全文获取类型
收费全文 | 6724篇 |
免费 | 243篇 |
国内免费 | 13篇 |
专业分类
电工技术 | 65篇 |
综合类 | 6篇 |
化学工业 | 1242篇 |
金属工艺 | 82篇 |
机械仪表 | 170篇 |
建筑科学 | 256篇 |
矿业工程 | 48篇 |
能源动力 | 158篇 |
轻工业 | 528篇 |
水利工程 | 94篇 |
石油天然气 | 14篇 |
无线电 | 373篇 |
一般工业技术 | 1115篇 |
冶金工业 | 1646篇 |
原子能技术 | 47篇 |
自动化技术 | 1136篇 |
出版年
2023年 | 44篇 |
2022年 | 29篇 |
2021年 | 108篇 |
2020年 | 84篇 |
2019年 | 96篇 |
2018年 | 141篇 |
2017年 | 120篇 |
2016年 | 122篇 |
2015年 | 128篇 |
2014年 | 184篇 |
2013年 | 417篇 |
2012年 | 335篇 |
2011年 | 408篇 |
2010年 | 290篇 |
2009年 | 262篇 |
2008年 | 365篇 |
2007年 | 358篇 |
2006年 | 309篇 |
2005年 | 285篇 |
2004年 | 246篇 |
2003年 | 210篇 |
2002年 | 219篇 |
2001年 | 137篇 |
2000年 | 108篇 |
1999年 | 136篇 |
1998年 | 119篇 |
1997年 | 125篇 |
1996年 | 114篇 |
1995年 | 103篇 |
1994年 | 113篇 |
1993年 | 92篇 |
1992年 | 111篇 |
1991年 | 54篇 |
1990年 | 101篇 |
1989年 | 77篇 |
1988年 | 71篇 |
1987年 | 89篇 |
1986年 | 58篇 |
1985年 | 72篇 |
1984年 | 60篇 |
1983年 | 67篇 |
1982年 | 59篇 |
1981年 | 47篇 |
1980年 | 45篇 |
1979年 | 45篇 |
1978年 | 37篇 |
1977年 | 43篇 |
1976年 | 28篇 |
1975年 | 33篇 |
1973年 | 19篇 |
排序方式: 共有6980条查询结果,搜索用时 859 毫秒
991.
Joshua Rodstein J. Steven McElfresh James D. Barbour Ann M. Ray Lawrence M. Hanks Jocelyn G. Millar 《Journal of chemical ecology》2009,35(5):590-600
Females of the large cerambycid beetle Prionus californicus produce a powerful sex pheromone that attracts males. The pheromone was adsorbed on solid phase microextraction (SPME) fibers
inserted into the ovipositor sheath and analyzed by coupled gas chromatography-electroantennogram detection and GC-mass spectrometry.
The pheromone was identified as an isomer of 3,5-dimethyldodecanoic acid by a combination of retention index comparisons and
mass spectral interpretation. The mass spectrum was misleading because it exhibited enlarged fragment ions that were not representative
of branch points or other obvious stabilizing structural elements. The structure was verified by synthesis of 3,5-dimethyldodecanoic
acid as a mixture of all four possible isomers, and this mixture was highly attractive to male beetles in field bioassays.
The SPME extracts also contained several other compounds that were tentatively identified as chain-extended homologs of the
main pheromone component. This pheromone should prove useful for sampling and management of the beetle, which is an important
pest of hops, and an occasional pest in a variety of orchard crops. Although this is the first female-produced pheromone to
be identified from the Cerambycidae, there is considerable evidence for pheromone production by females of other species in the subfamily Prioninae. Thus, this pheromone and the associated methodology used in its identification should be useful in the identification of
female-produced attractant pheromones from other members of the subfamily.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
992.
Effects of partial hydrogenation, epoxidation, and hydroxylation on the fuel properties of fatty acid methyl esters 总被引:1,自引:0,他引:1
Kapila Wadumesthrige Steven O. Salley K.Y. Simon Ng 《Fuel Processing Technology》2009,90(10):1292-1299
The properties of biodiesel depend on the chemical structure of individual fatty acid methyl esters (FAME). In this work the chemical structure of fatty acid chains was modified by catalytic hydrogenation, epoxidation and hydroxylation under controlled conditions. Hydrolysis of ester functionality or oxidation of fatty acid chain was not observed during these reactions. The properties of hydrogenated FAME strongly depend on the hydrogenation time. The total saturated fatty acid (SFA) percentage increased from 29.3% to 76.2% after 2 h of hydrogenation. This hydrogenated FAME showed higher oxidation stability and higher cetane number but poor cold flow properties. Formation of trans FAME was observed during hydrogenation. Both hydroxylation and epoxidation resulted in a decrease of unsaturated fatty acid methyl ester (UFA) fraction. The percentages of total unsaturated FAME decreased 39% in the epoxidation reaction and 44% in the hydroxylation reaction. The addition of hydroxyl groups to the unsaturated regions of the fatty acid chain yields biodiesel with better cold flow properties, increased lubricity and slightly increased oxidative stability. However, epoxy FAME shows some interesting properties such as higher oxidation stability, higher cetane number and acceptable cold flow properties, which met the limits of ASTM D6751 biodiesel specifications. 相似文献
993.
