Assessing the performance of an industrial SBCR for Fischer–Tropsch synthesis: Experimental and modeling

The main objective of this study is to predict the performance of an industrial‐scale (ID = 5.8 m) slurry bubble column reactor (SBCR) operating with iron‐based catalyst for Fischer–Tropsch (FT) synthesis, with emphasis on catalyst deactivation. To achieve this objective, a comprehensive reactor model, incorporating the hydrodynamic and mass‐transfer parameters (gas holdup, ε_G, Sauter‐mean diameter of gas bubbles, d₃₂, and volumetric liquid‐side mass‐transfer coefficients, k_La), and FT as well as water gas shift reaction kinetics, was developed. The hydrodynamic and mass‐transfer parameters for He/N₂ gaseous mixtures, as surrogates for H₂/CO, were obtained in an actual molten FT reactor wax produced from the same reactor. The data were measured in a pilot‐scale (0.29 m) SBCR under different pressures (4–31 bar), temperatures (380–500 K), superficial gas velocities (0.1–0.3 m/s), and iron‐based catalyst concentrations (0–45 wt %). The data were modeled and predictive correlations were incorporated into the reactor model. The reactor model was then used to study the effects of catalyst concentration and reactor length‐to‐diameter ratio (L/D) on the water partial pressure, which is mainly responsible for iron catalyst deactivation, the H₂ and CO conversions and the C₅₊ product yields. The modeling results of the industrial SBCR investigated in this study showed that (1) the water partial pressure should be maintained under 3 bars to minimize deactivation of the iron‐based catalyst used; (2) the catalyst concentration has much more impact on the gas holdup and reactor performance than the reactor height; and (3) the reactor should be operated in the kinetically controlled regime with an L/D of 4.48 and a catalyst concentration of 22 wt % to maximize C₅₊ products yield, while minimizing the iron catalyst deactivation. Under such conditions, the H₂ and CO conversions were 49.4% and 69.3%, respectively, and the C₅₊ products yield was 435.6 ton/day. © 2015 American Institute of Chemical Engineers AIChE J, 61: 3838–3857, 2015     

The influences of some additives on electrochemical behaviour of nickel electrodes

Nickel hydroxide is used as an active material in positive electrodes of rechargeable alkaline batteries. Since the nickel hydroxide electrode exhibits a poor performance which results not only from the competitive reactions of the oxidation of the active material but also from the evolution of oxygen. Its reduced charge acceptance is suspected to be related to a relatively long distance between nickel hydroxide particles and the nearest portion of the substrate. The practical capacity of the positive nickel electrode depends on the efficiency of the conductive network connecting the Ni(OH)₂ particle with the current collector.     

Photodegradation of Famotidine by Integrated Photocatalytic Adsorbent (IPCA) and Kinetic Study

Abstract  

Integrated photocatalytic adsorbents (IPCAs) comprised of nanocrystalline titanium dioxide (TiO₂) and activated carbon (AC) were prepared using an ultrasonic impregnation technique. The IPCAs were characterised by scanning electron microscopy (SEM) and Fourier-transform infrared (FT-IR) spectroscopy and were employed as catalysts for the photodegradation of famotidine-an active pharmaceutical ingredient-in aqueous solutions using illumination from a 125 W medium pressure mercury lamp. The degradation kinetics were found to follow a pseudo-first-order rate law and varying TiO₂ loadings induced different increases in the apparent first-order rate constant of the process. The kinetic behaviour can be described in terms of a modified Langmuir–Hinshelwood (LH) model. The IPCA prepared using a 10% TiO₂ to AC loading exhibited the highest rate constant with a K _C and k _r of 0.0172 L/mg and 0.237 mg/L/min, respectively. The LH model fits the experimental data and elucidates the effect of the TiO₂ content of the IPCA on the degradation rate. The use of calcination (heat treatment) in IPCA preparation and its effect on photocatalytic and adsorption performance were also investigated. The present work demonstrates that the combination of TiO₂ and AC results in a promising material for application in the degradation of organic pollutants.     

Magnetohydrodynamic peristaltic flow of unsteady tangent‐hyperbolic fluid in an asymmetric channel

The aim of the present numerical investigation is to explore the impact of magnetic field on peristaltic flow of an incompressible tangent‐hyperbolic fluid in an asymmetric channel. The present physical model is developed based on the considered flow configuration and with the help of small Reynolds number approximations. The current flow problem is revealed under the influence of applied magnetic field. The asymmetric channel has been considered to narrate the present physical problem. Considered physical situation in the current investigation gives the unsteady coupled highly nonlinear system of partial differential equations. Also, the simplified equations for pressure, pressure gradient, and streamlines have been obtained with the help of suitable transformations. A regular perturbation scheme is employed to produce the semi‐analytical results of the present problem. The influence of various physical parameters on pressure, pressure gradient, and streamlines are illustrated with the help of graphs. From the present analysis, it is observed that the increasing magnetic number decreases the pressure and pressure gradient in the channel. Also, the size of trapping bolus increases with increasing values of Weissenberg number.     

Hall and ion-slip effects on steady MHD free convective flow through a porous medium in a vertical microchannel

We have considered the steady fully developed magnetohydrodynamic free convection flow through a porous medium in a microchannel bounded by two infinite vertical parallel plates due to asymmetric heating of plates taking Hall and ion-slip effects into account. Effects of velocity slip and temperature jump have been considered on the microchannel surfaces, and the exact solutions have been obtained for momentum and energy equations under relevant boundary conditions. The influence of governing parameters on flow formation is discussed with the aid of graphs. The significant result from the study is that an increase in the value of rarefaction parameter leads to enhancement in volume flow rate. Furthermore, it is evident that the volume flow rate is found to be an increasing function of the Hall current parameter.     

