Mathematical Modeling of Heat and Mass Transfer during Convective Dehydration of an Anisotropic Cylindrical Foodstuff

Two‐dimensional, unsteady‐state mass transfer was studied for air drying of an anisotropic finite cylindrical body. A mathematical model was developed for predicting the temperature of the drying sample at any time and moisture in any position in the drying sample at any time. The anisotropic nature of the drying material was considered in the mathematical model by taking into account the different moisture diffusivities in the axial and radial directions. A cut fresh green bean was used as an anisotropic material and a pilot‐scaled dryer was set up to investigate the drying behavior of this foodstuff. Several length‐to‐diameter ratios of fresh green beans were considered and the mathematical model was validated by comparison of the predicted values of average moisture content with the experimental data. The model was used to predict the moisture distributions inside the drying samples. Different moisture content distributions in the axial and radial directions during drying confirms the anisotropic nature of cut green bean samples. © 2013 Wiley Periodicals, Inc. Heat Trans Asian Res; Published online in Wiley Online Library ( wileyonlinelibrary.com/journal/htj ). DOI 10.1002/htj.21119     

Producing Ti–6Al–4V/TiC composite with good ductility by vacuum induction melting furnace and hot rolling process

In this paper, Ti–6Al–4V/TiC composite was fabricated by VIM furnace and graphite crucible. X-ray diffraction analysis and EDS techniques were used to identify the phases in the material. Microstructure characteristics of the Ti–6Al–4V/TiC composite were evaluated by means of optical microscopy. The tensile test was performed at room temperature after hot-rolling of the samples in the beta phase field. The results revealed that at different melting times, three kinds of precipitates are formed in the microstructure including grain boundary, eutectic and transgranular precipitates. The size of transgranular precipitates was significantly larger than that of the other two types of carbides and had the worst effect on ductility. Furthermore, an increase in the amount of carbon by increasing the melting time led to an increase in hardness and strength and decrease in ductility. Finally, TiC/Ti–6Al–4V with high strength (∼1200 MPa) and good ductility (10% elongation and 15% reduction in area) was produced in VIM furnace using 0.5 min melting time.     

Rapid carbothermic synthesis of silicon carbide nano powders by using microwave heating

This paper reports an improved procedure for synthesis of silicon carbide nanopowders from silica by carbothermic reduction under fast microwave-induced heating. The powders have been prepared by direct solid-state reaction in a 2.45 GHz microwave field in nitrogen atmosphere after 40 h milling. For the first time, the formation of silicon carbide (β-SiC) as a major phase can be achieved at 1200 °C in 5 min of microwave exposure, resulting in nano sized particles ranging from 10 to 40 nm under optimized synthesis condition. The Rietveld quantitative phase-composition analysis confirmed that the major SiC polytype is cubic SiC (β-SiC) with 98.5(4) weight fraction and the remained is minor hexagonal SiC polytypic (α-SiC) phases. Therefore this method is the most efficient one for SiC powder synthesis in terms of energy and time saving as well as preparation of SiC nano powders.     

Rapid and green synthesis of bimetallic Au–Ag nanoparticles using an otherwise worthless weed Antigonon leptopus

We demonstrate a simple, straightforward, clean-green, single pot approach for the synthesis of bimetallic Ag/Au nanoparticles (BNPs) by using a highly invasive terrestrial weed coral vine (Antigonon leptopus). Aqueous extracts of the weed were found to reduce the metal ions to form nanosised aggregates and then stabilise them by preventing further aggregation. The efficacy of the extracts of all its parts was explored by varying the stoichiometry of reactants, temperature, pH and reaction time. The electron micrographs of the synthesised BNPs indicated the presence of particles of predominantly spherical shapes in sizes ranging from 10 to 60 nm. The presence of gold and silver atoms was confirmed from the energy dispersive X-ray, X-ray photoelectron and X-ray diffraction studies. The Fourier transform infra-red spectroscopic spectral study indicated that the phenolics (including flavonoids) and proteins contained in the plant extract could have been responsible for the formation and stabilisation of the BNPs.     

