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81.
M.L. Young S. Gollerthan A. Baruj J. Frenzel W.W. Schmahl G. Eggeler 《Acta Materialia》2013,61(15):5800-5806
Crack extension in pseudoelastic binary NiTi shape memory alloy (SMA) compact tension (CT) specimens was examined during static loading. The material composition of 50.7 at.% Ni (austenitic, pseudoelastic) was investigated using high-energy synchrotron X-ray diffraction. A miniature CT specimen was developed, which is small enough to allow in situ testing in a synchrotron beam line to identify phases, textures and lattice strains in front of a crack tip. Stress-induced martensite in pseudoelastic NiTi SMAs was mapped in front of the crack of a CT specimen during static loading using synchrotron radiation. The phase volume fraction and lattice microstrain results are discussed and compared with results from thermographic measurements. The Poisson effect is observed by comparing the lattice strains in the loading direction and transverse to the loading direction. 相似文献
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84.
Monaco E Brenner G 《Philosophical transactions. Series A, Mathematical, physical, and engineering sciences》2011,369(1945):2387-2395
The influence of walls on binary encounters of spherical particles under creeping flow is studied by means of the lattice Boltzmann method. Depending on the initial particle displacement different behaviours can be observed, including the 'swapping' trajectories. The domain of the swapping trajectories is identified for interacting spheres with the same diameter; some preliminary results are given for the case of two spheres with different diameters. Finally, the influence of particle swapping on the dynamics of monodisperse suspensions is also described. 相似文献
85.
Stefan Neuberg Steffen KellerMartin O'Connell Jochen SchürerRichard Thiele Ralf ZapfAthanassios Ziogas Gunther Kolb 《International Journal of Hydrogen Energy》2014
Wash-coated Pt/CeO2, Pt/CeO2/ZrO2 and Pt/Cu/CeO2 and Pt/CeO2/Al2O3 based formulations were tested in sandwich type microreactors for water–gas shift (WGS) activity. At low reaction temperature of 260 °C, low conversion of carbon monoxide was initially observed which increased considerably upon the addition of air, a behaviour which was observed even after multiple cycles of start-up, operation with and without air and shut-down. At a higher reaction temperature of 400 °C air addition did not further improve the performance of the catalysts, which converted the carbon monoxide already close to equilibrium. One of the catalysts was incorporated into a larger reactor of kW scale and tested for its performance under conditions of WGS and oxygen enhanced WGS. The carbon monoxide conversion was increased by the air addition also on the larger reactor. 相似文献
86.
Tun-Wen Pi Hsiao-Yu Lin Ya-Ting Liu Tsung-Da Lin Gunther K Wertheim Jueinai Kwo Minghwei Hong 《Nanoscale research letters》2013,8(1):169
High-resolution synchrotron radiation photoemission was employed to study the effects of atomic-layer-deposited trimethylaluminum (TMA) and water on Ga-rich GaAs(001)-4 × 6 and As-rich GaAs(001)-2 × 4 surfaces. No high charge states were found in either As 3d or Ga 3d core-level spectra before and after the deposition of the precursors. TMA adsorption does not disrupt the GaAs surface structure. For the (4 × 6) surface, the TMA precursor existed in both chemisorbed and physisorbed forms. In the former, TMA has lost a methyl group and is bonded to the As of the As-Ga dimer. Upon water purge, the dimethylaluminum-As group was etched off, allowing the now exposed Ga to bond with oxygen. Water also changed the physisorbed TMA into the As-O-Al(CH3)2 configuration. This configuration was also found in 1 cycle of TMA and water exposure of the (2 × 4) surface, but with a greater strength, accounting for the high interface defect density in the mid-gap region. 相似文献
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Yong Men Gunther KolbRalf Zapf David TiemannMartin Wichert Volker HesselHolger Löwe 《International Journal of Hydrogen Energy》2008
A complete miniaturized methanol fuel processor/fuel cell system was developed and put into operation as compact hydrogen supplier for low power application. The whole system consisting of a micro-structured evaporator, a micro-structured reformer and two stages of preferential oxidation of CO (PROX) reactor, micro-structured catalytic burner, and fuel cell was operated to evaluate the performance of the whole production line from methanol to electricity. The performance of micro methanol steam reformer and PROX reactor was systematically investigated. The effect of reaction temperature, steam to carbon ratio, and contact time on the methanol steam reformer performance is presented in terms of catalytic activity, selectivity, and reformate yield. The performance of PROX reactor fed with the reformate produced by the reformer reactor was evaluated by the variation of reaction temperature and oxygen to CO ratio. The results demonstrate that micro-structured device may be an attractive power source candidate for low power application. 相似文献
89.
A recursive blind equalizer is presented that directly estimates the transmitted symbols of multiple cochannel signals in the presence of ISI. The algorithm exploits shift structure present in the data model and the finite alphabet property of the signals. The proposed method possesses a separation property that allows the symbol sequences for each user to be estimated independently of the others. Problematic issues surrounding unknown and mismatched channel lengths for the cochannel users can be handled effectively in the recursive equalizer. Additionally, if the cochannel signals are encoded prior to transmission, we show how the code structure can be incorporated into the recursive equalizer to improve its performance 相似文献
90.