Explicit model predictive control through robust optimization

A strategy that calculates an explicit state feedback policy to regulate constrained uncertain discrete-time uncertain linear systems is presented. We consider uncertain processes, affected by box-bounded multiplicative uncertainty as well as bounded additive uncertainty with linear state and inputs constraints. The proposed method includes (i) the calculation of a terminal set constraint and (ii) the robust reformulation of state constraints in the prediction horizon. These features allow the derivation of the desired policy by solving a single multiparametric quadratic programming problem that guarantees feasible operation in the presence of uncertainty. Additionally, we employ variable and constraint elimination approaches to enhance the computational performance of the strategy. We demonstrate the steps and benefits of these developments with a numerical example and a chemical engineering case study.     

Characterization of the Tribological Behavior of Different Tool Coatings and Dry Lubricant for High-Strength Aluminum Alloys at Elevated Temperatures

The use of high-strength aluminum components in automotive manufacturing offers the opportunity to reduce vehicle weight significantly and provide new lightweight potentials. In the past, the so-called hot forming and quench process (HFQ) successfully demonstrates the potential for the production of complex-shaped components made out of age-hardenable high-strength aluminum alloys. Currently, no method permits wear-free quench forming without the use of lubricants. To fulfill the increasing ecological and economic requirements, it is necessary to identify wear-reducing techniques to promote this forming technology in the future. This contribution investigates the interaction of lubricant and tool coatings on the tribological performance during quench forming of the high-strength aluminum alloy AA7075 at elevated temperatures. For this purpose, the tribological behavior is investigated using both, flat strip drawing tests and deep drawing operations. Subsequently, the component quality is compared and discussed. The results demonstrate that tool coatings are effective for the production of high-strength components in the HFQ process with minimal or even no lubrication and thus provide ecological as well as economic advantages.     

Recovery of Hydroxytyrosol from Olive Mill Wastewater Using the Promiscuous Hydrolase/Acyltransferase PestE

Olive mill wastewater (OMWW) is produced annually during olive oil extraction and contains most of the health-promoting 3-hydroxytyrosol of the olive fruit. To facilitate its recovery, enzymatic transesterification of hydroxytyrosol (HT) was directly performed in an aqueous system in the presence of ethyl acetate, yielding a 3-hydroxytyrosol acetate rich extract. For this, the promiscuous acyltransferase from Pyrobaculum calidifontis VA1 (PestE) was engineered by rational design. The best mutant for the acetylation of hydroxytyrosol (PestE_I208A_L209F_N288A) was immobilized on EziG² beads, resulting in hydroxytyrosol conversions between 82 and 89 % in one hour, for at least ten reaction cycles in a buffered hydroxytyrosol solution. Due to inhibition by other phenols in OMWW the conversions of hydroxytyrosol from this source were between 51 and 62 %. In a preparative scale reaction, 13.8 mg (57 %) of 3-hydroxytyrosol acetate was extracted from 60 mL OMWW.     

Feasibility study on a full-scale wind turbine blade monitoring campaign: Comparing performance and robustness of features extracted from medium-frequency active vibrations

The present work investigates the performance of different features, extracted from vibration-based data, for structural health monitoring of a 52-meter wind turbine blade during fatigue testing. An active vibration monitoring system was used during the test campaign, providing periodic excitation of single frequencies in the medium-frequency range, and using accelerometers to measure the vibration output on different parts of the blade. Based on previous work from the authors, data is available for the wind turbine blade in healthy state, with a manually induced damage, and with progressively increasing damage severity. Using the vibration data, different signal processing methods are used to extract damage-sensitive features. Time series methods and time-frequency domain methods are used to quantify the applied active vibration signal. Using outlier analysis, the health state of the blade is classified, and the classification accuracy through use of the different features is compared. Highest performance is generally obtained by auto-regressive modeling of the vibration outputs, using the auto-regressive parameters as features. Finally, suggestions for future improvements of the present method toward practical implementation are given.     

Study of the dyeing properties of saffron and ultrafiltrated saffron powders,as colourants for natural and synthetic fibres

There is a noticeable growing interest in the use of natural dyes in contemporary textile dyeing, motivated by the requirements imposed, in favour of environmental prosperity. The use of natural dyes reduces significantly both the energy requirements and the environmental impact of the process. In the present work natural and synthetic fibres were dyed with the dyestuff isolated from Crocus sativus L., after aqueous extraction of the dried stigmas of the plant. Additionally, part of the powder was purified by using ultrafiltration technology. The saffron extract and the ultrafiltrated saffron retentate were used to dye cotton, wool, nylon and polyester, in various depths of shade and temperatures. Both saffron and ultrafiltrated saffron successfully dyed not only the natural substrates, but also the synthetic ones, while higher dyeing temperatures produced level dyeing with all substrates used. Ultrafiltrated saffron powder produced brighter and much stronger dyeing to the original saffron powder, due to the elimination of extraction by-products. Isothermal adsorptions for both colourants were performed on all substrates in order to investigate their adsorption mechanism. It was found that saffron and ultrafiltrated saffron follow a Freundlich-type adsorption isotherm on cotton, wool and nylon which is a typical mechanism for a planar-directed dye of big molecular weight. Nernst-type adsorption was found to occur on polyester which again is typical for the adsorption of disperse dyes on polyester. Thus, saffron can be claimed as a universal dye, able to successfully dye natural and synthetic substrates.     

Differential Effects of Betacyanin and Betaxanthin Pigments on Oxidative Stress and Inflammatory Response in Murine Macrophages

Scope: Betalain pigments are increasingly highlighted for their bioactive and anti-inflammatory properties, although research is lacking to demonstrate contributions of individual betalains. The work herein aimed to compare effects of four main betalains on inflammatory and cell-protective markers and to highlight potential structure-related relationships of the two main subgroups: betacyanins vs betaxanthins. Methods and results: Murine RAW 264.7 macrophages were stimulated with bacterial lipopolysaccharide following incubation with betacyanins (betanin, neobetanin) and betaxanthins (indicaxanthin, vulgaxanthin I) in concentrations from 1 to 100 µM. All betalains suppressed expression of pro-inflammatory markers IL-6, IL-1β, iNOS, and COX-2 with tendency for stronger effects of betacyanins compared to betaxanthins. In contrast, HO-1 and gGCS showed mixed and only moderate induction, while more emphasized effects were observed for betacyanins. While all betalains suppressed mRNA levels of NADPH oxidase 2 (NOX-2), a superoxide generating enzyme, only betacyanins were able to counteract hydrogen peroxide induced reactive oxygen species (ROS) generation, in alignment with their radical scavenging potential. Furthermore, betaxanthins exerted pro-oxidant properties, elevating ROS production beyond hydrogen peroxide stimulation. Conclusion: In summary, all betalains display anti-inflammatory properties, although only betacyanins demonstrate radical scavenging capacities, indicating potential differing responses under oxidative stress conditions, which requires further research.