Oxidation behavior and mechanism of aluminum oxynitride (AlON) at elevated temperatures

The oxidation behavior and mechanism of aluminum oxynitride (AlON) powder exposed to air at elevated temperatures between 800°C and 1300°C was investigated by X-ray diffractometry (XRD), scanning electron microscope (SEM), electron spin resonance (ESR), nuclear magnetic resonance (NMR), and simultaneous thermogravimetry, differential thermal analysis, and mass spectrometry techniques (TG-DTA-MS). The weight of AlON gradually increases to a maximum value at 1150°C and then decreases with further heating. Meanwhile, AlON powder undergoes chemical changes, as evidenced by lattice expansion, and turns eventually into alumina. ESR spectra reveal the occurrence of lone pair electrons in the oxidized products and the intensity of corresponding resonance signal increases before disappearing with the increase in temperature. Combined with the results of NMR and TG-DTA-MS, the measured data suggest that Al-N in [AlO₃N] tetrahedron and [AlO₅N] octahedron are gradually oxidized into Al-O-N group with lone pair electrons, which causes continuous weight gain and lattice expansion. Further oxidation at higher temperatures results in alumina and N₂.     

针对直流偏移和谐波干扰的单相锁相环

针对电网普遍存在的直流偏移和谐波干扰等问题,提出一种基于二阶广义积分器锁相环(SOGI-PLL)的改进型锁相环算法.该方法在前级二阶广义积分器(SOGI)中增加积分支路并且改为固定频率结构,以抑制直流偏移和简化参数设计;在后级锁相环(PLL)环路中引入滑动平均值滤波器(MAF),去掉比例积分控制器的积分环节,以增强滤波性能和加快动态响应速度.利用伯德图分析和小信号模型推导等方法,指导改进结构设计,确定相应的参数.所提出的改进型单相锁相环技术可以有效地消除直流偏移和高频谐波,同时具备良好的动态性能和稳定性.最后,通过Matlab/Simulink仿真和相关实验验证了该方法的优越性.     

Fe73.5Cu1.0Mo3.0Si13.5B9.0纳米软磁合金的结构与磁性

用X射线衍射及滋测量等方法研究了不同退火温度下Fe73.5Cu1.0Mo3.0Si13.5B9.0纳米软磁合金的结构与磁性,发现合金的显微组织结构与退火温度有关，退火温度为500-520℃时，合金具有最佳软磁性能，合金中如出现Fe-B化合物，软磁性能恶化.     

Characterization of （100）-orientated diamond film grown by HFCVD method with a positive DC bias voltage

The （100）-orientated diamond film was deposited by hot-filament chemical vapor deposition （HFCVD） technology with a positive DC bias voltage. The morphology, X-ray diffraction （XRD）, RMAN spectrum and dark current versus applied voltage characteristics analysis show that the positive dc bias can increase the nucleation density and （100）-orientated growth, making the growth of the high quality diamond film easier and cheaper than using other methods.     

Heat treatment process of new NdFeB magnet prepared by spark plasma sintering

1　INTRODUCTIONTraditionallysinteredNdFeBmagnetcanmeettherequirementofdimensional precisionthroughpost machining ,whichusuallyresultsin 4 5 %ofma terialloss.Post machiningnotonlywastestherareearthresources ,butalsoincreasesthe productioncost .Moreover ,itisdifficulttopreparehomogeneousworkpieceswithlargedimensionandcomplicatedshapeduetosomeuncontrollablefactorsinthecon ventionalsintering process .Ontheotherhand ,al thoughthebondedNdFeBmagnethasbetterforma bilityanddimensionalprecision ,…     

气—固相反应法制备Sm2Fe17Ny永磁合金过程中氮原子的扩散

研究了氮原子在Ｓｍ２Ｆｅ１７合金中的扩散行为，测定了扩散温度，时间与样品平均氮含量的关系，以及氮原子在样吕中的分布；计算了氮原子在Ｓｍ２Ｆｅ１７合金中的主散频率因子Ｄ０和扩散激活能Ｑ，运用扩散Ｆｉｃｋ第二定律计算了氮原子在Ｓｍ２Ｆｅ１７粉末颗粒内部的分布及其与扩散温度、扩散时间、颗粒尺寸之间的关系。     

铁基非晶合金局部晶化过程中的矫顽力拐折现象

本文研究了铁基非晶合金在局部晶化过程中矫顽力的变化,观察到等温退火时矫顽力的拐折现象,并用析出相粒子由单畴转变为多畴加以说明.计算得到的理论曲线与实验曲线的特征相符.     

Preparation of flee-standing diamond films for high frequency SAW devices

Free-standing diamond films were prepared by hot filament chemical vapor deposition （HFCVD） method under different conditions. Inter-digital transducers （IDTs） were formed on the nucleation sides of free-standing diamond films by photolithography technique. Then piezoelectric ZnO films were deposited by radio-frequency（RF） reactive magnetron sputtering to obtain the ZnO/diamond film structures. Surface morphologies of the nucleation sides and the IDTs were characterized by means of scanning electron microscopy （SEM）, atomic force microscope （AFM） and optical microscopy. The results indicate that the surfaces of nucleation sides are very smooth and the IDTs are of high quality without discontinuity and short circuit phenomenon. Raman spectra show the sharp diamond feature peak at about 1 334 cmI and the small amount of non-diamond carbon in the nucleation side. X-ray diffraction （XRD） patterns of the structure of ZnO/diamond films show a strong diffraction peak of ZnO （002）, which indicates that as-sputtered ZnO films are highly c-axis oriented.     

饱和黏土中复合条形防沉板基础承载特性研究

防沉板基础是深海油气资源开发中常用基础形式,其承受的荷载具有复杂性、非线性和不确定性,给防沉板基础的稳定性研究带来了巨大挑战。基于条形基础的承载特性提出了新型复合条形防沉板基础的结构形式,通过优化基础条数量n、宽度B和间距l可实现复合条形基础承载效率系数的最大化。结合工程设计实例,开展了该新型结构基础与传统矩形防沉板基础的对比设计。研究表明,在基础底面积相同的情况下,复合条形基础的竖直向极限承载力与矩形防沉板基础相比提高10%~20%。当复合条形基础的基础条宽度B一定时,地基竖直向极限承载力随着l/B的增加先增大后减小,最后趋于稳定。对不同的基础条宽度B,地基竖直向极限承载力均在l/B=0.2时达到最大值,且随着基础条数量n的增大而增大。     

新安江流域取水许可总量控制指标体系研究

对新安江流域水资源及其开发利用和流域取水许可现状等进行综合分析,提出了包括约束性和预期性指标在内的新安江流域取水许可总量控制指标体系,并确定出2010年流域取水许可总量控制各项指标取值.旨在为新安江流域科学实施取水许可管理制度提供定量化的技术支撑.