The effect of chemical crosslinking on the properties of Rotomolded high density polyethylene

In this study, high density polyethylene (HDPE) was combined with dicumyl peroxide (DCP) to produce crosslinked parts via rotational molding. The effect of DCP content (0.1–2.5 phr) on the crosslinking degree was investigated to determine its effect on the chemical, mechanical, physical, and thermal properties of HDPE. The gel content and crosslink density was found to increase with DCP content. These trends led to a reduction in the degree of crystallinity, melting, and crystallization temperature. Thermogravimetric analysis (TGA) showed that crosslinked HDPE (xHDPE) has higher thermal stability than the neat matrix in both air and nitrogen atmosphere. In addition, a direct relationship was observed between improved thermal resistance and higher impact strength. Finally, relationships between the tensile properties of xHDPE and the degree of crystallinity were observed, which were all controlled by the level of crosslinking. These results have the potential to advance the manufacturing of high performance materials suitable for a wide range of applications such as automotive parts, agricultural products, chemical storage tanks, large waste containers, and fuel tanks in general.     

Simple Method for Prediction of the Standard Gibbs Free Energy of Formation of Energetic Compounds

A reliable simple method for prediction of the standard Gibbs energy of formation (Δ_fG^θ) of energetic compounds containing nitroaromatic, acyclic, and cyclic nitramine, nitrate ester, and nitroaliphatic compounds is introduced herein. The method is based on the contribution of elemental composition (Δ_fG_elem^θ) and the correcting function for the presence of additive and non‐additive molecular fragments (Δ_fG_corr^θ). In presence of some molecular moieties, Δ_fG_corr^θ may increase or decrease the value of Δ_fG_elem^θ, depending on the intermolecular interactions. The experimental root‐mean‐square error (RMSE) of the novel correlation (22.7 kJ mol⁻¹) is quite good. For some energetic compounds, where the computed values of two complex models of the quantitative structure‐property relationship (QSPR) theory were available, the experimental RMSE developed by the new method is smaller than the values obtained by QSPR method.     

Effect of high temperature annealing on scratch behavior of acrylonitrile styrene acrylate copolymers

The scratch behavior of butyl-acrylate rubber-modified styrene-acrylonitrile (ASA) upon high temperature annealing is investigated following the ASTM D7027/ISO 19252 linearly increasing normal load test methodology. The critical normal loads at the onset of the major deformation transitions along the scratch path, such as groove formation, scratch visibility, microcrack formation, and plowing, are reported and quantitatively analyzed. It is found that the scratch resistance improves with high temperature annealing, i.e., 30 °C above T_g, as compared to annealing below or around T_g. Microscopic investigation suggests that the increase in scratch resistance is related to the changes in surface morphology of the polymer. It is concluded that performing high temperature annealing enhances the scratch performance without compromising ASA bulk properties. Implication of the present study for improving scratch resistance of polymers is discussed.     

Successful Use of Geoelectrical Surveys in Area 3 of the Gol-e-Gohar Iron Ore Mine,Iran

Geoelectrical surveys were conducted in Area 3 of the Gol-e-Gohar iron ore mine to provide geological and hydrogeological information. Open pit mining is currently underway in the northern part of the Area, and underground mining operations are planned for the southern section. Groundwater has already been encountered in the open pit mine. Twenty five resistivity soundings were first performed in the mine area; then, induced polarization (IP) measurements were carried out to remove ambiguities between clay and water-bearing layers. To investigate fault zones as water conduits, combined resistivity profiling surveys were also carried out. These measurements provided a detailed structural map of the pit area. Resistivity and IP results have subsequently been confirmed by observations at three monitoring wells and the mine pit wall. Monitoring and piezometric wells will be drilled at locations suggested by the results of the geoelectrical surveys. Drainage galleries may be developed to dewater the open pit mine. However, another option being considered is to start the underground mining with the idea that it will initially simply serve as a dewatering mechanism.     

