Enhancing the performance of dye-sensitized solar cells by incorporating nanosilicate platelets in gel electrolyte

Two kinds of gel-type dye-sensitized solar cells (DSSCs), composed of two types of electrolytes, were constructed and the respective cell performance was evaluated in this study. One electrolyte, TEOS-Triton X-100 gel, was based on a hybrid organic/inorganic gel electrolyte made by the sol–gel method and the other was based on poly(vinyidene fluoride-co-hexafluoro propylene) (PVDF-HFP) copolymer. TEOS-Triton X-100 gel was based on the reticulate structure of silica, formed by hydrolysis, and condensation of tetraethoxysilane (TEOS), while its organic subphase was a mixture of surfactant (Triton X-100) and ionic liquid electrolytes. Both DSSC gel-type electrolytes were composed of iodine, 1-propy-3-methyl-imidazolium iodide, and 3-methoxypropionitrile to create the redox couple of I₃⁻/I⁻. Based on the results obtained from the I–V characteristics, it was found that the optimal iodine concentrations for the TEOS-Triton X-100 gel electrolyte and PVDF-HFP gel electrolyte are 0.05 M and 0.1 M, respectively. Although the increase in the iodine concentration could enhance the short-circuit current density (J_SC), a further increase in the iodine concentration would reduce the J_SC due to increased dark current. Therefore, the concentration of I₂ is a significant factor in determining the performance of DSSCs.In order to enhance cell performance, the addition of nanosilicate platelets (NSPs) in the above-mentioned gel electrolytes was investigated. By incorporating NSP-Triton X-100 into the electrolytes, the J_SC of the cells increased due to the decrease of diffusion resistance, while the open circuit voltage (V_OC) remained almost the same. As the loading of the NSP-Triton X-100 in the TEOS-Triton X-100 gel electrolyte increased to 0.5 wt%, the J_SC and the conversion efficiency increased from 8.5 to 12 mA/cm² and from 3.6% to 4.7%, respectively. However, the J_SC decreased as the loading of NSP-Triton X-100 exceeded 0.5 wt%. At higher NSP-Triton X-100 loading, NSPs acted as a barrier interface between the electrolyte and the dye molecules, hindering electron transfer, hence, reducing the cell's photocurrent density. The same behavior was also observed in the PVDF-HFP gel electrolyte DSSC system.     

Analysis of stress intensity factors for three-dimensional interface crack problems in electronic packages using the virtual crack closure technique

In this study the fracture mechanics parameters, including the strain energy release rate, the stress intensity factors and phase angles, along the curvilinear front of a three-dimensional bimaterial interface crack in electronic packages are considered by using finite element method with the virtual crack closure technique (VCCT). In the numerical procedure normalized complex stress intensity factors and the corresponding phase angles (Rice, J Appl Mech 55:98–103, 1988) are calculated from the crack closure integrals for an opening interface crack tip. Alternative procedures are also described for the cases of crack under inner pressure and crack faces under large-scale contact. Validation for the procedure is performed by comparing numerical results to analytical solutions for the problems of interface crack subjected to either remote tension or mixed loading. The numerical approach is then applied to study interface crack problems in electronic packages. Solutions for semi-circular surface crack and quarter-circular corner crack on the interface of epoxy molding compound and silicon die under uniform temperature excursion are presented. In addition, embedded corner delaminations on the interface of silicon die and underfill in flip-chip package under thermomechanical load are investigated. Based on the distribution of the fracture mechanics parameters along the interface crack front, qualitative predictions on the propensity of interface crack propagation under thermomechanical loads are given.     

Predictors and consequences of promotion stress: A bad situation made worse by employment dependence.

