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When three-dimensional optical topometry of technical surfaces is performed, one major problem is that often the local reflectance of the object's surface varies within a wide range. This leads to overexposed and underexposed areas on the detector, where no measurements can be made. To overcome this problem, we have developed a method that extends the dynamic range of an imaging system. As an example we implemented this method to a measurement system that is based on fringe projection with a data projector and a color CCD camera. By projection of quasi-monochromatic fringes a different dynamic range in each of the three color channels of the camera is achieved. Hence the overall dynamic range of the system is increased by a factor larger than 5. 相似文献
954.
Raska CS Parker CE Dominski Z Marzluff WF Glish GL Pope RM Borchers CH 《Analytical chemistry》2002,74(14):3429-3433
Immobilized metal ion affinity chromatography (IMAC) is a useful method to selectively isolate and enrich phosphopeptides from a peptide mixture. Mass spectrometry is a very suitable method for exact molecular weight determination of IMAC-isolated phosphopeptides, due to its inherent high sensitivity. Even exact molecular weight determination, however, is not sufficient for identification of the phosphorylation site if more than one potential phosphorylation site is present on a peptide. The previous method of choice for sequencing the affinity-bound peptides was electrospray tandem mass spectrometry (ESI-MS/MS). This method required elution and salt removal prior to MS analysis of the peptides, which can lead to sample loss. Using a matrix-assisted laser desorption/ionization (MALDI) source coupled to an orthogonal injection quadrupole time-of-flight (QqTOF) mass spectrometer with true MS/MS capabilities, direct sequencing of IMAC-enriched peptides has been performed on IMAC beads applied directly to the MALDI target. The utility of this new method has been demonstrated on a protein with unknown phosphorylation sites, where direct MALDI-MS/MS of the tryptic peptides bound to the IMAC beads resulted in the identification of two novel phosphopeptides. Using this technique, the phosphorylation site determination is unambiguous, even with a peptide containing four potentially phosphorylated residues. Direct analysis of phosphorylated peptides on IMAC beads does not adversely affect the high-mass accuracy of an orthogonal injection QqTOF mass spectrometer, making it a suitable technique for phosphoproteomics. 相似文献
955.
Surface-protected, air-stable nanoparticles of CoPt and CoPt3 were prepared by thermal decomposition/reduction of organometallic precursors with a long-chain aliphatic diol, also known as the polyol process. Particles 3 nm in diameter showed ferromagnetic behavior up to 350 K (Hc = 65 Oe at T = 300 K; Hc = 410 Oe at T = 5K) and underwent a disordering-ordering phase transformation after annealing that resulted in an increase in coercivity (Hc = 170 Oe at T = 300 K; Hc = 2000 Oe at T = 5 K). 相似文献
956.
Karthiga Kanthasamy Markus Ring Dennes Nettelroth Christoph Tegenkamp Holger Butenschön Fabian Pauly Herbert Pfnür 《Small (Weinheim an der Bergstrasse, Germany)》2016,12(35):4849-4856
The charge transport through ferrocene 1,1′‐diamine (FDA) molecules between gold electrodes is investigated using the mechanically controllable break junction technique combined with a theoretical framework of density functional theory simulations to understand the physics of these molecular junctions. The characteristic conductances of the molecule are measured at low bias as well as current–voltage (IV) characteristics. By fitting the IV characteristics to the single‐level model, the values for the position of the molecular level, mainly responsible for the transport, and its coupling to the leads, are obtained. The influence of the binding sites, molecular conformation, and electrode distance are systematically studied from a theoretical perspective. While a strong dependence of conductance on the adsorption geometry is found, the decrease of conductance as a function of electrode distance arises mainly from a decrease of coupling strength of the molecular electronic orbitals through a reduced overlap and, to a lesser extent, from a shift of their alignment with respect to the Fermi energy. 相似文献
957.
Keith Arnold Christoph Kenel Alberto Colella Paolo Matteazzi 《Materials at High Temperatures》2018,35(1-3):141-150
AbstractGas atomised IN625 powder was mechanically alloyed with <1·0 Wt.% nano-yttria and consolidated by spark plasma sintering (SPS) to produce an oxide dispersion strengthened (ODS) alloy. The isothermal oxidation rate constant of the ODS alloy, and wrought IN625, was determined by thermogravimetric analysis. This was performed at 900 °C in static laboratory air for exposure times of up to 1000 h. It was found that the ODS alloy oxidised ~40x slower than wrought IN625, which is attributed to the reactive element effect. It is further proposed that the improvement in oxidation resistance of the ODS alloy, and the superior morphology of the oxide scale formed on the ODS alloy, may be related to the presence of Nb carbide, rather than δ-phase, in the ODS alloy. 相似文献
958.
959.
Anomalous Resistance Hysteresis in Oxide ReRAM: Oxygen Evolution and Reincorporation Revealed by In Situ TEM 下载免费PDF全文
David Cooper Christoph Baeumer Nicolas Bernier Astrid Marchewka Camilla La Torre Rafal E. Dunin‐Borkowski Stephan Menzel Rainer Waser Regina Dittmann 《Advanced materials (Deerfield Beach, Fla.)》2017,29(23)
The control and rational design of redox‐based memristive devices, which are highly attractive candidates for next‐generation nonvolatile memory and logic applications, is complicated by competing and poorly understood switching mechanisms, which can result in two coexisting resistance hystereses that have opposite voltage polarity. These competing processes can be defined as regular and anomalous resistive switching. Despite significant characterization efforts, the complex nanoscale redox processes that drive anomalous resistive switching and their implications for current transport remain poorly understood. Here, lateral and vertical mapping of O vacancy concentrations is used during the operation of such devices in situ in an aberration corrected transmission electron microscope to explain the anomalous switching mechanism. It is found that an increase (decrease) in the overall O vacancy concentration within the device after positive (negative) biasing of the Schottky‐type electrode is associated with the electrocatalytic release and reincorporation of oxygen at the electrode/oxide interface and is responsible for the resistance change. This fundamental insight presents a novel perspective on resistive switching processes and opens up new technological opportunities for the implementation of memristive devices, as anomalous switching can now be suppressed selectively or used deliberately to achieve the desirable so‐called deep Reset. 相似文献
960.
Christoph Tondera Teuku Fawzul Akbar Alvin Kuriakose Thomas Weilin Lin Carsten Werner Volker Busskamp Yixin Zhang Ivan R. Minev 《Small (Weinheim an der Bergstrasse, Germany)》2019,15(27)
Electrically conductive materials that mimic physical and biological properties of tissues are urgently required for seamless brain–machine interfaces. Here, a multinetwork hydrogel combining electrical conductivity of 26 S m?1, stretchability of 800%, and tissue‐like elastic modulus of 15 kPa with mimicry of the extracellular matrix is reported. Engineering this unique set of properties is enabled by a novel in‐scaffold polymerization approach. Colloidal hydrogels of the nanoclay Laponite are employed as supports for the assembly of secondary polymer networks. Laponite dramatically increases the conductivity of in‐scaffold polymerized poly(ethylene‐3,4‐diethoxy thiophene) in the absence of other dopants, while preserving excellent stretchability. The scaffold is coated with a layer containing adhesive peptide and polysaccharide dextran sulfate supporting the attachment, proliferation, and neuronal differentiation of human induced pluripotent stem cells directly on the surface of conductive hydrogels. Due to its compatibility with simple extrusion printing, this material promises to enable tissue‐mimetic neurostimulating electrodes. 相似文献