Interfacial tension measurement between immiscible polymers: improved deformed drop retraction method

This paper describes an improvement of the technique to measure interfacial tension in immiscible polymer blends. Our method is based on the droplet retraction method, in which one relates the kinetics of relaxation of a deformed droplet to the interfacial tension between the matrix and droplet. Previously, the problem with this technique has been the difficulty in preparing axisymmetric ellipsoidal droplets. In our work, we demonstrate that perfect axisymmetric ellipsoidal droplets are produced at a later stage of relaxation of short imbedded fibers. With this technique, we utilize the strengths of both the deformed droplet method and the imbedded fiber retraction method while overcoming their shortcomings. The interfacial tension value thus obtained was compared to that by conventional methods. Additionally, the effect of confinement by external walls on the interfacial tension measurement was studied. Confinement affects interfacial tension measurement when the gap between the walls is less than two times the equilibrium drop size.     

A sweeping window method for detection of flaws using an explicit dynamic XFEM and absorbing boundary layers

We present a sweeping window method in elastodynamics for detection of multiple flaws embedded in a large structure. The key idea is to measure the elastic wave propagation generated by a dynamic load within a smaller substructural detecting window domain, given a sufficient number of sensors. Hence, rather than solving the full structure, one solves a set of smaller dynamic problems quickly and efficiently. To this end, an explicit dynamic extended FEM with circular/elliptical void enrichments is implemented to model the propagation of elastic waves in the detecting window domain. To avoid wave reflections, we consider the window as an unbounded domain with the option of full‐infinite/semi‐infinite/quarter‐infinite domains and employ a simple multi‐dimensional absorbing boundary layer technique. A spatially varying Rayleigh damping is proposed to eliminate spurious wave reflections at the artificial model boundaries. In the process of flaw detection, two phases are proposed: (i) pre‐analysis—identification of rough damage regions through a data‐driven approach, and (ii) post‐analysis‐–identification of the true flaw parameters by a two‐stage optimization technique. The ‘pre‐analysis’ phase considers the information contained in the ‘pseudo’ healthy structure and the scattered wave signals, providing an admissible initial guess for the optimization process. Then a two‐stage optimization approach (the simplex method and a damped Gauss–Newton algorithm) is carried out in the ‘post‐analysis’ phase for convergence to the true flaw parameters. A weighted sum of the least squares, of the residuals between the measured and simulated waves, is used to construct the objective function for optimization. Several benchmark examples are numerically illustrated to test the performance of the proposed sweeping methodology for detection of multiple flaws in an unbounded elastic domain. Copyright © 2015 John Wiley & Sons, Ltd.     

A disposable,integrated loop-mediated isothermal amplification cassette with thermally actuated valves

An inexpensive, disposable, integrated, polymer-based cassette for loop-mediated isothermal amplification (LAMP) of target nucleic acids was designed, fabricated, and tested. The LAMP chamber was equipped with single-use, thermally actuated valves made with a composite consisting of a mixture of PDMS and expandable microspheres. The effect of the composite composition on its expansion was investigated, and the valve’s performance was evaluated. In its closed state, the valve can hold pressures as high as 200 kPa without any significant leakage. Both the LAMP chamber and the valves were actuated with thin film heaters. The utility of the cassette was demonstrated by carrying out LAMP of Escherichia coli DNA target and reverse transcribed loop meditated isothermal amplification (RT-LAMP) of RNA targets. The amplicons were detected in real time with a portable, compact detector. The system was capable of detecting as few as 10 target molecules per sample in well under 1 h. The portable, integrated cassette system described here is particularly suited for applications at the point of care and in resource-poor countries, where funds and trained personnel are in short supply.     

Control charts for the queue length in a G/G/S system

Statistical-process-control-based monitoring of performance measures of queuing systems has so far eluded mainstream practices within the quality engineering discipline. There are two reasons for this. First, most measures have highly skewed distributions, and, secondly, no general theoretical formulae exist that may provide a platform to calculate control limits for the general G/G/S queue. In this paper, Shewhart-like general control charts for attributes, recently introduced, are combined with existent highly accurate approximations for the steady-state probabilities of the G/G/S queue, to develop control charts for the queue size in a G/G/S system. The effectiveness of this approach is discussed and demonstrated by applying the proposed control charts to a sample of queues with various inter-arrival time and service time distributions.     

