding four different co‐solvents in to the poly(3‐hexylthiophene) (P3HT): [6,6]‐phenyl C61‐butyric acid methyl ester (PCBM) active layer blend solution, on the functioning of an inverted polymeric solar device. Photovoltaic devices primed with cyclohexanone co‐solvent showed the best performance with power conversion efficiency (PCE) reaching a value of 3.01 ± 0.04%. Improvement in efficiency is related to an increase in photocurrent which is due to a combined result of ordered P3HT crystallite growth, as well as of the precise size and phase separation of domains. POLYM. ENG. SCI., 55:1382–1388, 2015. © 2015 Society of Plastics Engineers 相似文献
82.
Nicholas R. Krogman Arlin L. Weikel Nhu Q. Nguyen Katherine A. Kristhart Syam P. Nukavarapu Lakshmi S. Nair Cato T. Laurencin Harry R. Allcock 《应用聚合物科学杂志》2010,115(1):431-437
New biomedically erodible polymer composites were investigated. Polyphosphazenes containing the dipeptide side groups alanyl–glycine ethyl ester, valinyl–glycine ethyl ester, and phenylalanyl–glycine ethyl ester were blended with poly(lactide‐co‐glycolide) (PLGA) with lactic to glycolic acid ratios of 50 : 50 [PLGA (50 : 50)] and 85 : 15 [PLGA (85 : 15)] with solution‐phase techniques. Each dipeptide ethyl ester side group contains two N? H protons that are capable of hydrogen bonding with the carbonyl functions of PLGA. Polyphosphazenes that contain only the dipeptide ethyl ester groups are insoluble in organic solvents and are thus unsuitable for solution‐phase composite formation. To ensure solubility during and after synthesis, cosubstituted polymers with both dipeptide ethyl ester and glycine or alanine ethyl ester side groups were used. Solution casting or electrospinning was used to fabricate polymer blend matrices with different ratios of polyphosphazene to polyester, and their miscibilities were estimated with differential scanning calorimetry and scanning electron microscopy techniques. Polyphosphazenes with alanyl–glycine ethyl ester side groups plus the second cosubstituent were completely miscible with PLGA (50 : 50) and PLGA (85 : 15) when processed via solution‐casting techniques. This suggests that the hydrogen‐bonding protons in alanyl–glycine ethyl ester have access to the oxygen atoms of the carbonyl units in PLGA. However, when the same pair of polymers was electrospun from solution, the polymers proved to be immiscible. Solution‐cast miscible polymer blends were obtained from PLGA (50 : 50) plus the polyphosphazene that was cosubstituted with valinyl–glycine ethyl ester and glycine ethyl ester side groups. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 相似文献
83.
Priya Nair Du Hyun Ku Chul Woo Lee Hun Young Park Ha Young Song Sang Su Lee Won Mook Lee 《应用聚合物科学杂志》2010,116(6):3534-3540
Studies on cement concrete microstructures are carried out to explain experimentally observed phenomenon and for modeling of concrete at the macroscopic level. In this article, the preparation of polymer impregnated mortar (PIC) is carried out by partially or fully replacing the pores in the cement mortars (OPC) by PMMA. The effect of this polymer impregnation on density and morphology of the cement matrix is studied. The microstructural changes in the mortar, on exposure of these specimens to hydrochloric acid and sea water for 7 and 28 days, are also investigated in this article. The above studies indicated that the polymer addition decreased the voids in the mortar thereby preventing leaching of water soluble salts present in the OPC. It was observed that the polymer also prevented the external chemical media from permeating into the cement matrix and undergoing interactions with it. It is concluded that the durability and chemical resistance properties of the PIC are better compared with OPC. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 相似文献
84.
The leather processing industry generates huge amounts of wastes, both in solid and liquid form. Fleshing from animal hides/skins is one such waste that is high in protein content. In this study, raw fleshing has been complexed with iron and is used for removal of chromium(VI). The effect of pH and the initial concentration of chromium(VI) on the removal of Cr(IV) by iron treated fleshing is presented. Iron treatment is shown to greatly improve adsorption of the fleshing for hexavalent chromium. The ultimate adsorption capacity of iron treated fleshing is 51 mg of chromium(VI) per gram of fleshing. That of untreated fleshing is 9 mg/g such that iron treatment increases the adsorption capacity of fleshing by 10-fold. The measured adsorption kinetics is well described by a pseudo-second-order kinetic model. The uptake of chromium(VI) by fleshing is best described by the Langmuir adsorption isotherm model. X-ray photoelectron spectroscopic (XPS) studies show that the iron is incorporated into the protein matrix. Shifts in XPS spectra suggest that dichromate binding occurs with iron at active adsorption sites and that iron treated fleshing removes chromium(VI) without reducing it to chromium(III). 相似文献
85.
