rGO Sheets/ZnFe2O4 Nanocomposities as an Efficient Electro Catalyst Material for I3−/I− Reaction for High Performance DSSCs

In this paper, Reduced Graphene Oxide (rGO)/ZnFe₂O₄ (rZnF) nanocomposite is synthesized by a simple hydrothermal method and employed as a counter electrode (CE) material for tri-iodide redox reactions in Dye sensitized solar cells (DSSC) to replace the traditional high cost platinum (Pt) CE. X-ray diffraction analysis and High resolution Transmission electron microscopy, clearly indicated the formation of rZnF nanocomposite and also amorphous rGO sheets were smoothly distributed on the surface of ZnFe₂O₄ (ZnF) nanostructure. The rZnF-50 CE shows excellent electro catalytic activity toward I₃^? reduction, which has simultaneously been confirmed by cyclic voltammetry, electrochemical impedance spectroscopy and Tafel polarization measurements. A DSSC developed by rZnF-50 CE (η?=?8.71%) obtained quite higher than the Pt (η?=?8.53%) based CE under the same condition. The superior performances of rZnF-50 CE due to addition of graphene in to Spinel (ZnF) nanostructure results in creation of highly active electrochemical sites, fast electron transport linkage between CE and electrolyte. Thus it’s a promising low cost CE material for DSSCs.

     

Yield and Quality Characteristics of Rendered Chicken Oil for Biodiesel Production

Whole dead poultry birds obtained from commercial layer farms were assessed for fat in the whole carcass and then dry rendered in three different rendering regimens T₁, T₂ and T₃ (temperature = 120, 130 and 140 °C and shell pressure = 1, 2 and 3 kg/cm² respectively) and the effect on the yield and quality of the rendered chicken oil were studied. The overall fat percentage of the whole dead poultry carcass was 14.55 ± 0.17 % and the fat content of ‘greaves’ was 14.49 ± 0.38 %. In the dry batch rendering trials, the mean overall fat recovery was 24.46 ± 1.19, 26.78 ± 3.14 and 22.42 ± 2.32 % and the overall fat yield was 3.52 ± 1.72, 3.84 ± 0.44 and 3.22 ± 0.33 % of the carcass weight in T₁, T₂ and T₃ respectively. Solvent extraction of fat could recover 96.10 ± 0.14 % of fat from ‘greaves’ which was significantly higher than the mechanical centrifugation method. Among the quality characteristics of the rendered chicken oil (RCO), moisture content ranged from 0.61 % (T₂) to 1.09 % (T₁) and the mean specific gravity was 0.91 at 30 °C. The FFA values of RCO obtained from the T₃ rendering regimen were significantly (p < 0.05) higher than the FFA values of T₂ and T₁. The mean acid value, iodine number, peroxide value, saponification value and unsaponifiable matter present in RCO showed no significant difference. The fatty acid profile and calorific values were studied. The RCO was converted to biodiesel by transesterification and the physico-chemical properties of the biodiesel were studied and compared with the Indian biodiesel specification.     

Linking care felt to engagement in innovative behaviors in the workplace: The mediating role of psychological conditions.

This study examines the relationships between care felt and engagement in innovative behaviors at work. We posit that when an individual perceives that coworkers care for him or her (i.e., care felt), this cultivates psychological conditions such as safety, meaningfulness, and availability, which result in a higher level of motivation and by implication engagement in innovative behaviors at work. A sample of 218 employees took part in the assessment of the relationship between the psychological conditions linked to care felt (measured at Time 1) and motivation and engagement in innovative behaviors (measured at Time 2). The results of structural equation modeling (SEM) indicate that care felt is positively linked to psychological conditions. The latter is positively related directly and indirectly (through motivation) to engagement in innovative behaviors. (PsycINFO Database Record (c) 2011 APA, all rights reserved)     