Crosstalk Stability Analysis in Multilayer Graphene Nanoribbon Interconnects

In this paper a time-domain response and Nyquist stability criterion to acquire dependence of degree of crosstalk relative stability based on transmission lines modeling (TLM) is investigated for coupled multilayer graphene nanoribbon (MLGNR) interconnects. This is the first instance that such an analysis has been presented for coupled MLGNR consisting of both capacitive and mutual-inductive couplings. The near-end and far-end outputs of coupled MLGNR individually are compared in two cases, with considering both couplings and without them (single MLGNR). It is observed that the near-end output of the system together with both couplings is more stable and at its far-end output, an induced voltage is created. By increasing capacitive coupling or decreasing inductive coupling, the near-end output becomes more stable. Also, the results of changes of length and width of each ribbon show that by increasing the length and decreasing the width, the coupled MLGNR interconnects become more stable.     

Optimal design of laser solid freeform fabrication system and real-time prediction of melt pool geometry using intelligent evolutionary algorithms

With the rapid growth of laser applications and the introduction of high efficiency lasers (e.g. fiber lasers), laser material processing has gained increasing importance in a variety of industries. Among the applications of laser technology, laser cladding has received significant attention due to its high potential for material processing such as metallic coating, high value component repair, prototyping, and even low-volume manufacturing. In this paper, two optimization methods have been applied to obtain optimal operating parameters of Laser Solid Freeform Fabrication Process (LSFF) as a real world engineering problem. First, Particle Swarm Optimization (PSO) algorithm was implemented for real-time prediction of melt pool geometry. Then, a hybrid evolutionary algorithm called Self-organizing Pareto based Evolutionary Algorithm (SOPEA) was proposed to find the optimal process parameters. For further assurance on the performance of the proposed optimization technique, it was compared to some well-known vector optimization algorithms such as Non-dominated Sorting Genetic Algorithm (NSGA-II) and Strength Pareto Evolutionary Algorithm (SPEA 2). Thereafter, it was applied for simultaneous optimization of clad height and melt pool depth in LSFF process. Since there is no exact mathematical model for the clad height (deposited layer thickness) and the melt pool depth, the authors developed two Adaptive Neuro-Fuzzy Inference Systems (ANFIS) to estimate these two process parameters. Optimization procedure being done, the archived non-dominated solutions were surveyed to find the appropriate ranges of process parameters with acceptable dilutions. Finally, the selected optimal ranges were used to find a case with the minimum rapid prototyping time. The results indicate the acceptable potential of evolutionary strategies for controlling and optimization of LSFF process as a complicated engineering problem.     

A practical eco-environmental distribution network planning model including fuel cells and non-renewable distributed energy resources

This paper presents a long-term dynamic multi-objective planning model for distribution network expansion along with distributed energy options. The proposed model optimizes two objectives, namely costs and emissions and determines the optimal schemes of sizing, placement and specially the dynamics (i.e., timing) of investments on distributed generation units and network reinforcements over the planning period. An efficient two-stage heuristic method is proposed to solve the formulated planning problem. The effectiveness of the proposed model is demonstrated by applying it to a distribution network and comparing the simulation results with other methods and models.     

Hybrid cascode compensation with feedforward stage for high-speed area-efficient three-stage CMOS amplifiers

Hybrid cascode feedforward compensation (HCFC) is proposed for low-power area-efficient three stage amplifiers driving large capacitive loads. With no overhead in power or area, the total compensation capacitor is divided and shared between two internal high-speed loops instead of solely one loop as is common in prior art. Detailed analysis of HCFC shows significant improvement in terms of stability and bandwidth. This is verified for a 1.2-V amplifier driving a 500-pF capacitive load in 90-nm CMOS technology, where HCFC reduces the total capacitor size and improves the gain-bandwidth by at least 30 and 40 %, respectively, compared to the prevailing schemes.