Steven C. Patch Margaret C. Ullman James J. Jetter 《The Science of the total environment》2009,407(22):5818-5824
A controlled simulation experiment was performed to assess whether dislodgeable arsenic can be tracked onto carpets via foot traffic from chromated copper arsenate (CCA) pressure-treated decks. The pilot simulation study demonstrated that it is possible to track arsenic from CCA-decks onto carpets under the test conditions evaluated. A total of nine CCA-decks and two non-CCA-treated control surfaces were tested under wet and dry conditions. Five participants walked in a controlled manner (60 cycles, 11 steps per cycle) across decks and then walked over various lanes of carpet to simulate the tracking of arsenic indoors on the bottoms of shoes under heavy foot traffic conditions. To determine if arsenic was transferred from the CCA-treated wood to the carpet via shoes, laboratory analysis was performed on three different types of samples: (1) wipe samples of dislodgeable arsenic from a 46 cm2 area of carpet, (2) dust samples obtained from vacuuming a 7442 cm2 area of carpet, and (3) extractions of 13 cm2 carpet samples. Wipe samples were also taken directly from the deck lumber. Following digestion and extraction, the amount of arsenic in each sample was measured using Graphite Furnace Atomic Absorption Spectrometry. The mean arsenic concentration measured on the carpets was 2.52 μg/(100 cm2) and 2.05 μg/(100 cm2) with wipes for the dry and wet conditions, respectively, 4.69 μg/(100 cm2) and 0.68 μg/(100 cm2) with vacuumed dust for the dry and wet conditions, respectively, and 15.56 μg/(100 cm2) and 12.31 μg/(100 cm2) with carpet extractions for the dry and wet conditions, respectively. The mean arsenic concentration measured on the decks was 22.2 μg/(100 cm2) with wipes. Further research is needed to determine if indoor exposure to arsenic due to track-in from outdoor decks via foot traffic is significant compared to exposures from other sources. 相似文献
994.
Roof wind design consist of three parts: determination of wind loads, evaluation of wind uplift resistance and correlating the resistance with the design load such that the resistance is higher than the load requirement. Wind uplift resistance of a system with its respective components is evaluated in laboratory testing. This paper presents a novel approach to estimate wind uplift resistance when components are substituted during field application. Wind dynamics, on a mechanically attached single-ply roofing assembly, lift the membrane and cause fluttering, introducing stresses at the attachment locations. In such assemblies, the fastener–deck interface is a critical design factor. First, by taking steel deck as a component this paper systematically characterizes the various steel decks that are commonly used in low slope application. Second component, namely the fasteners and its engagement strength with deck have been quantified for variations of its design, size and sources. Based on this component characterization, fastener pullout resistance (FPR) is identified as a verification factor for system wind resistance estimation. When variations occur in the fastener–deck interface between the proposed and the existing configurations, the present research through case studies has proved that: “as long as the FPR of the proposed configuration is higher than the existing configuration then wind uplift ratings can be maintained”. This is valid as long as both the configurations have all the remaining roofing components similar with comparable layout. Based on this verification, the study recommends that the testing lab should report the FPR along with the wind uplift resistance such that FPR can be used as a verification factor to accept design/field alternatives. 相似文献
995.
Shuli Yan Manhoe Kim Steven O. Salley K.Y. Simon Ng 《Applied Catalysis A: General》2009,360(2):163-170
Investigations were conducted on a series of calcium and lanthanum oxides catalyst for biodiesel production. Mixed oxides catalyst showed a superior transesterification activity over pure calcium or pure lanthanum oxide catalysts. The catalyst activity was correlated with surface basicity and specific surface areas. The effects of water and free fatty acids (FFA) levels in oil feedstock, water and CO2 in air, mass ratio of catalyst, molar ratio of oil to methanol, and reaction temperature on fatty acid methyl ester (FAME) yield were investigated. Under optimal conditions, FAME yields reached 94.3% within 60 min at 58 °C. Mixed CaO-La2O3 catalyst showed a high tolerance to water and FFA, and could be used for converting pure or diluted unrefined/waste oils to biodiesel. 相似文献
996.
