Synthesis,Spectroscopy and Tautomeric Study of Thiazoles substituted in positions 2 and 4 by hydroxy,mercapto and amino groups

Thiazoles substituted in positions 2 and 4 by hydroxy, mercapto and amino groups were synthesized, as well as its carbamate derivates and formylhydrazones. The research of the reaction of the formylhydrazide with 4-imino-2-thiazolidinone has not given the pyrazolo [3,4-d]- thiazol-2-one, but the 4-formylhydrazono-2-thiazolidine. The detailed tautomeric study of each of the heterocyclic compounds has been carried out by infrared spectroscopy, nuclear magnetic resonance of proton and of 13-carbon, and of masses.     

High-Speed CMI Optical Intraoffice Transmission System: Design and Performance

This paper presents the design and performance features of a successfully developed optical intraoffice transmission system operating at 100-400 Mbits/s. The keys to the commercial realization of this simple, highly reliable, and low-cost system are the employment of the 1.3 μm LED and graded-index multimode fiber. Additionally important, the system makes use of coded mark inversion (CMI) coding to ensure bit sequence independence (BSI) and good error-monitoring capability. Experimental results have clarified the optimum bandwidth of the low-pass filter at the receiver end and the commercially attainable transmission distance. Furthermore, an available system gain of 15.4 dB is demonstrated through 400 Mbit/s transmission experiments. This value enables transmission over distances in excess of 4 km through multimode fiber (900 MHzcdotpkm, 0.8 dB/km).     

Monte Carlo simulation program for ecosystems

A Monte Carlo computer simulation program is designed in order to describe the spatial and time evolution of a population of living individuals under preassigned environmental conditions of energy. The simulation is inspired by previous techniques developed in physics--in particular, in molecular dynamics and simulations of liquids--and it already provides some new insights regarding macroscopic deterministic models in ecology and concerning eventual control of artificial biomass production plants.     

Large intracranial vessel occlusive vasculopathy after radiation therapy in children: clinical features and usefulness of magnetic resonance imaging

The marine rotifer, Brachionus plicatilis, is able to digest Chlorella efficiently, suggesting that the rotifer contains a powerful cellulolytic enzyme system. A multi-component cellulolytic complex, including endoglucanase (CM-cellulase), cellobiohydrolase and beta-glucosidase, was found in Brachionus plicatilis. Endoglucanase (endo-beta-1,4 glucanase) was purified to homogeneity from rotifer homogenates using a sequential chromatographic method. The purified enzyme exhibits a strong hydrolytic activity with carboxymethyl(CM)-cellulose. The optimum temperature and pH for the endoglucanase activity were 37 degrees C and 7.0, respectively. 80% of the CM-cellulase activity was retained in salt mixture that ranged from 150 to 500 mM NaCl equivalent. The purified protein was isolated with a molecular weight of approximately 62 kDa estimated by SDS-polyacrylamide gel electrophoresis.     

Design and performance of an optoelectronic matrix switch usingSi-p-i-n photodiodes

Switching speed, isolation, optical-source requirements, and attainable matrix dimensions of an optoelectronic matrix switch using Si p-i-n photodiodes are discussed. By charging the internal capacitance of the diode with a photocurrent, forward bias voltages are attained that establish off-states. The novel features of the matrix switch are that the switch elements have high output impedance at off-states, and no electrical power is required to establish the off-states. This leads to advantages in fabricating large-dimension matrix switches     

Dithioester functionalization of poly(cyclohexene oxide) and its application to obtain block copolymers

A new method of introducing dithioester groups into the polymer chain of poly(cyclohexene oxide) is reported. It includes the use of diaryliodonium salt and an aromatic dithioacid as a redox couple to initiate the cationic polymerization of cyclohexene oxide. It was found that the dithioacid by itself cannot start the polymerization of cationic polymerizable monomers; however, in combination with a diaryliodonium salt, an exothermic reaction was produced, yielding a thiocarbonylthio‐functionalized polyether. Thermal profiles of the redox polymerizations were determined by means of optical pyrometry. A preliminary study showed that when the poly(cyclohexene oxide) functionalized with dithioester groups was introduced into the radical polymerization of styrene, the polystyryl growing radicals reacted with the dithioester‐functionalized polyether to form a block polymer. The amount of polyether actually incorporated into the block copolymer was calculated to be 70% of the initial amount of poly(cyclohexene oxide)/dithiobenzoic acid charged into the reactor. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Eicosanoids and fat emulsions in acute respiratory distress syndrome patients

Laparoscopic splenectomy has been accepted as a feasible extension of minimally invasive surgery, which has undergone dramatic improvements in both technology and instrumentation. We performed a laparoscopic splenectomy in a 7-year-old girl with hereditary spherocytosis. The patient recovered rapidly and returned to unrestricted activities quickly. The appropriate positioning of each laparoscopic port is essential for a good operative view and smooth access. It is also important to dissect the hilum of the spleen meticulously. Laparoscopic splenectomy in the pediatric age group appears to be another promising extension of laparoscopic surgery.     

The Spanish transition to democracy seen through the Spanish database isoc

The study has tried to look at the political transition through the articles published by Spanish scientists in Spanish journals of Social Sciences and Humanities. A sample of 11000 article references from a selected set of 32 journals published from 1976 till 1985, has been the basis of the analysis. This time frame has been divided into two 5 year periods in order to detect any change in the topics published. The result of the analysis has been compared with the “events” as recorded by “El Pais” a very popular newspaper, during the same 10 year period and with a set of specific articles devoted to the Spanish political transition.