Flexural and Charpy impact behaviour of epoxy/glass fabric treated by nano-SiO2 and silane blend

A sizing formulation, containing compatible and incompatible silane coupling agents with epoxy resin in conjunction with nanoscale colloidal silica, was used to modify the surface of glass fabric. The modified glass fabric/epoxy resin composite panels were fabricated and characterised by flexural test, Charpy impact test and scanning electron microscope (SEM). By combining nano silica with silane blend in the fabric sizing, more energy was consumed under bending and impacting, which resulted in an improvement of the toughness in composites. The flexural strength, bending stain and Charpy impact strength of the epoxy composite/glass fabric treated with 1?wt-% nano silica and silane blend were ～42, ～22 and 35%, respectively, higher than those of silane blend coated glass fabric-reinforced composites (without nano silica). Furthermore, the change of the brittle fracture of the composite into ductile fracture was investigated by SEM micrographs. A possible toughening mechanism was also proposed.     

Lessons from metal oxides to find why Nature selected manganese and calcium for water oxidation

The problem of finding a way to store energy from abundant sources such as sunlight, wind or geothermal heat is critical. Water splitting toward hydrogen production is a very promising way for the goal. Although the cathodic reaction is of major interest in hydrogen production, the concurrent anodic water oxidation, which provides cheap electrons for the cathodic reaction, is a limitation for hydrogen formation. The best water-oxidizing catalyst was found by Nature million years ago and used in plants, algae and cyanobacteria. We believe learning from the natural system is very promising, because Nature has been successfully splitting water for millions of years, using an inexpensive and environmentally friendly MnCa oxido cluster. Herein we study the phenol oxidation by some nano-sized metal oxides in the presence of H₂O₂. As metal oxides are functional and structural models for the water-oxidizing complex in Photosystem II, the results can be expanded for the natural site. We suggest that low organic compound oxidation under water oxidation is an important issue to select manganese and calcium ions for water oxidation.     

Prioritizing of wind farm locations for hydrogen production: A case study

Many advantages of renewable energies, especially wind energy, such as abundance, permanence, and lack of pollution has encouraged many industrialized and developing countries to focus more on these clean and economic sources of energy. Identifying a good location that is suitable for the construction of a wind farm is one of the important initial steps in harnessing wind energy which is assessed this study. The purpose of this study is to prioritize and rank 13 cities of Fars province in Iran, in terms of their suitability for the construction of a wind farm. Six important criteria were used to prioritize and rank the cities. Wind power density is the most important criterion among these criteria which is calculated by obtaining the 3-h wind speed data between 2004 and 2013. DEA (Data Envelopment Analysis) method is used for prioritizing and ranking cities, and then AHP (Analytical Hierarchy Process), and FTOPSIS (Technique for Order of Preference by Similarity to Ideal Solution) methods are used to assess the validity of results. It is concluded that Izadkhast city is the suggested location for the construction of wind farm. The utilizing a wind-hydrogen energy conversion system will result in a substantial amount of hydrogen production (averagely 21.9 ton/year) when a 900 kW wind turbine is installed in this location.     

Electrode and electrolyte materials for electrochemical capacitors

Among different electric energy storage technologies electrochemical capacitors are used for energy storage applications when high power delivery or uptake is needed. Their energy and power densities, durability and efficiency are influenced by electrode and electrolyte materials however due to a high cost/performance ratio; their widespread use in energy storage systems has not been attained yet.Thanks to their properties such as high surface area, controllable pore size, low electrical resistance, good polarizability and inertness; activated carbons derived from polymeric precursors are the most used electrode materials in electrochemical capacitors at present. Other electrode materials such as shaped nano-carbons or metal oxides are also investigated as electrode materials in electrochemical capacitors, but only as useful research tools.Most commercially used electrochemical capacitors employ organic electrolytes when offering concomitant high energy and high power densities. The use of aqueous based electrolytes in electrochemical capacitor applications is mainly limited to research purposes as a result of their narrow operating voltage. Recent studies on room temperature ionic liquids to be employed as electrolyte for electrochemical capacitor applications are focused on fine tuning their physical and transport properties in order to bring the energy density of the device closer to that of batteries without compromising the power densities.In this paper a performance analysis, recent progress and the direction of future developments of various types of materials used in the fabrication of electrodes for electrochemical capacitors are presented. The influence of different types of electrolytes on the performance of electrochemical capacitors such as their output voltage and energy/power densities is also discussed.     

Enhancement of in vitro antitumour activity of epirubicin in HER2+ breast cancer cells using immunoliposome formulation

Epirubicin (EPI) is one of the potent breast cancer (BC) chemotherapeutic agents, but its adverse effects limit its efficacy. Herein, EPI was selected to be loaded in liposomal carrier, which has been targeted by a monoclonal antibody, Herceptin. The preparation process of liposomes was a modified ethanol injection method followed by Herceptin conjugation. The in vitro cell toxicity and cellular uptake of optimum formulation against HER2+ and HER2− cancer cell lines were evaluated. The results showed that the drug loading (DL%) and encapsulation efficiency (EE%) of liposome preparation method yielded 30.62% ± 0.49% and 62.39% ± 8.75%, respectively. The average size of naked liposomes (EPI‐Lipo) and immunoliposomes (EPI‐Lipo‐mAb) was 234 ± 9.86 and 257.26 ± 6.25 nm, with a relatively monodisperse distribution, which was confirmed by SEM micrographs. The release kinetic followed Higuchi model for both naked and immunoliposomes. In vitro cytotoxicity study on three different BC cell lines including BT‐20, MDA‐MB‐453 and MCF‐7 demonstrated higher toxicity of EPI in the Herceptin conjugated form (EPI‐Lipo‐mAb) in comparison with the free EPI and EPI‐Lipo in HER2 overexpressing cell line. In addition, the cellular uptake study showed a higher uptake of immunoliposomes by MCF‐7 cells in comparison with naked liposomes. In conclusion, these data show that the targeted delivery of EPI to breast cancer cells can be achieved by EPI‐Lipo‐mAb in vitro, and this strategy could be used for breast cancer therapy with further studies.     