In this work, we present a simple method by which to preferentially detect either high molecular weight or low molecular weight ions generated by electrospray ionization. This approach, termed selective ion filtering by digital thresholding (SIFdT) is demonstrated on a commercial ESI-TOF instrument that employs a fast digitizer coupled to a microchannel plate detector. The digital representation of each individual scan is digitally filtered prior to spectral coaddition. As larger, more highly charged ions induce a more intense response than low molecular weight singly charged species, a digital threshold can be set that precludes the detection of singly charged species yet permits the efficient detection of larger, more highly charged species. In this work, we demonstrate the applicability of this approach to eliminate low molecular weight chemical noise in ESI-TOF spectra of oligonucleotide and protein ions, demonstrate improved dynamic range for analyte solutions containing high levels of low MW constituents, and show that spectra acquired at different digital thresholds can be subtracted to yield spectra of low molecular weight constituents with improved mass measurement accuracies. A notional scheme is presented in which an alternative digitization approach is employed using multiple differentially thresholded data streams to allow improved internal mass calibration and higher resolution ion partitioning. 相似文献
997.
润滑油抗氧剂协同作用研究 总被引:3,自引:2,他引:1
对润滑油的氧化机理做了简要阐述,并根据不同的抗氧作用机理,将抗氧剂分为三类:自由基清除剂(如酚类和胺类抗氧剂)、氢过氧化物分解剂(如氨基甲酸酯)和抗氧协合剂(如不含硫磷的钼酸酯).利用加压差示扫描量热法(PDSC)对不同类型抗氧剂以及它们之间的协同作用进行了考察.研究表明,作为氢过氧化物分解剂,改进的无灰氨基甲酸酯具有比胺类、酚类抗氧剂更好的性能,这显示了氢过氧化物分解型抗氧剂巨大的应用潜力.研究还表明,具有相同抗氧机理的不同抗氧剂,如酚类和胺类抗氧剂,具有协同作用;不同作用机理的两抗氧剂之间,如自由基清除剂和氢过氧化物分解剂,具有更好的抗氧化协同效果,其中,无灰氨基甲酸酯与烷基化二苯胺抗氧剂具有最佳的抗氧协同效能,可成为高温无灰抗氧剂应用的一个很好选择;不同抗氧机理的三种抗氧剂复合,如烷基化二苯胺,氨基甲酸锌和有机钼酸酯组成的三元复合抗氧剂,具有更为优秀的抗氧化性能.通过不同机理抗氧剂之间的协同,不仅可以获得优秀的抗氧化性能,还可获得附加的极压、抗磨和减摩性能,而且有的减摩、抗磨性能还非常突出,如烷基化二苯胺、氨基甲酸锌和有机钼酸酯组成的三元复合添加剂体系. 相似文献
998.
Shelby L. Oke Kendrick Lee Rosemary Papp Steven R. Laviolette Daniel B. Hardy 《International journal of molecular sciences》2021,22(14)
The rates of gestational cannabis use have increased despite limited evidence for its safety in fetal life. Recent animal studies demonstrate that prenatal exposure to Δ9-tetrahydrocannabinol (Δ9-THC, the psychoactive component of cannabis) promotes intrauterine growth restriction (IUGR), culminating in postnatal metabolic deficits. Given IUGR is associated with impaired hepatic function, we hypothesized that Δ9-THC offspring would exhibit hepatic dyslipidemia. Pregnant Wistar rat dams received daily injections of vehicular control or 3 mg/kg Δ9-THC i.p. from embryonic day (E) 6.5 through E22. Exposure to Δ9-THC decreased the liver to body weight ratio at birth, followed by catch-up growth by three weeks of age. At six months, Δ9-THC-exposed male offspring exhibited increased visceral adiposity and higher hepatic triglycerides. This was instigated by augmented expression of enzymes involved in triglyceride synthesis (ACCα, SCD, FABP1, and DGAT2) at three weeks. Furthermore, the expression of hepatic DGAT1/DGAT2 was sustained at six months, concomitant with mitochondrial dysfunction (i.e., elevated p66shc) and oxidative stress. Interestingly, decreases in miR-203a-3p and miR-29a/b/c, both implicated in dyslipidemia, were also observed in these Δ9-THC-exposed offspring. Collectively, these findings indicate that prenatal Δ9-THC exposure results in long-term dyslipidemia associated with enhanced hepatic lipogenesis. This is attributed by mitochondrial dysfunction and epigenetic mechanisms. 相似文献
999.
Steven Hostyn Gitte VanBaelen Guy L.F. Lemire Bert U.W. Maes 《Advanced Synthesis \u0026amp; Catalysis》2008,350(16):2653-2660
9H‐α‐Carbolines have been prepared via consecutive intermolecular Buchwald–Hartwig reaction and Pd‐catalyzed intramolecular direct arylation from commercially available 2,3‐dichloropyridines and substituted anilines. The combination of a high reaction temperature (180 °C) and the use of DBU were found to be crucial for the intramolecular direct arylation reactions of the 3‐chloro‐N‐phenylpyridin‐2‐amines as no reaction was observed at 120 °C and 180 °C using different inorganic and other organic bases. On the other hand, nitrogen‐methylated pyridine analogues of these substrates {N‐[3‐chloro‐1‐methylpyridin‐2(1H)‐ylidene]anilines} do undergo ring closure at 120 °C, with K3PO4 as base, affording the respective 1‐methyl‐1H‐α‐carbolines in good yields. 相似文献
1000.