Physical Aging of Amorphous Fructose

ABSTRACT: Physical aging of amorphous anhydrous fructose at temperature 5 °C and at 22 °C was studied using differential scanning calorimetry (DSC). The dynamic glass transition temperature, T_g0 for unaged samples was 16 °C and 13.3 °C for heating rate of 10 °C/min and 1 °C/min, respectively. The fictive temperature, T_f0 for unaged samples calculated by Richardson and Savill method was 12 °C, which is close to the dynamic value obtained from the lower DSC heating rate. The fictive temperature T_f of the aged fructose glasses at temperatures both below and above the transition region was fitted well by a non-exponential decay function (Williams-Watts form). Aging above the transition region (22 °C) for 18 d increased both the dynamic glass transition temperature T_g and the fictive temperature T_f. However, aging below the transition region (5 °C) for 1 d increased the dynamic glass transition temperature T_g but decreased the fictive temperature T_f.     

Comparison of the GFFF and LALLS Methods for the Measurement of Starch Granule Size Distribution in Spring Barley Caryopses

A newly developed method GFFF (Gravitational Field‐Flow Fractionation) and the well known method LALLS (Low Angle Laser Light Scattering) were used to assess starch granule size distribution of ten varieties of spring barley. As a distribution criterion, the ratio of starch granule content larger than 8 μm (type A) and smaller than 8 μm (type B) was chosen. Both methods divided the observed set in a similar way. Varieties Akcent, Forum and Atribut formed a variety set with the highest ratio of large and small starch granules. Varieties Scarlet and Kompakt had intermediate ratios. The remaining five varieties Amulet, Novum, Olbram, Tolar and Krona had the lowest ratios of large and small starch granules. Statistical analysis showed that there was a highly significant correlation between the GFFF and LALLS methods.     

On the application of adaptive antennas to microcellularenvironments: radio channel characteristics and system performance

The possible application of adaptive antennas in microcellular operational environments is studied in this paper with the help of a site-specific ray-tracing propagation model. First are examined the statistics of propagation parameters that play an important role for the performance of adaptive antennas. Particular emphasis is put on the spatial characteristics of the radio channel under line-of-sight (LOS) and non-LOS conditions. For this reason, area statistics are produced for a typical small-cell environment for parameters such as the number of multipath clusters, number of rays, angular size, and excess delay of each impulse response, as well as the number of rays, angular size and power of the multipath clusters. Results show that contrary to the common belief for such environments, the signal is not "almost" uniformly distributed in the spatial domain, instead is contained in a few narrow clusters. Then the effect of the microcellular environment on the uplink performance of some well-known techniques like conventional beamforming, maximum entropy, switched beams, maximum ratio and optimum combining, and beam-space optimum combining is examined . The results show that for typical time-division multiple-access (TDMA) scenarios with one and two users, the beam space optimum combining (strongest eigenvalue version) and the switched beams methods, offer the best performance     

Portable system for data acquisition and transmission based on handheld PC technology

A portable system is developed to monitor physical activity by acquiring and storing data from body-mounted sensors; a handheld PC is used for managing data acquisition and storage, including radio-transmission to a remote host. An application related to the use of a gyro-accelerometric sensor for determining walking distance is discussed.     

Electronic properties of Fibonacci quasi-periodic heterostructures

We study the electronic states of different GaAs-AlAs Fibonacci quasi-perodic heterostructures grown along the (001) direction. We employ an empirical tight-binding Hamiltonian including spin-orbit coupling together with the surface Green function matching method. We present results for the eighth Fibonacci generation formed from different building blocks. We compare these results with those of the constituent quantum wells and with those of heterostructures containing the same number of GaAs and AlAs slabs after periodic repetition of the building blocks. No Fibonacci spectrum is found in the energy regions near the conduction and valence band edges of GaAs. A selective localization of the local density of states in the GaAs layers is found for many electronic states.     

Vestigial sideband filtering at 10 Gbit/s using 12.5 GHzchannel-spacing demux

A 32-channel 12.5 GHz-spaced free-space demux with low crosstalk and low polarisation dependent loss has been constructed. Using this demux, vestigial sideband filtering at 10 Gbit/s has been studied. It is shown that this demux can achieve very high spectral efficiency without polarisation division multiplexing     

Low-loss athermal bulk-optic flat-top passband MUX/DMUX

Low-loss (<6 dB), flat-top, 16-wavelength, 100-GHz channel spacing DWDM (de)multiplexers are reported. The bulk-optics architecture used allows excellent thermal stability for operating temperature [-10, 60°C]     

A Varshamov-Gilbert bound for a class of formally self-dual codesand related quantum codes

It is proved that a class of q-ary (2n,n) formally self-dual codes obtained from symmetric matrices over GF (q), contains codes that meet the Varshamov-Gilbert bound. The codes are self-dual with respect to the symplectic inner product and yield quantum codes encoding one state with n q-ary qubits and having minimum distance proportional to n     

Nondestructive evaluation of the characteristics of degraded materials using backward radiated ultrasound

The frequency dependency of Rayleigh surface wave is investigated indirectly by measuring the angular dependency of the backward radiation of the incident ultrasonic wave in two kinds of degraded specimens by scuffing or corrosion. Then, the frequency dependency is compared with the residual stress distribution or the corrosion-fatigue characteristics for the scuffed or corroded specimens, respectively. The width of the backward radiation profile increases with the increase of the variation in residual stress distribution for the scuffed specimens. In the corroded specimens, the profile width decreases with the increase of the effective aging layer thickness and is inversely proportional to the exponent, m, in the Paris’ law that can predict the crack size increase due to fatigue. The result observed in this study demonstrates high potential of backward radiated ultrasound as a tool for nondestructive evaluation of subsurface gradient of material degradation generated by scuffing or corrosion.     

Interface stability during displacement reactions between Cu<Subscript>2</Subscript>O and Co<Subscript>1−<Emphasis Type="Italic">X</Emphasis></Subscript>Fe<Subscript><Emphasis Type="Italic">X</Emphasis></Subscript> alloys at 1223 K

The stability of the reactive interface during the solid-state displacement reaction, Cu₂O+Co_1−X Fe _X =2Cu+(Co_1−X Fe _X )O, is studied as a function of Co-Fe alloy composition at 1223 K. For X≤0.03, the reaction zone has a layered structure, and the cation diffusion in (Co, Fe)O is the rate-limiting step. The interface is unstable in the early stages of the reaction; the instability decreases with time as the oxide thickness increases, and the interface becomes planar at long times. The time required for the attainment of interface planarity increases with the value of X. The reaction kinetics are consistent with the available cation-diffusion data in (Co, Fe)O. For X≥0.045, the product zone is a composite of Cu+(Co, Fe)O, and the rate is limited by the oxygen transport in copper. The transition to interface instability occurs when the oxide can support a cation flux that exceeds the maximum possible oxygen flux in copper. During the reaction, composition gradients develop in (Co, Fe)O because of higher diffusion rates for iron than for cobalt.