Unstructured Oncological Image Cluster Identification Using Improved Unsupervised Clustering Techniques

This paper presents, a new approach of Medical Image Pixels Clustering (MIPC), aims to trace the dissimilar patterns over the Magnetic Resonance (MR) image through the process of automatically identify the appropriate number of distinct clusters based on different improved unsupervised clustering schemes for enrichment, pattern predication and deeper investigation. The proposed MIPC consists of two stages: clustering and validation. In the clustering stage, the MIPC automatically identifies the distinct number of dissimilar clusters over the gray scale MR image based on three different improved unsupervised clustering schemes likely improved Limited Agglomerative Clustering (iLIAC), Dynamic Automatic Agglomerative Clustering (DAAC) and Optimum N-Means (ONM). In the second stage, the performance of MIPC approach is estimated by measuring Intra intimacy and Intra contrast of each individual cluster in the result of MR image based on proposed validation method namely Shreekum Intra Cluster Measure (SICM). Experimental results show that the MIPC approach is better suited for automatic identification of highly relative dissimilar clusters over the MR cancer images with higher Intra closeness and lower Intra contrast based on improved unsupervised clustering schemes.     

NICE’s Indirect Coal-to-Liquid Process for Producing Clean Transportation Fuels Using Fischer-Tropsch Synthesis

China is currently the world’s top coal consumer and the largest oil importer to sustain its rising economy and meet the mounting demand for transportation fuels. However, the increasing emissions due to the huge fossil fuels consumption, coupled with oil market instability, could derail China’s economic growth and jeopardize its national energy security. To face such a hurdle, China has been aggressively supporting low-carbon businesses opportunuties over the past decade, has recently announced several plans to cap coal utilization, and is currently the biggest investor in clean energy technologies. Coal-to-Liquid (CTL) is one of the most promising clean coal technologies, offering an ideal solution that can meet China’s energy demands and environmental expectations. It is widely known that the Shenhua Group has pioneered and is currently leading the commercialization of the Direct Coal Liquefaction (DCL) process in China. This paper highlights a part of the joint research effort undertaken by the National Institute of Clean-and-Low-Carbon Energy (NICE) and University of Pittsburgh in order to develop and commercialize the Indirect Coal Liquefaction (ICL) process. In this mission, NICE has built and operated an ICL plant including a large-scale (5.8-m ID and 30-m height) Slurry-Bubble-Column Reactor (SBCR) for Fischer-Tropsch synthesis using iron catalyst. The research, conducted at the University of Pittsburgh over the past few years, allowed building a user-friendly Simulator, based on a comprehensive SBCR model integrated with Aspen Plus and is validated using data from the NICE actual ICL plant. In this paper, the Simulator predictions of the performance of the NICE SBCR, operating with iron and cobalt catalysts under four different tail gas recycle strategies: (1) direct recycle; (2) using a Pressure Swing Adsorption (PSA) unit; (3) using a reformer; and (4) using a Chemical looping Combustion (CLC) process, are presented. It should be mentioned also that our joint research effort has laid the foundation for the design of a commercial-scale SBCR for producing one-million tons per annum of environmentally friendly and ultraclean (no sulfur, no nitrogen and virtually no aromatics) transportation fuels, which could greatly contribute to ensuring China’s national energy security while curbing its lingering emission problems.     

Kinetics,equilibrium and thermodynamic studies on biosorption of hexavalent chromium by dead fungal biomass of marine Aspergillus niger

Quite a number of reports are available on metal binding capacity of different groups of microorganisms. However, reports on the equilibrium studies on biosorption by marine fungi are quite inadequate. The present study was carried out in a batch system using dead biomass of marine Aspergillus niger for the sorption of Cr(VI). The removal rate of Cr(VI) was increased with a decrease in pH and an increase in Cr(VI) and biomass concentration. A. niger exhibited the highest Cr(VI) uptake of 117.33 mg g^?1 of biomass at pH 1.0 in the presence of 400 mg l^?1 Cr at 50 °C. Kinetics studies based on fractional power, zero order, first order, pseudo-first order, Elovich, second order and pseudo-second order rate expressions have also been carried out. The experimental data were analyzed using five, two-parameter isotherms (Langmuir, Freundlich, Dubinin–Radushkevich, Temkin and Halsey). It was observed that Langmuir model exhibited the best fit to experimental data. Thermodynamic parameters of the biosorption (ΔG°, ΔH° and ΔS°) were also determined.     

Optimum Design of Bridge Abutments under Seismic Conditions: Reliability-Based Approach

The paper focuses on the reliability-based design optimization of gravity wall bridge abutments when subjected to active condition during earthquakes. An analytical study considering the effect of uncertainties in the seismic analysis of bridge abutments is presented. Planar failure surface has been considered in conjunction with the pseudostatic limit equilibrium method for the calculation of the seismic active earth pressure. Analysis is conducted to evaluate the external stability of bridge abutments when subjected to earthquake loads. Reliability analysis is used to estimate the probability of failure in three modes of failure viz. sliding failure of the wall on its base, overturning failure about its toe (or eccentricity failure of the resultant force) and bearing failure of foundation soil below the base of wall. The properties of backfill and foundation soil below the base of abutment are treated as random variables. In addition, the uncertainties associated with characteristics of earthquake ground motions such as horizontal seismic acceleration and shear wave velocity propagating through backfill soil are considered. The optimum proportions of the abutment needed to maintain the stability are obtained against three modes of failure by targeting various component and system reliability indices. Studies have also been made to study the influence of various parameters on the seismic stability.