Growth of diamond microcrystals by the oriented attachment mechanism at high pressure and high temperature

For the first time it has been experimentally shown that a powder of detonation nanodiamonds (DND) and a saturated acyclic hydrocarbon, mono- or dibasic alcohol, used as the reaction mixture after treatment at high pressures (5–8 GPa) and high temperatures (1300–1800°C) results in the formation of diamond single crystals up to 15 micron in size. The Raman spectrum indicates that the diamonds have a perfect of crystal structure. It has been suggested that the oriented attachment mechanism is responsible for growth of micrometer-size diamond single crystals out of DND particles with sizes of about 5 nm under these technological conditions.     

Relaxation Losses of Magnetic Excitations in Nanoscale Films of Yttrium Iron Garnet

Relaxation losses of magnetic excitations in nanoscale films of Y₃Fe₅O₁₂ (YIG) were studied. The films were obtained by laser molecular-beam epitaxy (LMBE). Ferromagnetic resonance linewidth ΔH was found to increase sharply as the temperature decreased from 300 to 77 K. The observed growth of ΔH is explained by typical relaxation processes caused by the presence of Fe²⁺ ions. This effect is not observed in thick films of YIG grown by liquid-phase epitaxy and containing Pb⁴⁺ ions, and, hence, we have concluded that the presence of acceptor ions in YIG films obtained by LMBE will facilitate decreasing the concentration of Fe²⁺ ions and, a result, diminishing relaxation losses.     

Highly Exposed ?NH2 Edge on Fragmented g-C3N4 Framework with Integrated Molybdenum Atoms for Catalytic CO2 Cycloaddition: DFT and Techno-Economic Assessment

This study focuses on the applicability of single-atom Mo-doped graphitic carbon nitride (GCN) nanosheets which are specifically engineered with high surface area (exfoliated GCN),  NH₂ rich edges, and maximum utilization of isolated atomic Mo for propylene carbonate (PC) production through CO₂ cycloaddition of propylene oxide (PO). Various operational parameters are optimized, for example, temperature (130 °C), pressure (20 bar), catalyst (Mo₂GCN), and catalyst mass (0.1 g). Under optimal conditions, 2% Mo-doped GCN (Mo₂GCN) has the highest catalytic performance, especially the turnover frequency (TOF) obtained, 36.4 h⁻¹ is higher than most reported studies. DFT simulations prove the catalytic performance of Mo₂GCN significantly decreases the activation energy barrier for PO ring-opening from 50–60 to 4.903 kcal mol⁻¹. Coexistence of Lewis acid/base group improves the CO₂ cycloaddition performance by the formation of coordination bond between electron-deficient Mo atom with O atom of PO, while  NH₂ surface group disrupts the stability of CO₂ bond by donating electrons into its low-level empty orbital. Steady-state process simulation of the industrial-scale consumes 4.4 ton h⁻¹ of CO₂ with PC production of 10.2 ton h⁻¹. Techno-economic assessment profit from Mo₂GCN is estimated to be 60.39 million USD year⁻¹ at a catalyst loss rate of 0.01 wt% h⁻¹.     

Laser with rapid tuning of the spectrum shape

We have studied a laser system with quick electronic tuning of the spectrum shape and continuous distribution. The proposed method is based on separate control of phase and amplitude spatial distributions of resonator transmittance. Evolution of the spectral function of the diffractively coupled dispersive resonators and the model for the formation of the resonator with the spectral function given by its moments are studied theoretically. The synthesis of continuous spectra is investigated experimentally in the laser with a novel control element including a spatial acousto-optic modulator and a tunable lens telescope.     

Agents’ model of uncertainty

Multi-agent systems play an increasing role in sensor networks, software engineering, web design, e-commerce, robotics, and many others areas. Uncertainty is a fundamental property of these areas. Agent-based systems use probabilistic and other uncertainty models developed earlier without explicit consideration of agents. This paper explores the impact of agents on uncertainty models and theories. We compare two methods of introducing agents to uncertainty theories and propose a new theory called the agent-based uncertainty theory (AUT). We show advantages of AUT for advancing multi-agent systems and for solving an internal fundamental question of uncertainty theories, that is identifying coherent approaches to uncertainty. The advantages of AUT are that it provides a uniform agent-based representation and an operational empirical interpretation for several uncertainty theories such as rough set theory, fuzzy sets theory, evidence theory, and probability theory. We show also that the introduction of agents to intuitionist uncertainty formalisms can reduce their conceptual complexity. To build such uniformity the AUT exploits the fact that agents as independent entities can give conflicting evaluations of the same attribute. The AUT is based on complex aggregations of crisp (non-fuzzy) conflicting judgments of agents. The generality of AUT is derived from the logical classification of types (orders) of conflicts in the agent populations. At the first order of conflict, the two agent populations are disjoint and there is no interference of logic values assigned to any statement p and its negation by agents. The second order of conflict models superposition (interference) of logic values for overlapping agent populations where an agent assigns conflicting logic values (true, false) to the same attribute simultaneously.