Internal flows which transist from turbulent through intermittent to laminar

A transition model for internal flows which enables the prediction of the change of flow regime from turbulent through intermittent to laminar has been implemented by numerical simulation. This model had previously been demonstrated to be effective for the prediction of the breakdown of an initially laminar internal flow and its subsequent transitions to either intermittent or turbulent states. The model was employed here to study a flow which is decelerated by passing through a conical diffuser. The flow enters the diffuser with a fully developed turbulent velocity profile and exhibits transitions either in the diffuser or in a pipe situated downstream of the diffuser exit. The presence or absence of flow separation affected the onset of laminarization. Proof that laminarization actually occurred is provided by the values of the fully developed friction factors in the pipe downstream of the exit of the diffuser. These friction factors spanned the range from pure laminar flow through intermittent flow to fully turbulent flow. Comparisons were made with established benchmarks for each of these three flow regimes.     

Mid-infrared diffused planar waveguides made of silver halide chloro-bromide

We have developed waveguides for the mid-IR spectrum using silver halide crystals. Diffused planar waveguides constructed from silver chlorobromide (AgClBr) with different diffusion thicknesses were designed and characterized. The waveguides were based on our changing the refractive index of the guiding layer by a diffusion of Br- ions into crystalline AgCl substrates. The waveguides were analyzed and investigated with a 10.6-microm CO2 laser, and the optically measured thicknesses of the waveguides were found to vary between 65 and 600 microm. The propagation losses were in the range of 4-16 dB/cm, and the maximal entrance angle was 62 degrees. The output beam distribution was measured and was in good correlation with a numerical analysis simulation based on a ray-tracing model, by use of the eikonal equation.     

Construction Management of a Small-Scale Accelerated Pavement Testing Facility

Research in accelerated pavement testing (APT) facilities has traditionally focused on the pavement performance such as rutting and fatigue cracking, but documentation on construction management and information of the actual pavement construction quality is limited. There are typically four critical factors that need to be considered to achieve the best possible outcome in construction: cost, schedule, construction process, and quality control, and management. With the objective of developing guidelines for planning and executing construction of a small-scale APT facility, this paper presents a case study documenting and evaluating the construction process and construction management efforts of two sensor-instrumented hot mix asphalt pavement test sections built in a small-scale APT facility. The focus of the experiment was to study bottom-up fatigue cracking of the flexible pavement structure. The presented information and lessons learned serve as a template and guide for agencies pursuing this type of research and pavement construction.     

Integrating visual goal models into the Rational Unified Process

The Rational Unified Process is a comprehensive process model that is tailorable, provides templates for the software engineering products, and integrates the use of the Unified Modeling Language (UML); it is rapidly becoming a de facto standard for developing software. The process supports the definition of requirements at multiple levels. Currently, the early requirements, or goals, are captured in a textual document called the Vision Document, as the UML does not include a goal modeling diagram. The goals are subsequently refined into software requirements, captured in UML Use Case Diagrams. Given the well documented advantages of visual modeling techniques in requirements engineering, including the efficient communication and understanding of complex information among numerous diverse stakeholders, the need for an enhanced version of the Vision Document template which supports the visual modeling of goals is identified. Here, an Enhanced Vision Document is proposed which integrates two existing visual goal models: AND/OR Graph for functional goals and Softgoal Interdependency Graph for non-functional goals. A specific approach to establishing traceability relationships from the goals to the Use Cases is presented. Tool support has been developed for the Enhanced Vision Document template; the approach is illustrated using an example system called the Quality Assurance Review Assistant Tool.     

Advanced trauma life support versus Combat Trauma Life Support courses: a comparison of cognitive knowledge decline

Post-thyroidectomy I-131 whole-body scintigraphy is an important aspect in the management of patients with thyroid cancer. The scan is used to detect residual thyroid tissue and distant functioning metastases. Extrathyroid I-131 accumulation does not always denote metastatic disease, and several potential sources of false-positive I-131 scans have been identified. This report presents four cases of benign oral disease as a cause of false-positive I-131 uptake. Benign oral disease has not been documented previously as an important source of false-positive I-131 whole-body scans.