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排序方式: 共有2422条查询结果,搜索用时 15 毫秒
71.
Watanabe M Takemasa I Kawaguchi N Miyake M Nishimura N Matsubara T Matsuo E Sekimoto M Nagai K Matsuura N Monden M Nishimura O 《Proteomics. Clinical applications》2008,2(6):925-935
In the development of novel biomarkers, the proteomic approach is advantageous because using it the cancer-associated proteins can be directly identified. We previously developed a 2-nitrobenzenesulfenyl (NBS) method to improve quantitative proteome analysis. Here, we applied this method to proteomic profiling of colorectal carcinoma (CRC) to identify novel proteins with altered expression in CRC. Each pair of tumor and normal tissue specimens from 12 CRC patients was analyzed, and approximately 5000 NBS-labeled paired peaks were quantified. Peaks with altered signal intensities (>1.5-fold) and occurring frequently in the samples (>70%) were selected, and 128 proteins were identified by MS/MS analyses as differentially expressed proteins in CRC tissues. Many proteins were newly revealed to be CRC related; 30 were reported in earlier studies of CRC. Six proteins that were up-regulated in CRC (ZYX, RAN, RCN1, AHCY, LGALS1, and VIM) were further characterized and validated by Western blot and immunohistochemistry. All six were found to be CRC-localized, either in cancer cells or in stroma cells near the cancer cells. These results indicate that the proteins identified in this study are novel candidates for CRC markers, and that the NBS method is useful in proteome mining to discover novel biomarkers. 相似文献
72.
Toshiyuki Abe Junji KubotaTamotsu Tanaka Kuniaki ShojiAkio Tajiri Masao Kaneko 《Electrochimica acta》2002,47(24):3901-3907
Electrocatalytic O2 reduction was studied using a modified electrode coated with a Nafion membrane (Nf) dispersing a trinuclear ruthenium ammine complex ([(NH3)5RuIIIORuIV(NH3)4ORuIII(NH3)5]Cl6, Ru-red). When measuring cyclic voltammogram under O2 atmosphere (at 0.5 mV s−1), catalytic currents due to O2 reduction were found to develop below −0.2 V (vs. Ag/AgCl). Since Ru-red undergoes irreversible decomposition into the mononuclear complexes via the reduced state (RuIII-RuIII-RuIII) (∼−0.1 V), it is suggested that the electrocatalysis originates from the decomposed species (initial active species: RuII(NH3)5(OH2) and RuII(NH3)4(OH2)2) rather than from the Ru-red. Although the present electrocatalyst was also applied to H2O2 reduction system, the catalytic activity was found to be poor from the voltammetric behavior. It appeared that the kinetics of the electrocatalysis is much faster in the O2 reduction than in the H2O2 one. A selective and direct catalysis for O2 reduction into H2O was suggested from a ring-disk voltammogram to take place by an aggregate of the mononuclear ruthenium complexes in the polymer matrix. In addition, it was found that electrocatalytic O2 reduction involves a slow kinetic process, so that factors affecting the overall kinetics were discussed in terms of the catalysis mechanism. 相似文献
73.
Bubble wake visualization by using photochromic dye 总被引:1,自引:0,他引:1
Wake structure of a single “clean bubble”, rising in rectilinear, zigzagging or spiraling path, is experimentally investigated. A single nitrogen gas bubble was produced in a silicone oil pool and the wake structure development in the rear of the rising bubble was visualized by using photochromic dye. The flexibility of this visualization method enabled us to distinguish wake from drift easily. Both bubble motion and wake structure were recorded by using stereo high-speed video camera simultaneously. We present the first experimental support for the existence of the standing eddy at the rear of the clean bubble, as predicted by a previous numerical study by Ryskin and Leal [1984. Journal of Fluid Mechanics 148, 19-35], Dandy and Leal [1986. Physics of Fluids 29(5), 1360-1366] and Blanco and Magnaudet [1995. Physics of Fluids 7(6), 1265-1274]. We study motion of a pair of vortex filaments, which is called double-threaded type wake, in the case of bubble rising in an axi-asymmetric path. Visualization results of multiple formations of horse-shoe type vortices in one period of zigzag motion of rising bubble with shape oscillations, which has not been observed in previous studies are also presented. 相似文献
74.
Toshio Ogasawara Yuichi Ishida Takashi Ishikawa Takahira Aoki Toshiyuki Ogura 《Composites Part A》2006,37(12):2236-2240
Helium gas permeability of silicate clay (montmorillonite) particles/epoxy nanocomposites was examined. The incorporation of increasing amounts of montmorillonite particles reduced the helium gas permeability. Based on Fick’s law, gas permeation behavior of the nanocomposite was evaluated. With the increase of montmorillonite loading, gas diffusivity decreased, while gas solubility increased. Helium diffusion behavior is in agreement to the numerical results based on the Hatta–Taya–Eshelby theory. It has been revealed that dispersion of nanoscale platelets in polymer is effective in improving gas barrier property. 相似文献
75.
Hiroshi Isakari Kazuki Niino Hitoshi Yoshikawa Naoshi Nishimura 《International journal for numerical methods in engineering》2012,90(4):484-505
Preconditioning methods based on Calderon's formulae for the periodic fast multipole method for elastodynamics in 3D are investigated. Three different types of formulations are proposed. The first type is a preconditioning just by appropriately ordering the coefficient matrix without multiplying preconditioners. The other two types utilise preconditioners constructed using matrices needed in the main fast multipole method algorithms. We make several numerical experiments with proposed preconditioners to confirm the efficiency of these proposed methods. We also conclude that the preconditioning of the first type is faster with respect to the computational time than other preconditioning methods discussed in this article. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
76.
