Compatibilization Effects of PE-g-MA on Mechanical,Thermal and Swelling Properties of High Density Polyethylene/Natural Rubber/Thermoplastic Tapioca Starch Blends

Effect of polyethylene grafted maleic anhydride (PE-g-MA) on mechanical, thermal and swelling characteristic of high density polyethylene (HDPE)/natural rubber (NR)/thermoplastic tapioca starch (TPS) blends were studied. The measurements from differential scanning calorimetric (DSC), dynamic mechanical analysis (DMA) and thermogravimetric analysis (TGA), proved the effectiveness of PE-g-MA as compatibilizer in improving the miscibility between HDPE/NR – TPS blends. A decrement in crystallinity index was found after adding PE-g-MA. It is due to restriction in mobility of the HDPE chains. In the presence of PE-g-MA, the blends have better thermal stability. On top of that, the storage modulus which is reflected to the blend stiffness also increased as indicated the improvement in HDPE/NR – TPS interaction.     

Palladium nanoparticles as reusable catalyst for the synthesis of N-aryl sulfonamides under mild reaction conditions

An efficient palladium nanoparticles-catalyzed N-arylation of sulfonamides and sulfonyl azides is described. This procedure serves as an active protocol for intermolecular C–N bond formation using Pd(OAc)₂ in PEG-400 under air. Aryl bromides and triflates react at 35°C, while aryl chlorides require heating to 50°C and give the desired products only in low yields. This reaction proceeds smoothly in acceptable yields using low catalyst loading.     

Degradation of PCBs in a marine sediment treated with ionizing and UV radiation

Radiolytic (electron beam) and photolytic (ultraviolet, UV) dechlorination of polychlorinated biphenyls (PCBs) in a marine sediment are described. Samples of a PCB-laden marine sediment, Standard Reference Material (SRM) 1944, NewYork/New Jersey Waterway Sediment, have been mixed with aqueous alcohol solutions and irradiated with an electron beam or photolyzed. Additives, such as alcohol, enhance the radiolytic yield and PCB dechlorination. In the electron beam irradiated samples, the concentrations of 29 PCB congeners decrease with irradiation dose. At the highest dose (500 kGy), the total concentration of PCBs is decreased by 83%. Photolysis leads to little dechlorination, but photolysis with added triethylamine leads to dechlorination (about 60%). It is likely that photolysis under optimal conditions (other additives, exposure time) may be as effective as electron beam radiolysis for the dechlorination of PCBs in sediment.     

A novel packaging approach for RF MEMS switching functions on alumina substrate

This paper reports the design of a hermetic-compatible wafer-scale package for RF MEMS based components. The presented packaging concept consists in encapsulating the whole RF device or subsystem instead of encapsulating each MEMS component separately, which will reduce the device size and cost. This approach is based on the MEMS fabrication technology on ceramic substrate and the use of laser drilled vias hole techniques to realize full metallized vias in alumina substrates. These vias holes will allow a low loss RF signal transmission inside the package without breaking its hermeticity. Hence, several packaged switching networks prototypes, based on ohmic contact MEMS switches, have been designed following this approach and the packaging electromagnetic impact on these components has been especially studied to result on good performance devices.     

Preparation of New Fibers on the Basis of Codeine Imprinted Polymer

A monolithic copolymer of methacrylic acid-ethylene glycol dimathacrylate as a fiber with 2 cm length and 0.3 mm diameter, containing codeine (CO) template was prepared through thermal radical co-polymerization procedure. This fiber is a robust recognition material capable of mimicking natural systems, combined with solid-phase micro-extraction (SPME) and gas chromatography/mass spectrometry for the extraction of trace CO from various street-drug samples. Effective experimental parameters such as Methacrylic Acid (MAA), Ethylene glycol dimethacrylate (EDMA), and CO proportions, nature, and dimension of mold, copolymerization time and temperature were optimized. Experimental studies such as scanning electron microscopy (SEM) reveal that highly homogenate fiber was achieved that can preciously be used for the above mentioned goals.     