Monitoring generator oscillations using Prony analysis is an application that is being increasingly implemented using phasor measurement units (PMUs) data. Most of the existing literature for power system oscillations using Prony method report implementing fixed sampling window that is obtained following a systematic iterative approach taking into account potential disturbances. The fixed sampling technique, although simple to implement, does not optimise the data acquisition time. Moreover, sampling using inadequate intervals can potentially lead to errors during Prony analysis. In this study mathematical formulations are derived to show the effect of small and large sampling intervals. Further, a technique using condition number is proposed as a quality index for signalling the errors arising because of the choice of sampling interval. To facilitate an efficient monitoring rate, while still maintaining sufficient accuracy, an adaptive sampling scheme is proposed. This study demonstrates that the proposed scheme can potentially exhibit faster monitoring rate with acceptable accuracy during practical implementation. 相似文献
86.
87.
M. H. Rahimkutty K. Rajendra Babu K. Sreedharan Pillai M. R. Sudarsana Kumar C. M. K. Nair 《Bulletin of Materials Science》2001,24(2):249-252
Thermal behaviour of strontium tartrate crystals grown with the aid of sodium metasilicate gel is investigated using thermogravimetry
(TG) and differential thermal analysis (DTA). Effect of magnetic field and dopant (Pb)2+ on the crystal stability is also studied using thermal analysis. This study reveals that water molecules are locked up in
the lattice with different strengths in the grown crystals. 相似文献
88.
Bing Li Tso‐Chien Pan Anand Nair 《The Structural Design of Tall and Special Buildings》2011,20(2):223-246
The response of tall buildings has been a major concern in metropolitan cities, especially with the recent surge in extreme activities targeted at structures with viable commercial values. This paper discusses a study carried out on the structural behaviour of a 2D frame, modelled to represent a tall building with ABAQUS. The model frame was subjected to a charge of the equivalent weight of 1 ton of TNT but placed at two varying cases of 5 and 10‐m standoff distances. Plane‐strain elements that incorporate the feature of material nonlinearity were utilized to model the structural components of the building and the simulated blast overpressures were obtained from the CONWEP software. The effects of large deformations of beams and columns corresponding to the short time loading duration depicted by the explosions were analysed from a local perspective. The extent of the damage is based on a local index defined as the ratio of curvatures. These local indices are consequently used to determine the possibility of disproportionate collapse of the frame from a global perspective. Finally, the provision of more ductile structural detailing is recommended to enhance the structural integrity of the building, increasing its resilience against blast attacks. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
89.
Energetic thermoplastic elastomers containing energetic groups, such as azido, nitrato, nitro, and so forth, are emerging as attractive binder systems for advanced solid rocket propellants. Poly[3,3‐bis(Azidomethyl) oxetane (BAMO)‐co‐3‐azidomethyl‐3‐methyl oxetane (AMMO)] comprising hard crystalline BAMO segment and the soft/amorphous AMMO segment in various molar ratios (80 : 20, 50 : 50 and 20 : 80) were synthesized during the present work. The homo polymers namely Poly‐BAMO and Poly‐AMMO were also synthesized. All the polymers and copolymers were characterized by spectral and thermal methods. They were found to be thermally stable. The most promising 80 : 20 copolymer softened at 56°C with Tg of −36°C. Rheological studies were also carried out to determine their suitability as a binder in explosive and propellant formulations. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 相似文献
90.
N.R. Sakthivel V. Sugumaran Binoy. B. Nair 《Mechanical Systems and Signal Processing》2010,24(6):1887-1906
Mono-block centrifugal pumps are widely used in a variety of applications. In many applications the role of mono-block centrifugal pump is critical and condition monitoring is essential. Vibration based continuous monitoring and analysis using machine learning approach is gaining momentum. Particularly, artificial neural networks, fuzzy logic have been employed for continuous monitoring and fault diagnosis. This paper presents the use of decision tree and rough sets to generate the rules from statistical features extracted from vibration signals under good and faulty conditions of a mono-block centrifugal pump. A fuzzy classifier is built using decision tree and rough set rules and tested using test data. The results obtained using decision tree rules and those obtained using rough set rules are compared. Finally, the accuracy of a principle component analysis based decision tree-fuzzy system is also evaluated. The study reveals that overall classification accuracy obtained by the decision tree-fuzzy hybrid system is to some extent better than the rough set-fuzzy hybrid system. 相似文献