Keiko Ohtsuka Hajime Kimura Toshiyuki Iwai Akihiro Matsumoto 《Polymer International》2014,63(4):752-759
Sulfur‐containing allyl ester, which reacts with diallyl phthalate (DAP) resin to have allyl groups, was synthesized by the reaction of allyl phthalic acid with bisphenol having sulfur atoms. The sulfur‐containing allyl ester compound was blended with DAP resin to improve the adhesive properties to copper. By modification with sulfur‐containing allyl ester compound, the T‐peel adhesive strength and the lap shear adhesive strength to copper was improved. In particular, the adhesive strength was greatly improved when the resin was modified with the allyl ester compound having a disulfide bond (?S?S?) (DADS). It is concluded that this result is due to the improvement of the interfacial adhesive strength because the sulfur atom was found to be located in the surface of the copper by Fourier transform infrared (FTIR) analysis. The glass transition temperature (Tg) and the thermal decomposition temperature (Td) of the cured DAP resin modified with DADS slightly decreased with increasing concentration of DADS. The lowering of Tg is because the crosslinking density of the DAP resin modified with DADS is smaller than that of DAP resin. Moreover, from thermogravimetric analysis, the lowering of Td of the DAP resin modified with DADS is because DADS is likely to pyrolyze. © 2013 Society of Chemical Industry 相似文献
77.
Herein we propose a production scheme for conductive films composed of thin graphite sheets with high crystallinity and polymeric resin. The crystalline graphite sheets were successfully produced from natural graphite powder by solution-phase synthesis of graphite intercalation compounds (GICs), following a wet planetary-ball milling under mild conditions. The shear forces in the milling pot lead to a peeling of graphite flakes. Taking into consideration the interlayer bonding force, the delamination should be preferentially done from the expanded GICs interlayer rather than intrinsic graphite one. Some composite films derived from the phenolic resin and flaky graphite sheets displayed much higher electrical conductivities compared to the film from the feed graphite particles. We also demonstrate the stage structure of synthetic GICs affected the film conductivity. The composite films made from exfoliated products of ground (around stage IV) GICs exhibited high electrical conductivity with a small amount of the graphite sheets. 相似文献
78.
Takato Mashita Dr. Toshiyuki Kowada Hiroto Takahashi Prof. Dr. Toshitaka Matsui Prof. Dr. Shin Mizukami 《Chembiochem : a European journal of chemical biology》2019,20(11):1382-1386
Photopharmacology has attracted research attention as a new tool for achieving optical control of biomolecules, following the methods of caged compounds and optogenetics. We have developed an efficient photopharmacological inhibitor—azoMTX—for Escherichia coli dihydrofolate reductase (eDHFR) by replacing some atoms of the original ligand, methotrexate, to achieve photoisomerization properties. This fine molecular design enabled quick structural conversion between the active “bent” Z isomer of azoMTX and the inactive “extended” E isomer, and this property afforded quantitative control over the enzyme activity, depending on the wavelength of irradiating light applied. Real-time photoreversible control over enzyme activity was also achieved. 相似文献
79.
Sakdinun Nuntang Sirilux Poompradub Suchada Butnark Toshiyuki Yokoi Takashi Tatsumi Chawalit Ngamcharussrivichai 《Materials Chemistry and Physics》2014
This study is the first report on synthesis, characterization and catalytic application of propylsulfonic acid-functionalized mesoporous composites based on natural rubber (NR) and hexagonal mesoporous silica (HMS). In comparison with propylsulfonic acid-functionalized HMS (HMS-SO3H), a series of NR/HMS-SO3H composites were prepared via an in situ sol–gel process using tetrahydrofuran as the synthesis media. Tetraethylorthosilicate as the silica source, was simultaneously condensed with 3-mercaptopropyltrimethoxysilane in a solution of NR followed by oxidation with hydrogen peroxide to achieve the mesoporous composites containing propylsulfonic acid groups. Fourier-transform infrared spectroscopy and 29Si MAS nuclear magnetic resonance spectroscopy results verified that the silica surfaces of the NR/HMS-SO3H composites were functionalized with propylsulfonic acid groups and covered with NR molecules. After the incorporation of NR and organo-functional group into HMS, the hexagonal mesostructure remained intact concomitantly with an increased framework wall thickness and unit cell size, as evidenced by the X-ray powder diffraction analysis. Scanning electron microscopy analysis indicated a high interparticle porosity of NR/HMS-SO3H composites. The textural properties of NR/HMS-SO3H were affected by the amount of MPTMS loading to a smaller extent than that of HMS-SO3H. NR/HMS-SO3H exhibited higher hydrophobicity than HMS-SO3H, as revealed by H2O adsorption–desorption measurements. Moreover, the NR/HMS-SO3H catalysts possessed a superior specific activity to HMS-SO3H in the esterification of lauric acid with ethanol, resulting in a higher conversion level. 相似文献
80.
Toshiyuki Yano 《世界建筑导报》2019,(5)
<正>这间房屋是一间单层别墅,坐落于山梨县富士山山脚的海滨地区。该地区面朝美丽的湖泊,是个非常迷人的地方。湖泊在微风和阳光的抚摸下泛起丝丝涟漪。湖泊两旁种植了高大的榉树和日本枫树。在设计房屋时,我们的主旨就是欣赏周围美丽的自然环境。整间房屋30米×6.3米,沿湖而建,因此在每个房间都可以欣赏湖泊的全景。房屋室内采用以白色为主题色的简约设计。没有任何装饰性元素的中性空间面朝美丽的大自然。室内采光十分充足,室 相似文献