Effect of sulfur on graphite aspect ratio and tensile properties in compacted graphite irons

In this research, the effect of sulfur content on graphite aspect ratio and tensile properties of compacted graphite iron (CGI) was investigated. Different samples with sulfur levels ranging from 0.023 to 0.080% were produced in which the amount of magnesium was the same. Magnesium was added as FeSiMg by sandwich method and sulfur was added as pyrite powder in reaction chamber of the mold. In order to study the microstructure and mechanical properties, metallographic examination and mechanical tests were conducted on specimens. The metallographic results showed that increasing of sulfur level from 0.023 to 0.080% in constant magnesium level of 0.057% increases the graphite aspect ratio from 0.6 to 12.4. Evaluation of the mechanical test results indicated that increasing of sulfur level, decreases the tensile properties of compacted graphite iron.     

A collective and abridged lexical query for delineation of nanotechnology publications

In order to monitor articles/patents in nanotechnology, there is little agreement on a universal lexical query or even an explicit definition of nanotechnology. Here in the light of a proposed definition, a set of case studies has been conducted to remove keywords which are not exclusive to nanotechnology. This resulted in a collective and abridged lexical query (CALQ) for nanotechnology delineation. Through bibliometric quantification of already-proposed as well as the novel keywords, it was shown that all keywords included in CALQ have considerable exclusive retrieval and precision, while the removed keywords do not satisfy either of these numerical thresholds. This approach may also be applied for the future updating of CALQ.     

Controlled release of prednisolone acetate from molecularly imprinted hydrogel contact lenses

The aim of this work was to study the influence of methacrylic acid (MAA) as a comonomer and the application of a molecular imprinting technique on the loading and release properties of weakly crosslinked 2‐hydroxyethyl methacrylate (HEMA) hydrogels, with a view toward their use as reloadable soft contact lenses for the administration of prednisolone acetate (PA). The hydrogels were prepared with HEMA (95.90–98.30 mol %) as a backbone monomer, ethylene glycol dimethacrylate (140 mM) as a crosslinker, and MAA (0, 50, 100, or 200 mM) as a functional monomer. Different PA/MAA molar ratios (0, 1 : 8, 1 : 6, and 1 : 4) in the feed composition of the hydrogels were also applied to study the influence of the molecular imprinting technique on their binding properties. The hydrogels (0.4 mm thick) were synthesized by thermal polymerization at 60°C for 24 h in a polypropylene mold. The hydrogels were then characterized by the determination of their swelling and binding properties in water. Their loading and release properties were also studied in 0.9% NaCl and artificial lachrymal fluid. Increasing the MAA content of the hydrogel and applying the molecular imprinting technique led to an increase in the loading capacity of the hydrogel. The optimized imprinted hydrogel showed the highest affinity for PA and the greatest ability to control the release process, sustaining it for 48 h. The results obtained clearly indicate that the incorporation of MAA as a comonomer increased the PA loading capacity of hydrogel. Our data showed that the molecular imprinting technique also had a significant effect on the loading and release properties of the hydrogels. © 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012     

The likely adverse environmental impacts of renewable energy sources

The global attention has always been focussed on the adverse environmental impacts of conventional energy sources. In contrast nonconventional energy sources, particularly the renewable ones, have enjoyed a ‘clean’ image vis a vis environmental impacts. The only major exception to this general trend has been large hydropower projects; experience has taught us that they can be disastrous for the environment. The belief now is that minihydel and microhydel projects are harmless alternatives. But are renewable energy sources really as benign as is widely believed? The present essay addresses this question in the background of Lovin's classical paradigm, which had postulated the hard (malignant) and soft (benign) energy concepts in the first place. It critically evaluates the environmental impacts of major renewable energy sources. It then comes up with the broad conclusion that renewable energy sources are not the panacea they are popularly perceived to be; indeed in some cases their adverse environmental impacts can be as strongly negative as the impacts of conventional energy sources. The paper also dwells on the steps we need to take so that we can utilize renewable energy sources without facing environmental backlashes of the type we got from hydropower projects.