System integration of high voltage electrostatic MEMS actuators

A system integration for High Voltage (HV) electrostatic MicroElectroMechanical Systems (MEMS) actuators is introduced on a micro-Printed Circuit Board. The system includes a programmable microcontroller, a programmable DC/DC converter, a multi output HV interface and electrostatic MEMS actuators. The system produces high output voltages (10–300 V) and can control a large variety of MEMS capacitive loads (1 to 50 pF) by combining diverse semiconductor technologies. This system proves that technologies, such as low voltage CMOS of different processes, high voltage DMOS and MEMS, can interact, communicate and even be integrated as a System In Package (SIP), providing significant size and cost reductions. The system was programmed to control electrostatic MEMS actuator. The DC/DC converter was made from components of different technologies and two addressable high voltage CMOS interfaces were fabricated with DALSA's 0.8 μm High Voltage process. A prototype of the global system has been built and tested.     

An Empirical Study of Factors Affecting e-Commerce Adoption among Small- and Medium-Sized Enterprises in a Developing Country: Evidence from Malaysia

The purpose of this paper is to empirically examine determinants of e-commerce adoption among Malaysian small- and medium-sized enterprises (SMEs). This study tested eight hypotheses on determinants affecting e-commerce adoption with empirical data from several survey instruments: an online questionnaire-based survey, mailed survey and questionnaire collected in-person from a sample of 307 SMEs in Malaysia. The findings show that e-commerce adoption within Malaysian SMEs is affected by perceived relative advantage, perceived compatibility, managers/owner's knowledge and expertise, management characteristics and external change agents. This study contributes to enhancing the understanding of the determinants of adopting e-commerce in SMEs and provides some interesting perspective from Malaysia. Those parties interested in promoting their business online may find these results helpful in guiding their efforts.     

Folksonomy link prediction based on a tripartite graph for tag recommendation

Nowadays social tagging has become a popular way to annotate, search, navigate and discover online resources, in turn leading to the sheer amount of user-generated metadata. This paper addresses the problem of recommending suitable tags during folksonomy development from a graph-based perspective. The proposed approach adapts the Katz measure, a path-ensemble based proximity measure, for the use in social tagging systems. We model a folksonomy as a weighted, undirected tripartite graph. We then apply the Katz measure to this graph, and exploit it to provide tag recommendations for individual users. We evaluate our method on two real-world folksonomies collected from CiteULike and Last.fm. The experimental results demonstrate that the proposed method improves the recommendation performance and is effective for both active taggers and cold-start taggers compared to existing algorithms.     

Silver (Ag) as a novel masking material in glass etching for microfluidics applications

In this paper, we report the use of a single masking film for deep glass etching in hydrofluoric acid (HF). Thin film silver (Ag) is the key masking material in this work enabling a simple and low cost fabrication of microfluidic structures. The Ag film was deposited by evaporation and etched in a diluted nitric acid and de-ionized water solution at a ratio of 1:3. Surface morphology for different thicknesses of Ag film and its correlation to the maximum achievable etch depth is analyzed. AFM results shows low roughness values (<5 nm), indicating the Ag films are of smooth surface. With a 100 nm Ag film, a 220 μm etch depth in borosilicate glass substrates were produced and by further thickening the Ag to 300 nm, etch depths exceeding 300 μm were successfully achieved. SEM images show that thinner Ag films are of finer grains, potentially a source for pinholes formation where rapid penetration of HF along the grain boundaries peels off the Ag film from the glass surface. However, the Ag film was found not to react with HF. The process was demonstrated in the fabrication of cavities for integration with other microfluidic devices.     

A flexible three-level logistic network design considering cost and time criteria with a multi-objective evolutionary algorithm

Nowadays, time and cost are familiar criteria for every logistic provider, and both have been long treated to be minimized simultaneously. However, the criteria are naturally conflicted even with flexibilities and/or constraints appeared in the logistic networks. This paper is concerned with three-level logistic networks with potential suppliers, distributed centers (DCs), and deterministic demands from available consumers. The networks also benefit from potential direct shipments from suppliers to consumers as long as suppliers and DCs facilities might face limited capacity in their own seasonal supplying and warehousing processes. The goal is (re)configure the networks in order to minimize response time to consumers, transportation cost and facility cost. Therefore, the networks are formulated as multiple criteria decision making problems, which have more than one configuration through the time and cost optimizing at the same time. Due to the flexibility and the constraints, the decision maker(s) needs a set of compromise solutions for the networks that represent optimal configurations based on the objectives without considering prior knowledge. To this end, the problems are formulated into four individual logistic network models varying with the flexibility option and/or the capacitated facilities. To find the compromise solutions, Pareto-based multi-objective evolutionary algorithm, NSGA-II is customized and then utilized to deal with an illustrative case study. The results are analyzed through the two performance measures, hypervolume and the number of optimal solutions obtained so far.