Esterification and Transesterification of Renewable Chemicals

An overview is given of newly developed Lewis or Brønsted acid and base catalysts for esterification, transesterification and ester interchange reactions. The most relevant applications of these catalysts and reactions in the domain of renewable resources, in particular, oils and fats, are discussed.     

Aphid deterrence by glucose esters in glandular trichome exudate of the wild tomato,Lycopersicon pennellii

Settling of the potato aphid,Macrosiphum euphorbiae, on feeding membranes was deterred by methanolic leaf rinses ofLycopersicon pennellii, or of its F₁ with tomato,L. esculentum. The active compounds in theL. pennellii rinsates were identified as 2,3,4-tri-O-acylglucoses bearing short to medium chain length fatty acids. These compounds are localized in the glandular exudate of the type IV trichomes and may accumulate to levels in excess of 400 g/cm². In choice assays, purified glucose esters fromL. pennellii reduced aphid settling at concentrations as low as 25 g/cm²; at concentrations of 150 g/cm² or more, all aphids avoided treated areas. Glucose esters were also active in deterring aphid settling in no-choice assays. At 100 g/ cm², these esters resulted in increased levels of mortality after 48 hr.     

Patientenverfügung und Behandlungsvereinbarung als Instrumente der Vorausplanung in der forensischen Psychiatrie

Definition of the problem

In Germany as well as in many other countries, mentally ill criminals who are not guilty by reasons of insanity can be sentenced to psychiatric treatment in forensic clinics. In 2011, the German Constitutional Court substantially strengthened these patients’ right to self-determination in case of treatment refusal.

Arguments

In this context, we discuss the significance of instruments of advance healthcare planning. First, we describe the context of psychiatric treatment in forensic clinics and the changes the new German legal regulations brought about. A case study helps to illustrate the consequences of treatment refusal for both patient and healthcare personnel.

Conclusion

Eventually, we discuss if and how advance directives and joint crisis plans can be useful in forensic clinics and how additional measures can help to facilitate patient self-determination.

     

The dynamic contact area of elastomers at different velocities

The friction in tribo-systems that contain viscoelastic materials, such as elastomers, is relevant for a large number of applications. Examples include tyres, hoses, transmission and conveyor belts. To quantify the friction in these applications, one must first understand the contact behaviour of such viscoelastic materials, both in static and in dynamic situations. This work discusses an experimental study into the change of the contact area with the sliding velocity and relates the change in contact area with the mechanical properties of the elastomer. The results show that for a tribo-system containing an elastomer, there is a threshold velocity, above which the size of the contact area significantly reduces.     

Viewing direction measurements on flat and curved flexible E‐paper displays

The viewing direction characterization of reflective displays is more demanding than for emissive displays because defined illumination–detection geometries must be maintained for each viewing direction. In addition, the geometry should mimic the behavior of viewers who tend to exclude the reflection of light sources from a handheld reflective display. Viewing direction data was extracted from measured Bidirectional Reflectance Distribution Functions, showing that a source inclination of 45° sufficiently excludes the specular and haze components of source reflection from the measurement. Applying this so‐called 45/θ geometry to curved flexible displays is not straightforward since viewing direction, display curvature, and alignment each affect the measured reflectance. The viewing direction geometry proposed for convex cylindrical displays uses a ring light to deliver viewing‐direction independent illuminance, and maps the range of viewing directions onto the pixels of an image sensor. The illumination can also be applied to flat displays, allowing direct comparisons of flat and cylindrical display states. First results on e‐paper show good agreement with Bidirectional Reflectance Distribution Function data.     

