Identification and analysis of wax esters by mass spectrometry

Several ions in the mass spectra of wax esters were related to the molecular structures. Assigned structures of ions were confirmed by deuterium labeling. A simple, direct method for quantititive analyses of mixtures was developed. The method involved a comparison of sets of three ions, RCO₂H⁺, RCO₂H₂ ⁺ and [R′−1]⁺ from all compounds in the mixture. The method was found applicable for mixtures of unsaturated wax esters after reduction with tetradeuterio hydrazine. Presented in part before the ISF-AOCS World Congress, Chicago, September 1970. Part III of a series of mass spectrometry of lipids. For VI see Lipids.     

Fusion of digital television,broadband Internet and mobile communications—Part II: Future service scenarios

This is the second part of the tutorial paper following the previous tutorial paper describing enabling technologies in digital video broadcasting (DVB) system. The paper presents the current and future operational scenarios for DVB via satellite (DVB‐S) system. Review of the current state‐of‐the‐art technologies consisting of integration of broadband Internet and mobile communications and integration of broadband Internet and DVB are given. The future operational scenarios emphasize the fusion of DVB systems with other technologies in terms of network fusion and terminal fusion. For satellite service scenarios, it also takes into consideration mobility management and standard quality‐of‐service mechanism issues, such as integrated services and differentiated services. Several research directions for providing seamless services regardless of network, access technology and terminal in the fusion network are also highlighted in this paper. Copyright © 2007 John Wiley & Sons, Ltd.     

Control of systems with actuator saturation non-linearities: An LMI approach

In this paper, we develop a static, full-state feedback and a dynamic, output feedback control design framework for continuous-time, multivariable, linear, time-invariant systems subject to time-invariant, sector-bounded, input non-linearities. The proposed framework directly accounts for robust stability and robust performance over the class of input non-linearities. Specifically, the problem of feedback control design in the presence of time-invariant, sector-bounded, input non-linearities is embedded within a Lure-Postnikov Lyapunov function framework by constructing a set of linear-matrix-inequality conditions whose solution guarantees closed-loop asymptotic stability with guaranteed domains of attraction in the face of time-invariant, sector-bounded, actuator non-linearities. A detailed numerical algorithm is provided for solving the linear-matrix-inequality conditions arising in actuator saturation control. Three illustrative numerical examples are presented to demonstrate the effectiveness of the proposed approach.     

“竹纤维”说法准确性的评析

<正>引言在2006年末至2007年,网络上出现大量商户销售声称使用"竹纤维"制作的服装。他们在广告中宣称"竹纤维"非常柔软,同时比棉纤维更易染色,并具有天然抗菌性能;而且由于生长过程中没有使用农药;要远比棉花纤维等其他纤维更环保。     

Psychological functioning among mothers of children with insulin-dependent diabetes mellitus: A longitudinal study.

Mothers of children with newly diagnosed insulin-dependent diabetes mellitus (IDDM) were assessed repeatedly over a period of 6 years in order to determine the psychological correlates of managing this chronic illness. Both maternal depression and overall emotional distress after the 1st year of the IDDM increased slightly with illness duration and were also influenced by other factors. Mothers' adjustment shortly after their children were diagnosed with IDDM was a strong predictor of their long-term emotional symptomatology. However, mothers' symptoms over time were not related to medical aspects of IDDM (i.e., the extent of the children's metabolic control, number of rehospitalizations, or their compliance with the medical regimen) and were also unrelated to the levels of depression or anxiety reported by their children. Mothers generally found it easier to cope with the IDDM the longer their children had the illness. However, the degree to which mothers perceived the IDDM to be bothersome or difficult to manage at any given point in time was associated with their overall levels of emotional distress. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Nutritional chemistry of chromium

There has been considerable progress in understanding the role of chromium in human nutrition. However, the lack of data on the forms of chromium-absorption from foods by the gastro-intestinal tract, and our concomitant inability to obtain an accurate assessment of the daily mobile pool of metabolically active chromium in the human body continues to be an impediment in assessing the overall impact of chromium nutrition. Based on recent chromium data on human tissues and body fluids available in the literature, an assessment of chromium content in different body compartments as well as in the total body is presented. However, on the analytical side, a few problems still persist and, therefore, a reliable analysis for chromium is restricted to a few selected laboratories.     

Online measurement of water content in candidate reference materials by acousto-optical tuneable filter near-infrared spectrometry (AOTF-NIR) using pork meat calibrants controlled by Karl Fischer titration

Certified reference materials (CRMs) are prepared from a wide variety of matrices. Water removal is an excellent way of achieving increased matrix lifetime and hence CRM stability. High-speed acousto-optical tuneable filter near-infrared spectrometry (AOTF-NIR) has been implemented for measurement of water content in powder matrix reference materials in amber glass vials. Almost 50,000 spectra were collected from 1300 to 2100 nm with a 2 nm increment for powders of meat, rye grass, potato, cotton seed and sugar beet. The AOTF-NIR instrument was placed in a capping machine, with a measurement frequency of 10–15 vials/min and a trigger signal for reproducible collection of spectra. The calibrants comprised 19 pork meat powder samples equilibrated with different hygrostatic solutions or subjected to oven drying to achieve different water concentrations. Mixtures of powders with different water content were also prepared in order to obtain a calibration range from 0.5 to 8.3% water (m/m). All calibration samples were measured by volumetric Karl Fischer titration (V-KFT), accredited under ISO 17025. The calibrants were then measured by AOTF-NIR together with the samples. Multiplicative scatter correction (MSC) was applied to the absorbance spectra in order to correct for the scattering of light in the different powders and scattering effects from the vials. A partial least squares regression model (PLS) based on two principal components was created and applied for prediction of water content in the samples with a standard error of 0.5% water (m/m).     

Studies on microstructure and density of sintered ZnO-based non-linear resistors

Systematic studies have been made of the grain growth and density of sintered ZnO-based systems containing one or more additive oxides of the type Nb₂O₅, Bi₂O₃, Sb₂O₃, CoO, Cr₂O₃, MnO₂, NiO and Al₂O₃. These samples were characterized using such techniques as scanning electron microscopy, X-ray diffraction and electron probe microanalysis. The influence of the nature and amount of additive oxides and sintering temperature is discussed in relation to microstructure, density and the phases present.     

Experimental Studies on Damage Growth in Composites under Dynamic Loads

Experimental investigations have been carried out to study the dynamic damage growth in glass/polyester composites. Detonation of two PETN explosive charges on a modified single edge notch (MSEN) specimen provides the dynamic load in the form of a planar tensile wave. High speed photography is used to record the dynamic damage events. The results show that damage grows perpendicular to the loading direction, similar to the static growth; the damage zone splits analogous to the crack branching in unreinforced polyester. The damage propagation velocity in a composite is higher than the crack propagation velocity in polyester resin. The damage area grows at an average rate of 4.3 m²/sec. Static experiments show that about 4 percent of the total energy is spent on the fiber-matrix interface debonding. The damage zone under dynamic loads is much higher than under static loads.     

Characterization of defects in gallium arsenide

It is well-known that the properties of semiconductor materials including gallium arsenide are controlled by defects and impurities. The characterization of these defects is important not only for better understanding of the solid state phenomena but also for improved reliability and performance of electronic devices. We have been investigating the defects in gallium arsenide for several years using deep level transient spectroscopy, photoconductivity, transient photoconductivity, photoluminescence etc. Results drawn from our recent studies are presented here to illustrate some of the problems concerning transition metal impurities, process-induced defects, occurrence of intracentre transitions and metastability of deep levels in gallium arsenide.