Twelve-Week Outcomes From an Investigation of High-Dose Nicotine Patch Therapy for Heavy Smokers With a Past History of Alcohol Dependence.

This study reports findings from an investigation of the efficacy of high-dose nicotine patch (NP) therapy for heavy smokers with a past history of alcohol dependence. One hundred thirty participants were randomly assigned to 42 mg or 21 mg of transdermal nicotine for 4 weeks, followed by an 8-week dose titration. Follow-up assessments were conducted at 4 and 12 weeks. Differences between dose conditions were nonsignificant, although unexpectedly, outcomes favored participants in the 21-mg NP condition. Nicotine abstinence at follow-up was related to longer length of alcohol abstinence at time of enrollment. Future research should investigate ways to improve smoking quit rates in this population, including more frequent counseling sessions and/or other pharmacotherapies. These investigations should focus primarily on smokers in early alcohol recovery. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

线阵CCD光谱分辨率检测系统设计

在分析光谱测试仪器检测设备发展现状的前提下,为解决光栅分辨率测试仪器中存在的电路复杂、探测器灵敏度低、结构可变通性差等问题,设计了一种以线阵CCD ILX554B为探测器的、以STM32F103为主控单元的线阵CCD光谱分辨率检测系统。系统利用片上高速时钟产生线阵CCD所需的驱动时序,经片上ADC采样后获取实时的光谱数据,将采集的数据经USB接口上传给上位机进行处理,获得最终的被测分光器件的光谱分辨率信息。最后,分别以汞灯和氩灯为光源,利用所设计的系统对光栅分辨率进行了测试,实验数据表明,在500 k Hz的驱动频率下,系统光谱分辨率可以达到0.01nm。系统满足低成本、高精度、稳定和可靠等要求。     

Thermally reversible cross-links in a healable polymer: Estimating the quantity,rate of formation,and effect on viscosity

The conversion behavior of 2MEP4FS, a polymer with thermally reversible Diels–Alder cross-links, is modeled. A processing method is developed to create small, homogeneous prepolymer samples. The glass transition temperature of the prepolymer is estimated using temperature modulated differential scanning calorimetry and equated with the conversion of the polymer. Comparing the measured energy with the literature and computational estimates, the fully cured polymer appears to have a large portion of its moieties unreacted. An autocatalytic model is considered to approximate the reaction rate of 2MEP4FS as a function of conversion and temperature. Outside of the fitted temperature range, the model underpredicts the reaction rates at room temperature and 100 °C. Manual mixing of the monomers is determined to be inadequate to obtain a maximum level of cross-linking. Viscosity measurements made at room temperature and elevated temperatures are correlated with the conversion of the prepolymer.     

ISSN exercise & sport nutrition review: research & recommendations

Sports nutrition is a constantly evolving field with hundreds of research papers published annually. For this reason, keeping up to date with the literature is often difficult. This paper is a five year update of the sports nutrition review article published as the lead paper to launch the JISSN in 2004 and presents a well-referenced overview of the current state of the science related to how to optimize training and athletic performance through nutrition. More specifically, this paper provides an overview of: 1.) The definitional category of ergogenic aids and dietary supplements; 2.) How dietary supplements are legally regulated; 3.) How to evaluate the scientific merit of nutritional supplements; 4.) General nutritional strategies to optimize performance and enhance recovery; and, 5.) An overview of our current understanding of the ergogenic value of nutrition and dietary supplementation in regards to weight gain, weight loss, and performance enhancement. Our hope is that ISSN members and individuals interested in sports nutrition find this review useful in their daily practice and consultation with their clients.     

Fuzzy and probability vectors as elements of a vector space

The problem of defining vector space operations on fuzzy and probability vectors is discussed. It is shown that such a definition is equivalent to choosing a 1-1 and onto mapping from the unit interval into the real axis. Although such a mapping cannot be continuous, it is suggested that under certain approximations a continuous mapping can be chosen. A characterization of some useful mappings with applications to image processing is also given.