Perceptual evaluation of backchannel strategies for artificial listeners

Artificial listeners are virtual agents that can listen attentively to a human speaker in a dialog. In this paper, we present two experiments where we investigate the perception of rule-based backchannel strategies for artificial listeners. In both, we collect subjective judgements of humans who observe a video of a speaker together with a corresponding animation of an artificial listener. In the first experiment, we evaluate six rule-based strategies that differ in the types of features (e.g. prosody, gaze) they consider. The ratings are given at the level of a speech turn and can be considered a measure for how human-like the generated listening behavior is perceived. In the second experiment, we systematically investigate the effect of the quantity, type and timing of backchannels within the discourse of the speaker. Additionally, we asked human observers to press a button whenever they thought a generated backchannel occurrence was inappropriate. Both experiments together give insights in the factors, both from an observation and generation point-of-view, that influence the perception of backchannel strategies for artificial listeners.     

Design and analysis of migration in parallel evolutionary algorithms

Parallelization is becoming a more important issue for solving difficult optimization problems. Island models combine phases of independent evolution with migration where genetic information is spread out to neighbored islands. This can lead to an increased diversity within the population. Despite many successful applications, the reasons behind the success of island models are not well understood. We perform a first rigorous runtime analysis for island models and construct a function where phases of independent evolution as well as communication among the islands are essential. A simple island model with migration finds a global optimum in polynomial time, while panmictic populations as well as island models without migration need exponential time, with very high probability. Our results lead to new insights into the usefulness of migration, how information is propagated in island models, and how to set parameters such as the migration interval. This is a novel contribution to the theoretical foundation of parallel EAs. Further, we provide empirical results that complement the theoretical results, investigate the robustness with respect to the choice of the migration interval and compare various migration topologies using statistical tests.     

How commercial involvement affects open source projects: three case studies on issue reporting

Whereas most research on Internetware has focused on new technologies for keeping track of a changing Internet,little attention has been paid to the software development process.A large portion of the software running the Internet is open source software.Open source software is developed both by volunteers and commercial companies,often jointly.Companies get involved in open source projects for commercial reasons,and bring with them a commercial software development process.Thus,it is important to understand how commercial involvement affects the software development process of open source projects.This article presents case studies of three open source application servers that are being developed jointly by a volunteer community and one primary software company.We are interested in better understanding developer behavior,specifically task distribution and performance,based on whether the developer is an external contributor,e.g.,a volunteer working in their spare time,or a commercial developer from inside the primary backing company who is being paid for their time.To achieve this,we look at issue reporting as an example of commercial involvement in open source projects.In particular,we investigate the distribution of tasks among volunteers and commercial developers by studying the source of reported issues and quantify the task performance on user experience via the issue resolution speed.We construct measures based on historical records in issue tracking repositories.Our results show that,with intensified commercial involvement,the majority of issue reporting tasks would be undertaken by commercial developers,and issue resolution time would be reduced,implying a better user experience.We hope our methods and results provide practical insights for designing an efficient hybrid development process in the Internetware environment.     

Privacy-enhanced architecture for smart metering

The recent deployment of smart grids promises to bring numerous advantages in terms of energy consumption reduction in both homes and businesses. A more transparent and instantaneous measurement of electricity consumption through smart meters utilization leads to an enhancement in the ability of monitoring, controlling and predicting energy usage. Nevertheless, it also has associated drawbacks related to the privacy of customers, since such management might reveal their personal habits, which electrical appliances they are using at each moment, whether they are at home or not, etc. In this work, we present a privacy-enhanced architecture for smart metering aimed at tackling this threat by means of encrypting individual measurements while allowing the electricity supplier to access the aggregation of the corresponding decrypted values.     

Supporting multiple perspectives in feature-based configuration

Feature diagrams have become commonplace in software product line engineering as a means to document variability early in the life cycle. Over the years, their application has also been extended to assist stakeholders in the configuration of software products. However, existing feature-based configuration techniques offer little support for tailoring configuration views to the profiles of the various stakeholders. In this paper, we propose a lightweight, yet formal and flexible, mechanism to leverage multidimensional separation of concerns in feature-based configuration. We propose a technique to specify concerns in feature diagrams and to generate automatically concern-specific configuration views. Three alternative visualisations are proposed. Our contributions are motivated and illustrated through excerpts from a real web-based meeting management application which was also used for a preliminary evaluation. We also report on the progress made in the development of a tool supporting multi-view feature-based configuration.