This study examined the key role that employment dependence played in intensifying both the level of promotion stress experienced as well as its effects in a sample of 257 government employees. Workers who tended to have higher levels of promotion stress were (a) less likely to have experienced career support from their supervisors; (b) less likely to perceive attractive opportunities; (c) more likely to have promotion aspirations; (d) more likely to perceive the existence of competition for positions; and (e) more likely to be dependent on their organization for employment (employment dependence). Moreover, such workers were less committed to their organization and were more likely to be looking for another job. Employment dependence intensified the effects of promotion aspirations and a lack of supervisory support on promotion stress, as well as the negative effect of promotion stress on affective commitment. Affective commitment ameliorated the association between promotion stress and the intention to leave the organization. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Wideband communication characteristics of subway stations with and without trains

The bit error rate (BER) performance for high‐speed personal communication service in subway station with and without trains is investigated. The impulse responses of subway stations for any transmitter–receiver location are computed by shooting and bouncing ray/image techniques. By using the impulse responses of these multipath channels, the BER performance of binary phase shift keying (BPSK) with orthogonal frequency division multiplexing (OFDM) system are calculated. Numerical results have shown that the multipath effect by the trains in the subway stations is an important factor for BER performance. In addition, the effect of space diversity techniques and polarization diversity techniques as well as sectored antenna on mitigating the multipath fading is also investigated. Finally, it is worth noting that in these cases the present work provides not only comparative information but also quantitative information on the performance reduction. Copyright © 2004 John Wiley & Sons, Ltd.     

Influence of mechanical properties in carbon black (CB) filled isotactic polypropylene (iPP) and propylene-ethylene block copolymer

The mechanical properties of isotactic polypropylene (iPP) and propylene-ethylene block copolymer (Co-PP) with carbon black (CB) were added as a filler. By mixing appropriate amounts of the two components through melt-blending in a twin-screw extruder, the blended pellets were prepared to a series of test specimens by injection molding. A scanning electron microscopic study was performed of the morphologies of the impact fractured surfaces. The blending of CB in Co-PP not only improves the impact strength, but also improves the flexural modulus and tensile strength; however, the heat distortion temperature (HDT) of the Co-PP/CB blends decreased with greater filler content. Furthermore, the filler of CB improves the tensile yield strength only at low filler content in iPP/CB blends, and the heat distortion temperature (HDT) and flexural modulus of the iPP/CB blends increased with greater filler content. The impact behavior is not good for the iPP/CB blends. Overall, Co-PP/CB has better interaction of molecules than iPP/CB. © 1996 John Wiley & Sons, Inc.     

Soapless emulsion polymerization of methyl methacrylate. II. Simulation of polymer particle formation

In this work, a generalized mathematical model was developed to estimate the variation of particle concentration during the entire course of soapless emulsion polymerization of methylmethacrylate (MMA). All of the factors, such as oligomeric radical absorption or desorption by polymer particles, coagulation between polymer particles, and the termination effect on the formation mechanism of polymer particles, were considered and included in this model. When appropriate parameters were selected, this model could be successfully used to interpret the experimental behavior of particle concentration during the entire reaction. Under different conditions, the rate of polymerization, the number of radicals in each particle, the instantaneous average molecular weight of polymers, and the rate constant of termination were also calculated. All of them coincided with the experimental results quite well. © 1996 John Wiley & Sons, Inc.     

Self-assisted wound healing using piezoelectric and triboelectric nanogenerators

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Real-time computability of real numbers by chemical reaction networks

Natural Computing - We explore the class of real numbers that are computed in real time by deterministic chemical reaction networks that are integral in the sense that all their reaction rate...     

Ion exchange of alkali metal cations with an inorganic resin

A comparison of the ion exchange properties of the inorganic resin Isolute SCX-2 with alkali metal cations, including francium, to the organic Dowex 50X8 resin is presented. The purpose of this study was to investigate the ion exchange properties of the alkali metal cations with a resin containing a less hydrophobic backbone structure. It was found that the less hydrophobic Isolute SCX-2 resin had a smaller range of values for the distribution coefficients when exchanged with the alkali metals than Dowex 50X8.