既有屋面防水喷涂聚脲整体翻新技术

我国既有屋面防水改造面临工作量日多,且无相关技术规范、完善的系统设计以及适用的材料等问题,喷涂聚脲防水涂料性能优异,以它为主构建的无缝防水体系适用于各类屋面,工程防水效果显著、施工简便。     

硅酮密封胶中矿物油增塑剂的应用及其检测方法研究

介绍了国内建筑硅酮密封胶中矿物油增塑剂的品种、性能和应用情况,分析了滥用矿物油增塑剂产生的危害,概述了基于热失重方法定量检测硅酮密封胶中矿物油增塑剂含量的研究结果,提出了改进检测方法包括选择较高试验温度和较长加热时间的建议.     

肇庆高新区垃圾中转站项目全过程造价管理实践

搞要:通过肇庆高新区垃圾中转站项目建设管理实践,探讨建筑工程项目各阶段造价管理的特点和重点,其中决策阶段重点是加强对项目建议书及可行性研究报告投资估算的审核和审批;设计阶段是加强对初步设计总概算和项目预算书的审定;招投标阶段是确定合理的控制价,完善合同条款;施工实施阶段是控制材料价格,减少设计变更;竣工验收和项目后评价阶段是加强对竣工结算的审核等。本文的经验可为建设工程项目管理提供一些借鉴。     

Preparation of a novel chelating resin bearing amidinothiourea moieties and its removal properties for Hg(II) ions in aqueous solution

A novel chelating resin bearing amidinothiourea (ADTU) moieties was prepared by chloroethyl crosslinked polystyrene (CMPS) with ADTU in the presence of a phase transfer catalyst. Fourier transform infrared spectra (FT-IR) and scanning electron microscopy (SEM) were used to characterized the resulting chelating resin. The saturated adsorption capacity of Hg(II) ions estimated from the Langmuir model was up to 1215 mg g^?1at 313 K. Furthermore, the resin was able to selectively separate Hg(II) from multicomponent solutions with Cd(II), Co(II), Cu(II), Zn(II), Mg(II) and Pb(II). The desorption process showed the mercury recovery reached to 99.2% under eluting condition of 1 M HCl + 8% thiourea.     

Preparation and characterization of the modulus intermediate layer in carbon fiber/epoxy composites by depositing sepiolites

An important aspect in development of multi‐scale reinforced composites is their mass production which can be easily realized. In this article, the sepiolites (Si12O30Mg8(OH)4(OH2)4·8H2O) are directly deposited onto the surface of JH‐T800 carbon fibers for the first time with no need for removal of the commercial sizing agent. The sepiolites adhering to the carbon fibers are uniformly distributed with random orientation, and participated in the formation of high modulus intermediate layer encompassing the carbon fiber. After the deposition of sepiolites, the interfacial shear strengths (IFSS) of the carbon fiber/epoxy composites are significantly improved as shown in single‐fiber composite fragmentation tests. Compared to the commercial carbon fiber composites, the sepiolite‐deposited fiber composites also exhibit obvious improvement in the interlaminar shear strength and flexural strength. As a new kind of multi‐scale reinforcement with industrial application value, the sepiolite‐deposited carbon fibers can further raise the level of mechanical properties of the existing carbon fiber reinforced composites. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43955.     

High‐performance polymer‐supported extractants with phosphonate ligands for scandium(III) separation

As the market demand for scandium has grown, a great deal of interest has been generated in its recovery. To substantially simplify the process and provide a green alternative for scandium separation, novel polymer‐supported extractants containing di(2‐ethylhexyl) phosphonate and bis(2,4,4‐trimethylpentyl) phosphonate, [D201][DEHP] and [D201][C272] are proposed because they demonstrate improved adsorption capacity and selectivity toward scandium(III). Scandium(III) adsorption is significantly affected by the solution pH, with the maximum adsorption occurring at a pH of approximately 0.78. The batch adsorption data fit well with the Langmuir isotherm and pseudo‐second‐order kinetic models. A combination of the Fourier transform infrared and XPS spectra suggest that the complexation of oxygen atoms in phosphate groups with scandium(III) is the predominant adsorption mechanism. Additionally, the two resins were used to recover scandium from leaching liquor of nickel laterite ore. [D201][DEHP] exhibits unusual selectivity for scandium and low competitive behavior with other metals, thus increasing its market potential. © 2016 American Institute of Chemical Engineers AIChE J, 62: 2479–2489, 2016     

Significant Improvement of Superconducting Properties in Nano‐NiFe2O4‐Doped Y–Ba–Cu–O Single‐Grain Superconductor

Introduction of refined second‐phase particles in superconducting YBa₂Cu₃O_7?x (Y‐123) matrix is known to be an effective route to improve the δl‐type pinning and the performance of Y–Ba–Cu–O (YBCO) single‐grain superconductors, while the δT_c‐type pinning induced by spatial fluctuations in matrix composition is also important and contributes to the in‐field J_c performance and high‐field applications of bulk superconductors. In this communication, chemical doping of nano‐sized NiFe₂O₄ (mean size 50 nm) in single‐grain YBCO superconductor is performed using a novel top‐seeded infiltration growth (TSIG) technique based on a solid source pellet (SSP) of nano‐Y₂O₃ + BaCuO₂. The results indicate that, significant improvement of bulk performances including levitation force (33.93 N) and trapped field (0.3628 T) has been observed in the 0.2 wt% nano‐NiFe₂O₄‐doped sample, which are much higher than the undoped sample (28.81 N and 0.2754 T). T_c measurement indicates that, a decreased onset T_c of about 87.5 K and a broadened transition width of about 5 K are observed in the NiFe₂O₄‐doped sample, indicating appearance of weak superconducting regions in superconducting matrix caused by Ni and Fe substitutions in Y‐123 crystal lattice. This study supplies a practical approach to increase the YBCO bulk performance significantly.     

对水泥生料易烧性试验方法的改进

正0前言水泥生料易烧性是评价水泥原料和生料的重要工艺指标,是正确选择原料、设计生料、确定生料准备方法以及保证高产低耗的重要依据和参数[1]。目前,水泥生料的易烧性都是按照GB/T26566—2011《水泥生料易烧性试验方法》进行试验。但是在实际应用过程中发现,利用该标准方法进行检测时,由于加水量小而不易拌匀,且试体太小需反复制备试体。同时煅烧时需要在温度稍低的高温炉内先预烧,然后取出再放入更高温度的高温炉内煅烧,且煅