$ell_1$ Optimal Robust Steady-State Tracking for Unknown First-Order Plant

This note considers the problem of the optimal ldquosteady-staterdquo tracking for an unknown first-order plant with an unknown control delay, under the assumption of known upper bounds on model parameters and the control delay. The plant is subjected to perturbations in output and control as well as an exogenous disturbance with unknown upper bounds. The solution of the problem is based on treating the control criterion, which is the worst-case steady-state value of an error signal, as the identification criterion.     

Properties of Gauss Digitized Shapes and Digital Surface Integration

This paper presents new topological and geometric properties of Gauss digitizations of Euclidean shapes, most of them holding in arbitrary dimension d. We focus on r-regular shapes sampled by Gauss digitization at gridstep h. The digitized boundary is shown to be close to the Euclidean boundary in the Hausdorff sense, the minimum distance \(\frac{\sqrt{d}}{2}h\) being achieved by the projection map \(\xi \) induced by the Euclidean distance. Although it is known that Gauss digitized boundaries may not be manifold when \(d \ge 3\), we show that non-manifoldness may only occur in places where the normal vector is almost aligned with some digitization axis, and the limit angle decreases with h. We then have a closer look at the projection of the digitized boundary onto the continuous boundary by \(\xi \). We show that the size of its non-injective part tends to zero with h. This leads us to study the classical digital surface integration scheme, which allocates a measure to each surface element that is proportional to the cosine of the angle between an estimated normal vector and the trivial surface element normal vector. We show that digital integration is convergent whenever the normal estimator is multigrid convergent, and we explicit the convergence speed. Since convergent estimators are now available in the literature, digital integration provides a convergent measure for digitized objects.     

Generating heavy particles with energy and momentum conservation

We propose a novel algorithm, called REGGAE, for the generation of momenta of a given sample of particle masses, evenly distributed in Lorentz-invariant phase space and obeying energy and momentum conservation. In comparison to other existing algorithms, REGGAE is designed for the use in multiparticle production in hadronic and nuclear collisions where many hadrons are produced and a large part of the available energy is stored in the form of their masses. The algorithm uses a loop simulating multiple collisions which lead to production of configurations with reasonably large weights.

Program summary

Program title: REGGAE (REscattering-after-Genbod GenerAtor of Events)Catalogue identifier: AEJR_v1_0Program summary URL:http://cpc.cs.qub.ac.uk/summaries/AEJR_v1_0.htmlProgram obtainable from: CPC Program Library, Queen?s University, Belfast, N. IrelandLicensing provisions: Standard CPC licence, http://cpc.cs.qub.ac.uk/licence/licence.htmlNo. of lines in distributed program, including test data, etc.: 1523No. of bytes in distributed program, including test data, etc.: 9608Distribution format: tar.gzProgramming language: C++Computer: PC Pentium 4, though no particular tuning for this machine was performed.Operating system: Originally designed on Linux PC with g++, but it has been compiled and ran successfully on OS X with g++ and MS Windows with Microsoft Visual C++ 2008 Express Edition, as well.RAM: This depends on the number of particles which are generated. For 10 particles like in the attached example it requires about 120 kB.Classification: 11.2Nature of problem: The task is to generate momenta of a sample of particles with given masses which obey energy and momentum conservation. Generated samples should be evenly distributed in the available Lorentz-invariant phase space.Solution method: In general, the algorithm works in two steps. First, all momenta are generated with the GENBOD algorithm. There, particle production is modeled as a sequence of two-body decays of heavy resonances. After all momenta are generated this way, they are reshuffled. Each particle undergoes a collision with some other partner such that in the pair center of mass system the new directions of momenta are distributed isotropically. After each particle collides only a few times, the momenta are distributed evenly across the whole available phase space. Starting with GENBOD is not essential for the procedure but it improves the performance.Running time: This depends on the number of particles and number of events one wants to generate. On a LINUX PC with 2 GHz processor, generation of 1000 events with 10 particles each takes about 3 s.     

An auto-generated real-time iteration algorithm for nonlinear MPC in the microsecond range

In this paper, we present an automatic C-code generation strategy for real-time nonlinear model predictive control (NMPC), which is designed for applications with kilohertz sample rates. The corresponding code export module has been implemented within the software package ACADO Toolkit. It is capable of exporting fixed step-size integrators together with their sensitivities as well as a real-time Gauss–Newton method. Here, we employ the symbolic representation of optimal control problems in ACADO in order to auto-generate plain C-code which is optimized for final production. The exported code has been tested for model predictive control scenarios comprising constrained nonlinear dynamic systems with four states and a control horizon of ten samples. The numerical simulations show a promising performance of the exported code being able to provide feedback in much less than a millisecond.