Effect of temperature,storage times,and stress state on the caking of bulk materials

Results are reported from experimental studies of the susceptibility of bulk materials to caking in relation to temperature conditions, storage times, and the stress state of the material.Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 51, No. 3, pp. 462–464, September, 1986.     

Determination of the shear deformation resistance of powders

Translated from Poroshkovaya Metallurgiya, No. 3(315), pp. 30–32, March, 1989.     

Wafer-Scale High-Quality Microtubular Devices Fabricated via Dry-Etching for Optical and Microelectronic Applications

Mechanical strain formed at the interfaces of thin films has been widely applied to self-assemble 3D microarchitectures. Among them, rolled-up microtubes possess a unique 3D geometry beneficial for working as photonic, electromagnetic, energy storage, and sensing devices. However, the yield and quality of microtubular architectures are often limited by the wet-release of lithographically patterned stacks of thin-film structures. To address the drawbacks of conventionally used wet-etching methods in self-assembly techniques, here a dry-release approach is developed to roll-up both metallic and dielectric, as well as metallic/dielectric hybrid thin films for the fabrication of electronic and optical devices. A silicon thin film sacrificial layer on insulator is etched by dry fluorine chemistry, triggering self-assembly of prestrained nanomembranes in a well-controlled wafer scale fashion. More than 6000 integrated microcapacitors as well as hundreds of active microtubular optical cavities are obtained in a simultaneous self-assembly process. The fabrication of wafer-scale self-assembled microdevices results in high yield, reproducibility, uniformity, and performance, which promise broad applications in microelectronics, photonics, and opto-electronics.     

Silica coated hard-magnetic strontium hexaferrite nanoparticles

Stable colloids of hard magnetic particles are newly developed and very promising materials. Surface functionalization of these particles remains challenging because the particles tend to aggregate during reaction due to strong magnetic interactions. Herein we report on a synthesis of strontium hexaferrite hard magnetic nanoparticles coated with silica by hydrolysis of tetraethoxysilane. As a source of hexaferrite we used stable colloid of plate-like nanoparticles with mean diameter of 40 nm and thickness of 5 nm, which were prepared by a glass-ceramic process. We have shown that to successfully coat each hexaferrite particle individually the hydrolysis conditions should provide heterogeneous nucleation of silica with rate higher than the aggregation rate of the colloidal nanoparticles. The resulting materials represent single crystal hexaferrite cores wrapped in silica shell with mean thickness of 18 and 23 nm depending on synthesis conditions. The obtained core-shell particles can be easily dispersed as stable aqueous colloids. The materials can be used as magnetic sorbents or nanocontainers and, furthermore, they are very promising colloidal building blocks for various magnetically assembled nanostructures.     

New iterative reconstruction methods for fan-beam tomography

In this paper, we present a novel class of iterative reconstruction methods for severely angular undersampled or/and limited-view tomographic problems with fan-beam scanning geometry. The proposed algorithms are based on a new analytical transform which generalizes Fourier-slice theorem to divergent-beam scanning geometries. Using a non-rigid coordinate transform, divergent rays can be reorganized into parallel ones. Therefore, one can employ a simpler parallel-beam projection model instead of more complicated divergent-beam geometries. Various existing iterative reconstruction techniques for divergent-beam geometries can be easily adapted to the proposed framework. The significant advantage of this formulation is the possibility of exploiting efficient Fourier-based recovery methods without rebinning of the projections. In case of highly sparse measurements (few-view data), rebinning methods are not suitable due to error-prone angular interpolation involved. In this work, three new methods based on the novel analytical framework for fan-beam geometry are presented: the Gerchberg-Papoulis algorithm, the Neumann decomposition method and its total variation regularized version. Presented numerical experiments demonstrate that the methods can be competitive in reconstructing from few-view noisy tomographic measurements.     

Flexible surface-enhanced Raman scattering-active substrates based on nanofibrous membranes

Surface-enhanced Raman scattering (SERS) has emerged as an excellent analytical tool for the effective detection and fingerprint identification of various chemicals. Recently, significant progress has been made in the fabrication of SERS-active substrates using simple, inexpensive, and affordable methods. The full potential of universal SERS diagnostics will likely be realized with the development of approaches and devices capable of effectively detecting analytes on various surfaces as well as in multicomponent media. In addition, the combination of implantable or wearable SERS-active substrates and remote portable devices enables real-time diagnostics that ideally fit the concept of personalized medicine. In this paper, we summarize recent achievements in fabricating flexible SERS substrates made of cellulose paper, polymer membranes, and textile fibrous films. Emphasis is placed on the in-situ extraction and detection of various chemicals in real-world surfaces and complex media using flexible nanofibrous SERS platforms. The potential SERS applications and future perspectives in on-site diagnostics are also discussed.

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Spherical harmonics method applied to the multi-dimensional radiation transfer

The spectral radiation transfer equation in 2D axisymmetrical and 3D geometries is solved by the P₁-approximation of the spherical harmonics and ray-tracing methods. Martian atmosphere and typical entry conditions are considered. Navier–Stokes equations coupled with the nonequilibrium vibrational excitation and finite rate chemistry describe thermodynamically and chemically nonequilibrium gas. The multi-group model is used to model optical properties of CO₂–N₂ mixture. The developed methodology of integration of the P₁-approximation on unstructured grids and subsequent numerical solution allow us to reach reasonable agreement with the accurate ray-tracing method and drastically reduce the cost of solution of the radiation transfer equation in multi-dimensional geometries.     

Early Development of the GABAergic System and the Associated Risks of Neonatal Anesthesia

Human and animal studies have elucidated the apparent neurodevelopmental effects resulting from neonatal anesthesia. Observations of learning and behavioral deficits in children, who were exposed to anesthesia early in development, have instigated a flurry of studies that have predominantly utilized animal models to further interrogate the mechanisms of neonatal anesthesia-induced neurotoxicity. Specifically, while neonatal anesthesia has demonstrated its propensity to affect multiple cell types in the brain, it has shown to have a particularly detrimental effect on the gamma aminobutyric acid (GABA)ergic system, which contributes to the observed learning and behavioral deficits. The damage to GABAergic neurons, resulting from neonatal anesthesia, seems to involve structure-specific changes in excitatory-inhibitory balance and neurovascular coupling, which manifest following a significant interval after neonatal anesthesia exposure. Thus, to better understand how neonatal anesthesia affects the GABAergic system, we first review the early development of the GABAergic system in various structures that have been the focus of neonatal anesthesia research. This is followed by an explanation that, due to the prolonged developmental curve of the GABAergic system, the entirety of the negative effects of neonatal anesthesia on learning and behavior in children are not immediately evident, but instead take a substantial amount of time (years) to fully develop. In order to address these concerns going forward, we subsequently offer a variety of in vivo methods which can be used to record these delayed effects.