Mitigation of the impact of transformer inrush current on voltage sag by TCSC

Thyristor Controlled Series Capacitor (TCSC) as a dynamic system, besides its capability in increasing power transfer in transmission lines, can be used to enhance different power system issues. In this paper, the effect of TCSC on voltage sag following transformer inrush current is investigated. It is shown that excessive transient inrush current occurring during transformer energizing can be mitigated by TCSC. Hence, voltage sag as one of the key components of the power quality is alleviated for the sensitive loads that are connected to the same bus which the power transformer is energized from. During a fault, TCSC can improve the voltage sag by limiting the current and help to keep the voltage as high as possible. Moreover, the inrush currents and the associated voltage sags that usually occur after clearing heavy single- or multistage faults are mitigated by the presence of TCSC. The model used for simulating inrush current is based on the characteristics of the major hysteresis loop out of which the internal trajectories are defined using the translation principal and a linear compensation to generate closed loops. An arctangent relation between the flux and the exciting current is defined. The expression parameters are deduced by curve fitting empirical data defining the major loop or the single-valued saturation characteristic.     

Hard- and soft-modeling approaches for resolution of complex formation of Co2+ and Ni2+ with glycine

Principal component analysis (PCA) was used to obtain information about the number of components in the complex formation equilibria of Co(2+) and Ni(2+) with glycine (Gly). In order to obtain a clearer insight into these complex formation systems, multivariate curve resolution-alternating least squares (MCR-ALS) was used. Using MCR-ALS as a soft-modeling method, well-defined concentration and spectral profiles were obtained under unimodality, non-negativity, and closure constraints. Based on the obtained results, an equilibrium model was proposed and subsequently, a hard-modeling method was used to resolve the complex formation equilibria completely. Due to the presence of multiple equilibria, the resolution of such systems is very difficult. The Co-Gly system was best described by a model consisting of M(GlyH), M(Gly), M(Gly)(2), M(Gly)(2)H, and M(Gly)(3) (M = Co(2+)) with the overall stability constants determined to be 7.10 ± 0.011, 5.14 ± 0.006, 9.28 ± 0.009, 13.75 ± 0.016, and 11.10 ± 0.010, respectively. On the other hand, the system of Ni-Gly was best fitted by a model containing M(GlyH), M(Gly), M(Gly)(2), M(Gly)(3), and M(Gly)(2)(OH) (M = Ni(2+)) with overall stability constants of 10.95 ± 0.04, 6.41 ± 0.03, 11.31 ± 0.03, 15.39 ± 0.06, and 14.32 ± 0.02, respectively.     

Comparing thermal and mechanochemical decomposition of ammonium paratungstate (APT)

In this research, the possibility of mechanochemical decomposition of ammonium paratungstate (APT) has been studied, and compared with thermal decomposition method. For this purpose, APT powders were milled using a planetary ball mill up to 36 h and under air atmosphere. For thermal decomposition, APT powders were heated for 30 minutes at 300 and 450 °C in air atmosphere. X-ray diffraction (XRD), differential scanning calorimeter (DSC), and thermo gravimetric analyzer (TGA) were used to study the decomposition progress, and products. The XRD results showed that APT completely decomposed to WO₃ by thermal decomposition, while the final product of mechanochemical decomposition was WO₃ (H₂O)_0.5. According to DSC and TGA results, during thermal decomposition, ammonia and water released in four steps, and leaved WO₃. By mechanochemical decomposition crystal water and ammonia liberated from APT structure, but structural water of APT remained. In both methods, an X-ray amorphous phase was the intermediate product of APT decomposition.     

Estimating Young's modulus of zona pellucida by micropipette aspiration in combination with theoretical models of ovum

The zona pellucida (ZP) is the spherical layer that surrounds the mammalian oocyte. The physical hardness of this layer plays a crucial role in fertilization and is largely unknown because of the lack of appropriate measuring and modelling methods. The aim of this study is to measure the biomechanical properties of the ZP of human/mouse ovum and to test the hypothesis that Young''s modulus of the ZP varies with fertilization. Young''s moduli of ZP are determined before and after fertilization by using the micropipette aspiration technique, coupled with theoretical models of the oocyte as an elastic incompressible half-space (half-space model), an elastic compressible bilayer (layered model) or an elastic compressible shell (shell model). Comparison of the models shows that incorporation of the layered geometry of the ovum and the compressibility of the ZP in the layered and shell models may provide a means of more accurately characterizing ZP elasticity. Evaluation of results shows that although the results of the models are different, all confirm that the hardening of ZP will increase following fertilization. As can be seen, different choices of models and experimental parameters can affect the interpretation of experimental data and lead to differing mechanical properties.